Related papers: Hard-Sphere Fluids with Chemical Self-Potentials
The definition of the fundamental quantity, the chemical potential, is badly confused in the literature: there are at least three distinct definitions in various books and papers. While they all give the same result in the thermodynamic…
This work presents a pedagogical derivation of the thermodynamics of a van der Waals fluid by explicitly incorporating pairwise molecular interactions and the finite size of particles into the statistical-mechanical description. Starting…
Fluid phase equilibrium depends on the external constraints imposed on a system. In a closed system with fixed volume, depending on the average density, a vapor bubble may be stable, metastable, or unstable, with respect to the homogeneous…
We calculate thermodynamic and structural quantities of a fluid of hard spheres of diameter $\sigma$ in a quasi-one-dimensional pore with accessible pore width $W $ smaller than $\sigma$ by applying a perturbative method worked out earlier…
A fluid in a pore can form diverse heterogeneous structures. We combine a capillary description with the cubic-plus-association equation of state to study the thermodynamic stability of droplets, bubbles and films of water at 358 K in a…
The interest in the description of the properties of fluids of restricted dimensionality is growing for theoretical and practical reasons. In this work, we have firstly developed an analytical expression for the Helmholtz free energy of the…
We investigate the instability and stability of specific steady-state solutions of the two-dimensional non-homogeneous, incompressible, and viscous Navier-Stokes equations under the influence of a general potential $f$. This potential is…
We propose a formally exact statistical field theory for describing classical fluids with ingredients similar to those introduced in quantum field theory. We consider the following essential and related problems : i) how to find the correct…
A new phase field crystal (PFC) type theory is presented, which accounts for the full spectrum of solid-liquid-vapor phase transitions within the framework of a single density order parameter. Its equilibrium properties show the most…
We characterize a system of hard spheres with a simple collision rule that breaks time reversal symmetry, but conserves energy. The collisions lead to an a-chiral, isotropic, and homogeneous stationary state, whose properties are determined…
In this paper we consider a coupled hydrodynamical system which involves the Navier-Stokes equations for the velocity field and kinematic transport equations for the molecular orientation field. By applying the Chemin-Lerner's time-space…
We study the question of existence and uniqueness for the finite temperature Kohn-Sham equations. For finite volumes, a unique soluion is shown to exists if the effective potential satisfies a set of general conditions and the coupling…
The clearing up of a wave nature of the energy and mass transfer phenomena in classical expressions of the molecular-kinetic theory has allowed to find a quantitative measure of intensity of processes of a thermal conductivity, viscosity…
In a generic random system, the coexistence of extended and localized states can be evidenced by the subextensive width of energy distribution of a physical initial state in, for example, the quantum quenches which involving the local…
We investigate the phase behavior of a single-component system in 3 dimensions with spherically-symmetric, pairwise-additive, soft-core interactions with an attractive well at a long distance, a repulsive soft-core shoulder at an…
The self-diffusion process of a hard sphere fluid confined by two parallel plates separated by a distance on the order of the particle diameter is studied. The starting point is a closed kinetic equation for the distribution function that…
Definitions for a local pressure in an inhomogeneous fluid are considered for both equilibrium and local equilibrium states. Thermodynamic and mechanical (hydrodynamic) contexts are reconciled. Remaining problems and uncertainties are…
In this work we study in a formal way the density dependent hadron field theory at finite temperature for nuclear matter. The thermodynamical potential and related quantities, as energy density and pressure are derived in two different…
We study the Navier-Stokes system describing the motion of a compressible viscous fluid driven by a nonlinear multiplicative stochastic force. We establish local in time existence (up to a positive stopping time) of a unique solution, which…
A density-functional theory is established for inhomogeneous superfluids at finite temperature, subject to time-dependent external fields in isothermal conditions. After outlining parallelisms between a neutral superfluid and a charged…