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Recent theoretical studies found that mixtures of active and passive colloidal particles phase separate but only at very high activity ratio. The high value poses serious obstacles for experimental exploration of this phenomenon. Here we…

Soft Condensed Matter · Physics 2017-03-08 Jan Smrek , Kurt Kremer

We consider a ternary mixture of hard colloidal spheres, ideal polymer spheres, and rigid vanishingly thin needles, which model stretched polymers or colloidal rods. For this model we develop a geometry-based density functional theory,…

Soft Condensed Matter · Physics 2009-11-07 Matthias Schmidt , Alan R. Denton

In this work we derive and analyze coarse-grained descriptions of self-propelled particles with selective attraction-repulsion interaction, where individuals may respond differently to their neighbours depending on their relative state of…

Soft Condensed Matter · Physics 2016-05-02 Robert Grossmann , Lutz Schimansky-Geier , Pawel Romanczuk

We study structural properties of a ring polymeric melt confined in a film in comparison to a linear counterpart using molecular dynamics simulations. Local structure orderings of ring and linear polymers in the vicinity of the surface are…

Soft Condensed Matter · Physics 2015-10-21 Eunsang Lee , YounJoon Jung

We study the dynamics of an ideal polymer chain in a crowded, viscoelastic medium and in the presence of active forces. The motion of the centre of mass and of individual monomers is calculated. On time scales that are comparable to the…

Soft Condensed Matter · Physics 2015-12-23 Hans Vandebroek , Carlo Vanderzande

We investigate the interaction energy between two colloidal particles on or immersed in nonadsorbing polymer brushes grafted onto the substrate as a function of the separation of the particles by use of self-consistent field theory…

Soft Condensed Matter · Physics 2007-05-23 Kang Chen , Yu-qiang Ma

The statistical theory of polymers tethered around the inner surface of a cylindrical channel has traditionally employed the assumption that the equilibrium density of the polymers is independent of the azimuthal coordinate. However,…

Soft Condensed Matter · Physics 2015-01-30 D. Osmanovic , M. Kerr-Winter , R. C. Eccleston , B. W. Hoogenboom , I. J. Ford

We present results from molecular dynamics simulations of a spherically confined neutral polymer in the presence of crowding agents, studying polymer shapes and conformations as a function of the confining potential, solvent quality and the…

Soft Condensed Matter · Physics 2020-01-29 Kamal Tripathi , Gautam I. Menon , Satyavani Vemparala

Experiments with polymer latex solutions show the coexistence of order-disorder structures of macroions. Because of the large macroions' sizes, this order-disorder phase coexistence imply the existence of very long-range attractive and…

Soft Condensed Matter · Physics 2019-02-20 Alfredo González-Calderón , Enrique González-Tovar , Marcelo Lozada-Cassou

We present the results of analytic calculations and numerical simulations of the behaviour of a new class of chain molecules which we call thick polymers. The concept of the thickness of such a polymer, viewed as a tube, is encapsulated by…

Soft Condensed Matter · Physics 2015-06-25 D. Marenduzzo , A. Flammini , A. Trovato , J. R. Banavar , A. Maritan

Given the wide range of length scales, the analysis of polymer systems often requires coarse-graining, for which various levels of description may be possible depending on the phenomenon under consideration. Here, we provide a super-coarse…

Soft Condensed Matter · Physics 2024-09-05 Naoki Iso , Yuki Norizoe , Takahiro Sakaue

In the presented work we study, by means of numerical simulations, the behaviour of a suspension of active ring polymers in the bulk and under lateral confinement. When changing the separation between the confining planes and the polymers'…

Soft Condensed Matter · Physics 2023-07-31 Juan Pablo Miranda-López , Emanuele Locatelli , Chantal Valeriani

We study the equilibrium behaviour of a mixture of monodisperse hard sphere colloids and polydisperse non-adsorbing polymers at their $\theta$-point, using the Asakura-Oosawa model treated within the free-volume approximation. Our focus is…

Soft Condensed Matter · Physics 2007-05-23 Moreno Fasolo , Peter Sollich

We present Monte Carlo simulations of colloidal particles pulled into grafted polymer layers by external fields. The insertion free energy of a single colloid into the polymer layer is qualitatively different for surfaces with an ordered…

Soft Condensed Matter · Physics 2012-10-17 Tine Curk , Francisco J. Martinez-Veracoechea , Daan Frenkel , Jure Dobnikar

We report an extensive numerical study of a charged colloidal system with competing short-range depletion attraction and long-range electrostatic repulsion. By analizing the cluster properties, we identify two distinct regions in the phase…

Soft Condensed Matter · Physics 2009-03-18 Juan Carlos Fernandez Toledano , Francesco Sciortino , Emanuela Zaccarelli

We discuss structural correlations in mixtures of free polymer and colloidal particles based on a microscopic, 2-component liquid state integral equation theory. Whereas in the case of polymers much smaller than the spherical particles the…

Soft Condensed Matter · Physics 2009-11-07 Matthias Fuchs , Kenneth S. Schweizer

We formulate a density functional theory that describes the phase behavior of hard rods and depleting polymers, as realized in recent experiments on suspensions of \emph{fd} virus and non-adsorbing polymer. The theory predicts the relative…

Soft Condensed Matter · Physics 2015-05-28 Yasheng Yang , Michael F. Hagan

Under high cylindrical confinement, segments of ring polymers can be localized along the long axis of the cylinder by introducing internal loops within the ring polymer. The emergent organization of the polymer segments occurs because of…

Soft Condensed Matter · Physics 2026-04-06 Sanjay Bhandarkar , Debarshi Mitra , Jürgen Horbach , Apratim Chatterji

Large-scale Monte Carlo simulations of a phase-separating colloid-polymer mixture are performed and compared to recent experiments. The approach is based on effective interaction potentials in which the central monomers of self-avoiding…

Soft Condensed Matter · Physics 2007-05-23 R. L. C. Vink , A. Jusufi , J. Dzubiella , C. N. Likos

While the dynamics of polymer chains in equilibrium media is well understood by now, the polymer dynamics in active non-equilibrium environments can be very different. Here we study the dynamics of polymers in a viscous medium containing…

Soft Condensed Matter · Physics 2017-06-23 Jaeoh Shin , Andrey G. Cherstvy , Won Kyu Kim , Vasily Zaburdaev