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Precise calculations of core properties in heavy-atom systems which are described by the operators heavily concentrated in atomic cores, like to hyperfine structure and P,T-parity nonconservation effects, usually require accounting for…

Atomic Physics · Physics 2015-06-26 A. V. Titov , N. S. Mosyagin , A. N. Petrov , T. A. Isaev

We suggest to include the density of electron charge explicitly in the electron potential of density functional theory, rather than implicitly via exchange-correlation functionals. The advantages of the approach are conceptual and…

Materials Science · Physics 2007-05-23 Werner A. Hofer , Krisztian Palotas

The full potential linearized augmented plane wave (FLAPW) method was used to study the crystal structure and electronic structure properties of PbFe0.5Nb0.5O3 (PFN). The optimized crystal structure, density of states, band structure and…

Materials Science · Physics 2009-11-10 Yuan Xu Wang , C L Wang , M L Zhao , J L Zhang

We study the charge-density wave phase in $\textup{TiSe}_2$ by using first principle calculations. We show that, regardless of the local functional used and as long as the cell parameters are in agreement with the experiment,…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Raffaello Bianco , Matteo Calandra , Francesco Mauri

Recent photoemission experiments on the Si(553)-Au reconstruction show a one-dimensional band with a peculiar ~1/4 filling. This band could provide an opportunity for observing large spin-charge separation if electron-electron interactions…

Materials Science · Physics 2009-11-11 Sampsa Riikonen , Daniel Sanchez-Portal

In the pursuit of advancing solar energy technologies, this study presents 20 direct and quasi-direct band gap silicon crystalline semiconductors that satisfy the Shockley-Queisser limit, a benchmark for solar cell efficiency. Employing two…

Materials Science · Physics 2024-10-28 Mostafa Yaghoobi , Mojtaba Alaei , Mahtab Shirazi , Nafise Rezaei , Stefano de Gironcoli

The LDA-1/2 method for self-energy correction is a powerful tool for calculating accurate band structures of semiconductors, while keeping the computational load as low as standard LDA. Nevertheless, controversies remain regarding the…

Computational Physics · Physics 2024-09-17 Kan-Hao Xue , Jun-Hui Yuan , Leonardo R. C. Fonseca , Xiang-Shui Miao

A comprehensive angle resolved photoemission spectroscopy study of the band structure in single layer cuprates is presented with the aim of uncovering universal trends across different materials. Five different hole- and electron-doped…

Most density functionals have been developed by imposing the known exact constraints on the exchange-correlation energy, or by a fit to a set of properties of selected systems, or by both. However, accurate modeling of the conventional…

Materials Science · Physics 2016-08-24 Jianmin Tao , Yuxiang Mo

We present a first-principles framework to extract deformation potentials in Silicon based on density-functional theory (DFT) and density-functional perturbation theory (DFPT). We compute the electronic band structures, phonon dispersion…

Materials Science · Physics 2021-11-05 Zhen Li , Patrizio Graziosi , Neophytos Neophytou

Solving the many-electron problem, even approximately, is one of the most challenging and simultaneously most important problems in contemporary condensed matter physics with various connections to other fields. The standard approach is to…

Strongly Correlated Electrons · Physics 2026-04-10 Jonas B. Profe , Jakša Vučičević , P. Peter Stavropoulos , Malte Rösner , Roser Valentí , Lennart Klebl

We fully implement the Aversa and Sipe sum-over-states formulism and make a full ab initio band structure analysis of interband and intraband contributions for the third-order nonlinear optical susceptibilities of bulk silicon. The band…

Materials Science · Physics 2017-03-21 You-Zhao Lan

We present an optimization algorithm to construct pseudopotentials and use it to generate a set of Optimized Norm-Conserving Vanderbilt (ONCV) pseudopotentials for elements up to Z=83 (Bi) (excluding Lanthanides). We introduce a quality…

Materials Science · Physics 2016-05-04 Martin Schlipf , Francois Gygi

GW approximation is one of the most popular parameter-free many-body methods that goes beyond the limitations of the standard density functional theory (DFT) to determine the excitation spectra for moderately correlated materials and in…

Materials Science · Physics 2023-12-12 Kristjan Haule , Subhasish Mandal

Semilocal density functional theory is the most used computational method for electronic structure calculations in theoretical solid-state physics and quantum chemistry of large systems, providing good accuracy with a very attractive…

Other Condensed Matter · Physics 2016-03-31 L. A. Constantin , E. Fabiano , J. M. Pitarke , F. Della Sala

The properties of mobile impurities in quantum magnets are fundamental for our understanding of strongly correlated materials and may play a key role in the physics of high-temperature superconductivity. Hereby, the motion of hole-like…

Strongly Correlated Electrons · Physics 2021-10-25 K. K. Nielsen , M. A. Bastarrachea-Magnani , T. Pohl , G. M. Bruun

Chemical accuracy serves as an important metric for assessing the effectiveness of the numerical method in Kohn--Sham density functional theory. It is found that to achieve chemical accuracy, not only the Kohn--Sham wavefunctions but also…

Computational Physics · Physics 2023-10-25 Yang Kuang , Yedan Shen , Guanghui Hu

In order to optimize the optoelectronic properties of novel solar cell architectures, such as the amorphous-crystalline interface in silicon heterojunction devices, we calculate and analyze the local microscopic structure at this interface…

Materials Science · Physics 2017-08-25 Philippe Czaja , Massimo Celino , Simone Giusepponi , Michele Gusso , Urs Aeberhard

Accurately modeling the electronic structure of materials is a persistent challenge to high-throughput screening. A promising means of balancing accuracy against computational cost are non-self-consistent calculations with hybrid…

Materials Science · Physics 2020-05-04 Jonathan M. Skelton , David S. D. Gunn , Sebastian Metz , Stephen C. Parker

A means to take advantage of molecular similarity to lower the computational cost of electronic structure theory is explored, in which parameters are embedded into a low-cost, low-level (LL) ab initio model and adjusted to obtain agreement…

Chemical Physics · Physics 2015-03-27 Matteus Tanha , Haichen Li , Shiva Kaul , Alexander Cappiello , Geoffrey J. Gordon , David J. Yaron