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The size of a zero thickness (no excluded volume) polymer ring is shown to scale with chain length $N$ in the same way as the size of the excluded volume (self-avoiding) linear polymer, as $N^{\nu}$, where $\nu \approx 0.588$. The…

Soft Condensed Matter · Physics 2009-10-31 Alexander Yu. Grosberg

We employ computer simulations and thermodynamic integration to analyse the effects of bending rigidity and slit confinement on the free energy cost of tying knots, $\Delta F_{\rm knotting}$, on polymer chains under tension. A…

Soft Condensed Matter · Physics 2014-05-15 Peter Poier , Christos N. Likos , Richard Matthews

We study the geometry of a semiflexible polymer at finite temperatures. The writhe can be calculated from the properties of Gaussian random walks on the sphere. We calculate static and dynamic writhe correlation functions. The writhe of a…

Soft Condensed Matter · Physics 2009-10-31 A. C. Maggs

This manuscript introduces a new framework for the study of knots by exploring the neighborhood of knot embeddings in the space of simple open and closed curves in 3-space. The latter gives rise to a knotoid spectrum, which determines the…

Geometric Topology · Mathematics 2024-10-22 Eleni Panagiotou

The varying coefficient model has received broad attention from researchers as it is a powerful dimension reduction tool for non-parametric modeling. Most existing varying coefficient models fitted with polynomial spline assume equidistant…

Methodology · Statistics 2022-06-15 Xufei Wang , Bo Jiang , Jun S. Liu

An off-lattice Monte Carlo algorithm for solutions of equilibrium polymers (EP) is proposed. At low and moderate densities this is shown to reproduce faithfully the (static) properties found recently for flexible linear EP using a lattice…

Statistical Mechanics · Physics 2009-10-31 A. Milchev , J. P. Wittmer , D. P. Landau

The lectures review the state of affairs in modern branch of mathematical physics called probabilistic topology. In particular we consider the following problems: (i) We estimate the probability of a trivial knot formation on the lattice…

Statistical Mechanics · Physics 2007-05-23 Sergei Nechaev

In this paper we study how randomly generated knots occupy a volume of space using topological methods. To this end, we consider the evolution of the first homology of an immersed metric neighbourhood of a knot's embedding for growing…

Geometric Topology · Mathematics 2021-08-09 Daniele Celoria , Barbara I. Mahler

Proteins can sometimes be knotted, and for many reasons the study of knotted proteins is rapidly becoming very important. For example, it has been proposed that a knot increases the stability of a protein. Knots may also alter enzymatic…

Soft Condensed Matter · Physics 2009-07-02 Martin Lundgren , Antti J. Niemi

We investigate the knotting probability after a local strand passage is performed in an unknotted self-avoiding polygon on the simple cubic lattice. We assume that two polygon segments have already been brought close together for the…

Statistical Mechanics · Physics 2015-05-27 M. L. Szafron , C. E. Soteros

We consider a natural model of random knotting- choose a knot diagram at random from the finite set of diagrams with n crossings. We tabulate diagrams with 10 and fewer crossings and classify the diagrams by knot type, allowing us to…

Geometric Topology · Mathematics 2016-10-12 Jason Cantarella , Harrison Chapman , Matt Mastin

I show that random distributions of vortex-antivortex pairs (rather than of individual vortices) lead to scaling of typical winding numbers W trapped inside a loop of circumference C with the square root of C when the expected winding…

Statistical Mechanics · Physics 2014-10-03 Wojciech H. Zurek

A polynomial knot in $\mathbb{R}^n$ is a smooth embedding of $\mathbb{R}$ in $\mathbb{R}^n$ such that the component functions are real polynomials. In the earlier paper with Mishra, we have studied the space $\mathcal{P}$ of polynomial…

General Topology · Mathematics 2021-01-05 Hitesh Raundal

We present a quantitative comparison between extensive Monte Carlo simulations and self-consistent field calculations on the phase diagram and wetting behavior of a symmetric, binary (AB) polymer blend confined into a film. The flat walls…

Statistical Mechanics · Physics 2009-10-31 M. Mueller , K. Binder

Using Monte Carlo simulations and advanced knot localization methods, we analyze the length and distribution of prime components in composite knots tied on Freely Jointed Rings (FJRs). For increasing contour length, we observe the…

Statistical Mechanics · Physics 2015-06-18 Luca Tubiana

The geometry of a smooth line is characterized locally by its curvature and torsion, or globally by its writhe. In many situations of physical interest the line is, however, not smooth so that the classical Frenet description of the…

Soft Condensed Matter · Physics 2007-05-23 A. C. Maggs

The effect of chain topology on the statics and dynamics of chain at the interface of two immiscible fluids is studied by means of molecular dynamics simulations. For three topologically different chains, namely, linear, ring, and…

Soft Condensed Matter · Physics 2024-08-01 Jenis Thongam , Lenin S. Shagolsem

The knotting probability is defined by the probability with which an $N$-step self-avoiding polygon (SAP) with a fixed type of knot appears in the configuration space. We evaluate these probabilities for some knot types on a simple cubic…

Statistical Mechanics · Physics 2009-11-07 Akihisa Yao , Hiroshi Matsuda , Hiroshi Tsukahara , Miyuki K. Shimamura , Tetsuo Deguchi

Polymer composites are ubiquitous in biology and industry alike, owing to their emergent desirable mechanical properties not attainable in single-species systems. At the same time, polymer topology has been shown to play a key role in…

The work in this article is inspired by a classical problem: the statistical physical properties of a closed polymer loop that is wound around a rod. Historically the preserved topology of this system has been addressed through…

Statistical Mechanics · Physics 2015-09-14 Christian M. Rohwer , Kristian K. Müller-Nedebock , F. -E. Mpiana Mulamba