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We investigate the fine structure of graphene on iridium, which is a model for graphene weakly interacting with a transition metal substrate. Even the highest quality epitaxial graphene displays tiny imperfections, i.e. small biaxial…

Materials Science · Physics 2013-02-25 Nils Blanc , Johann Coraux , Chi Vo-Van , Alpha T. N'Diaye , Olivier Geaymond , Gilles Renaud

While crystalline two-dimensional materials have become an experimental reality during the past few years, an amorphous 2-D material has not been reported before. Here, using electron irradiation we create an sp2-hybridized one-atom-thick…

Materials Science · Physics 2011-03-22 J. Kotakoski , A. V. Krasheninnikov , U. Kaiser , J. C. Meyer

The study of the nanomechanics of graphene $-$ and other 2D materials $-$ has led to the discovery of exciting new properties in 2D crystals, such as their remarkable in-plane stiffness and out of plane flexibility, as well as their unique…

Materials Science · Physics 2019-02-14 Filippo Cellini , Francesco Lavini , Claire Berger , Walt de Heer , Elisa Riedo

Two-dimensional alloys of carbon and nitrogen represent an urgent interest due to prospective applications in nanomechanical and optoelectronic devices. Stability of these chemical structures must be understood as a function of their…

Materials Science · Physics 2015-02-09 Vitaly V. Chaban , Oleg V. Prezhdo

Previous Raman measurements on supported graphene under high pressure reported a very different shift rate of in-plane phonon frequency of graphene (16 cm$^{-1}$GPa$^{-1}$) from graphite (4.7 cm$^{-1}$GPa$^{-1}$), implying very different…

Materials Science · Physics 2019-10-02 Y. W. Sun , W. Liu , I. Hernandez , J. Gonzalez , F. Rodriguez , D. J. Dunstan , C. J. Humphreys

Remote epitaxy has garnered considerable attention as a promising method that facilitates the growth of thin films that replicate the crystallographic characteristics of a substrate by utilizing two-dimensional (2D) material interlayers…

The electronic structure of graphene on Cu(111) and Cu(100) single crystals is investigated using low energy electron microscopy, low energy electron diffraction and angle resolved photoemission spectroscopy. On both substrates the graphene…

Graphene is intrinsically non-flat and corrugates randomly. Since the corrugating physics of atomically-thin graphene is strongly tied to its electronics properties, randomly corrugating morphology of graphene poses significant challenge to…

Mesoscale and Nanoscale Physics · Physics 2011-11-10 Teng Li

Two-dimensional materials are popular in design of nanodevices. To improve bending stiffness of few-layered graphene ribbon, the relative sliding between neighboring layers should be avoided by method such as bonding them together. In this…

Materials Science · Physics 2021-05-26 Jiao Shi , Chunwei Hu , Jiaxing Ji , Bo Song

Atomically thin graphene exhibits fascinating mechanical properties, although its hardness and transverse stiffness are inferior to those of diamond. To date, there hasn't been any practical demonstration of the transformation of…

Here, the possibility of the existence of nitro-graphene derivatives with undisturbed graphene backbone is considered. Based on the first-principles calculation, it is shown that while NO$_2$ is unable to form a covalent bond with bare…

Materials Science · Physics 2020-08-12 Ruslan Yamaletdinov

We study the stability and evolution of various elastic defects in a flat graphene sheet and the electronic properties of the most stable configurations. Two types of dislocations are found to be stable: "glide" dislocations consisting of…

Mesoscale and Nanoscale Physics · Physics 2008-06-19 Ana Carpio , Luis L. Bonilla , Fernando de Juan , María A. H. Vozmediano

We report the results of X-ray spectroscopy and Raman measurements of as-prepared graphene on a high quality copper surface and the same materials after 1.5 years under different conditions (ambient and low humidity). The obtained results…

Polycrystalline graphene has an inherent tendency to buckle, i.e. develop out-of-plane, three-dimensional structure. A force applied to stretch a piece of polycrystalline graphene influences the out-of-plane structure. Even if the graphene…

Materials Science · Physics 2019-10-28 Federico D'Ambrosio , Vladimir Juričić , Gerard T. Barkema

We determine the graphene morphology regulated by substrates with herringbone and checkerboard surface corrugations. As the graphene/substrate interfacial bonding energy and the substrate surface roughness vary, the graphene morphology…

Mesoscale and Nanoscale Physics · Physics 2010-01-08 Teng Li , Zhao Zhang

We report on detailed microscopy studies of graphene and few-layer-graphene produced by mechanical exfoliation on various semi-conducting substrates. We demonstrate the possibility to prepare and analyze graphene on (001)-GaAs, manganese…

Materials Science · Physics 2009-11-13 U. Stöberl , U. Wurstbauer , W. Wegscheider , D. Weiss , J. Eroms

Graphene is a truly two-dimensional atomic crystal with exceptional electronic and mechanical properties. Whereas conventional bulk and thin-film materials have been studied extensively, the key mechanical properties of graphene, such as…

Materials Science · Physics 2010-05-25 Dipanjan Sen , Kostya S. Novoselov , Pedro M. Reis , Markus J. Buehler

Graphene, a thinnest material in the world, can form moire structures on different substrates, including graphite, h-BN, or metal surfaces. In such systems the structure of graphene, i. e. its corrugation, as well as its electronic and…

Mesoscale and Nanoscale Physics · Physics 2016-07-12 Elena Voloshina , Yuriy Dedkov

We demonstrate the growth of graphene nanocrystals by molecular beam methods that employ a solid carbon source, and that can be used on a diverse class of large area dielectric substrates. Characterization by Raman and Near Edge X-ray…

Transmission of low-energetic electrons through two-dimensional materials leads to unique scattering resonances. These resonances contribute to photoemission from occupied bands where they appear as strongly dispersive features of…

Materials Science · Physics 2017-11-22 M. Krivenkov , D. Marchenko , J. Sánchez-Barriga , O. Rader , A. Varykhalov
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