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We present a numerically efficient technique to evaluate the Green's function for extended two dimensional systems without relying on periodic boundary conditions. Different regions of interest, or `patches', are connected using self energy…

Mesoscale and Nanoscale Physics · Physics 2015-06-23 Mikkel Settnes , Stephen R. Power , Jun Lin , Dirch H. Petersen , Antti-Pekka Jauho

Embedding calculations that find approximate solutions to the Schr\"{o}dinger equation for large molecules and realistic solids are performed commonly in a three step procedure involving (i) construction of a model system with effective…

Strongly Correlated Electrons · Physics 2016-11-15 Alexander A. Rusakov , Jordan J. Phillips , Dominika Zgid

We present an efficient implementation of a surface Green's-function method for atomistic modeling of surfaces within the framework of density functional theory using a pseudopotential localized basis set approach. In this method, the…

We present a method for obtaining well-localized Wannier-like functions (WFs) for energy bands that are attached to or mixed with other bands. The present scheme removes the limitation of the usual maximally-localized WFs method (N. Marzari…

Materials Science · Physics 2009-11-07 Ivo Souza , Nicola Marzari , David Vanderbilt

Using a plane wave pseudopotential approach to density functional theory we investigate the electron localization length in various oxides. For this purpose, we first set up a theory of the band-by-band decomposition of this quantity, more…

Materials Science · Physics 2009-11-07 M. Veithen , X. Gonze , Ph. Ghosez

We develop a Green's function approach to quasiparticle excitations of open-shell systems within the GW approximation. It is shown that accurate calculations of the characteristic multiplet structure require a precise knowledge of the self…

Materials Science · Physics 2014-09-11 Johannes Lischner , Jack Deslippe , Manish Jain , Steven G. Louie

Exploratory variational pseudopotential density functional calculations are performed for the electronic properties of many-electron systems in the 3D cartesian coordinate grid (CCG). The atom-centered localized gaussian basis set,…

Chemical Physics · Physics 2015-05-18 Amlan K Roy

Kohn-Sham (KS) density functional theory (DFT) is a very efficient method for calculating various properties of solids as, for instance, the total energy, the electron density, or the electronic band structure. The KS-DFT method leads to…

Materials Science · Physics 2019-09-20 Fabien Tran , Jan Doumont , Leila Kalantari , Ahmad W. Huran , Miguel A. L. Marques , Peter Blaha

We consider the expansion of wave packets governed by the free Schr\"odinger equation. This seemingly simple task plays an important role in simulations of various quantum experiments and in particular in the field of matter-wave…

Computational Physics · Physics 2023-03-17 Jan-Frederik Mennemann , Sebastian Erne , Igor Mazets , Norbert J. Mauser

Fractional calculus has become an essential framework in geophysics, optics, and biological systems to capture long-range correlations and anomalous transport. In this article, we extend fractional calculus to explore a particle in a…

Quantum Physics · Physics 2025-11-25 Brenden R. Guyette , Joshua M. Lewis , Lincoln D. Carr

By minimizing the difference between the left- and the right-hand sides of the many-body time-dependent Schr\"{o}dinger equation with the Slater-determinant wave-function, we derive a non-adiabatic and self-interaction free time-dependent…

Quantum Physics · Physics 2013-04-26 V. U. Nazarov

In the one-dimensional periodic potential case, we formulate the condition of Bloch periodicity for the reduced action by using the relation between the wave function and the reduced action established in the context of the equivalence…

Quantum Physics · Physics 2008-11-26 A. Bouda , A. Mohamed Meziane

Recently, bootstrap methods from conformal field theory have been adapted for studying the energy spectrum of various quantum mechanical systems. In this paper, we consider the application of these methods in obtaining the spectrum from the…

Quantum Physics · Physics 2022-12-16 Matthew J. Blacker , Arpan Bhattacharyya , Aritra Banerjee

We examine whether essence and quantitative aspects of electronic excitation spectra are correctly captured by an effective low-energy model constructed from an {\em ab initio} downfolding scheme. A global electronic structure is first…

Strongly Correlated Electrons · Physics 2009-11-13 Kazuma Nakamura , Yoshihide Yoshimoto , Ryotaro Arita , Shinji Tsuneyuki , Masatoshi Imada

The semiclassical Schr\"{o}dinger equation with multiscale and random potentials often appears when studying electron dynamics in heterogeneous quantum systems. As time evolves, the wavefunction develops high-frequency oscillations in both…

Numerical Analysis · Mathematics 2019-07-02 Jingrun Chen , Dingjiong Ma , Zhiwen Zhang

We present an approach based on density-functional theory for the calculation of fundamental gaps of both finite and periodic two-dimensional (2D) electronic systems. The computational cost of our approach is comparable to that of total…

Materials Science · Physics 2021-08-11 Alberto Guandalini , Alice Ruini , Esa Räsänen , Carlo Andrea Rozzi , Stefano Pittalis

We develop a new envelope-function formalism to describe electrons in slowly-varying inhomogeneously strained semiconductor crystals. A coordinate transformation is used to map a deformed crystal back to geometrically undeformed structure…

Materials Science · Physics 2014-10-29 Wenbin Li , Xiaofeng Qian , Ju Li

We apply the Merrifield variational method to the Holstein molecular crystal model in D dimensions to compute non-adiabatic polaron band energies and Franck-Condon factors at general crystal momenta. We analyze these observable properties…

Materials Science · Physics 2016-09-28 David W. Brown , Aldo H. Romero , Katja Lindenberg

In the recent work of S. Sharma \emph{et al.}, (arxiv.org: arxiv:0912.1118), a single-electron spectrum associated with the natural orbitals was defined as the derivative of the total energy with respect to the occupation numbers at half…

Chemical Physics · Physics 2012-03-07 E. N. Zarkadoula , S. Sharma , J. K. Dewhurst , E. K. U. Gross , N. N. Lathiotakis

In electronic structure calculations the optimized effective potential (OEP) is a method that treats exchange interactions exactly using a local potential within density-functional theory (DFT). We present a method using density functional…

Materials Science · Physics 2013-01-24 Tom W. Hollins , Stewart J. Clark , Keith Refson , Nikitas I. Gidopoulos
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