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Silicon has long been synonymous with semiconductor technology. This unique role is due largely to the remarkable properties of the Si-SiO_2 interface, especially the (001)-oriented interface used in most devices. Although Si is crystalline…

Materials Science · Physics 2009-10-31 Yuhai Tu , J. Tersoff

The structural and electronic properties of the LaAlO3/Si(001) interface are determined using state-of-the-art electronic structure calculations. The atomic structure differs from previous proposals, but is reminiscent of La adsorption…

Materials Science · Physics 2016-08-31 Clemens J. Foerst , Karlheinz Schwarz , Peter E. Bloechl

We present first-principles calculations of the structural and electronic properties of Si(001)-SiO2 interfaces. We first arrive at reasonable structures for the c-Si/a-SiO2 interface via a Monte-Carlo simulated annealing applied to an…

Materials Science · Physics 2009-10-31 Kwok-On Ng , David Vanderbilt

The mechanism determining the band alignment of the amorphous/crystalline Si heterostructures is addressed with direct atomistic simulations of the interface performed using a hierarchical combination of various computational schemes…

Materials Science · Physics 2016-08-31 Maria Peressi , Luciano Colombo , Stefano de Gironcoli

We present a first-principles study of the electronic structures and properties of ideal (atomically sharp) LaAlO3/SrTiO3 (001) heterointerfaces and their variants such as a new class of quantum well systems. We demonstrate the…

Materials Science · Physics 2015-05-19 Hanghui Chen , Alexie M. Kolpak , Sohrab Ismail-Beigi

We propose the atomic structures of the 4H-SiC/SiO$_2$ interface for the $a$, $m$, C, and Si faces after NO annealing. Our proposed structures preferentially form at the topmost layers of the SiC side of the interface, which agrees with the…

Materials Science · Physics 2024-01-09 Naoki Komatsu , Mizuho Ohmoto , Mitsuharu Uemoto , Tomoya Ono

The electronic structure of the transparent semiconductor In2O3 has been studied by angle resolved photoemission spectroscopy upon deposition of metallic indium and also tin on the surface of the semiconductor. By deposition of metallic…

Materials Science · Physics 2016-03-02 M. Nazarzahdemoafi , F. Titze , S. Machulik , C. Janowitz , Z. Galazka , R. Manzke , M. Mulazzi

We have successfully demonstrated Si/GaAs p-n heterostructures using Al2O3 ultra-thin oxide interfacial layers. The band diagram and band offsets were investigated using X-ray photoelectron spectroscopy and confirm a small discontinuity in…

Aluminum oxide (Al2O3) has been grown by atomic layer deposition on n-type 4H-SiC with and without a thin silicon dioxide (SiO2) intermediate layer. By means of Capacitance Voltage and Thermal Dielectric Relaxation Current measurements, the…

Materials Science · Physics 2007-05-23 Marc Avice , Ulrike Grossner , Ioana Pintilie , Bengt G. Svensson , Ola Nilsen , Helmer Fjellvag

The two-dimensional electron gas (2DEG) found in KTaO3-based interfaces has garnered attention due to its remarkable electronic properties. In this study, we investigated the conducting system embedded at the Si3N4/Al//KTO(110)…

The band offsets and the chemical bonding at the interfaces between (-201) $\beta$-Ga$_2$O$_3$ and Al$_2$O$_3$ polymorphs are studied through hybrid functional calculations. For alumina, we consider four representative phases, i.e.,…

Materials Science · Physics 2022-09-15 Sai Lyu

Conventional two-dimensional electron gases are realized by engineering the interfaces between semiconducting compounds. In 2004, Ohtomo and Hwang discovered that an electron gas can be also realized at the interface between large gap…

We have constructed microscopic, structurally-relaxed atomistic models of Si/SiO$_2$ superlattices. The structural distortion and oxidation-state characteristics of the interface Si atoms are examined in detail. The role played by the…

Materials Science · Physics 2015-06-24 Pierre Carrier , Laurent J. Lewis , M. W. Chandre Dharma-wardana

Metal-semiconductor contacts are a pillar of modern semiconductor technology. Historically, their microscopic understanding has been hampered by the inability of traditional analytical and numerical methods to fully capture the complex…

Materials Science · Physics 2016-04-13 Daniele Stradi , Umberto Martinez , Anders Blom , Mads Brandbyge , Kurt Stokbro

The ability to follow Moore's Law has been the basis of the tremendous success of the semiconductor industry in the past decades. To date, the greatest challenge for device scaling is the required replacement of silicon dioxide-based gate…

Materials Science · Physics 2007-05-23 Clemens J. Foerst , Christopher R. Ashman , Karlheinz Schwarz , Peter E. Bloechl

Modern electronic devices are unthinkable without the well-controlled formation of interfaces at heterostructures. These often involve at least one amorphous material. Modeling such interfaces poses a significant challenge, since a…

Computational Physics · Physics 2015-06-17 L. E. Hintzsche , C. M. Fang , M. Marsman , M. W. P. E. Lamers , A. W. Weeber , G. Kresse

Motivated by recent electron microscopy studies on the Si3N4/rare-earth oxide interfaces, the atomic and electronic structures of bare beta-Si3N4 surfaces are investigated from first principles. The equilibrium shape of a Si3N4 crystal is…

Materials Science · Physics 2009-11-11 Juan C. Idrobo , Hakim Iddir , Serdar Ogut , Alexander Ziegler , Nigel D. Browning , R. O. Ritchie

Silicon carbide (SiC) is an attractive semiconductor material for applications in power electronic devices. However, fabrication of a high-quality SiC/SiO${}_2$ interface has been a challenge. It is well-known that there is a great…

Materials Science · Physics 2018-05-23 So Takamoto , Takahiro Yamasaki , Takahisa Ohno , Chioko Kaneta , Asuka Hatano , Satoshi Izumi

The LaAlO3/KTaO3 system serves as a prototype to study the electronic properties that emerge as a result of spin-orbit coupling. In this article, we have used first-principles calculations to systematically study two types of defect-free (0…

Materials Science · Physics 2023-08-16 Sanchari Bhattacharya , Sanjoy Datta

We have performed accurate \emph{ab--initio} pseudopotential calculations for the structural and electronic properties of ZnSe/GaAs(001) heterostructures with interface configurations accounting for charge neutrality prescriptions. Beside…

Materials Science · Physics 2011-12-30 A. Stroppa , M. Peressi
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