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Atomically precise graphene nanoribbons are a promising emerging class of designer quantum materials with electronic properties that are tunable by chemical design. However, many challenges remain in the device integration of these…

It is known that there is a wide class of quasi-two-dimensional graphenelike nanomaterials which in many respects can outperform graphene. So, here in addition to graphene, the attention is directed to stanene (buckled honeycomb structure)…

Mesoscale and Nanoscale Physics · Physics 2019-10-02 S. Krompiewski

We study edge state magnetism in graphene nanostructures using a mean field theory of the Hubbard model. We investigate how the magnetism of the zigzag edges of graphene is affected by the presence of other types of terminating edges and…

Mesoscale and Nanoscale Physics · Physics 2008-07-04 Somnath Bhowmick , Vijay B. Shenoy

On the basis of first principles calculations, we report energy estimated to cut a graphene sheet into nanoribbons of armchair and zigzag configurations. Our calculations show that the energy required to cut a graphene sheet into zigzag…

Mesoscale and Nanoscale Physics · Physics 2013-09-12 Deepika , T. J. Dhilip Kumar , Rakesh Kumar

We study the effect of transversal electric-field (E-field) on the electronic properties of multilayer armchair-graphene-nanoribbon (AGNR). The bandgap in multilayer-AGNRs can be reversibly modulated with the application of E-field. At…

Mesoscale and Nanoscale Physics · Physics 2011-07-29 S. Bala kumar , Jing Guoa

In this paper, we apply the first-principle theory to explore how the electronic structures of armchair graphene nanoribbons (AGNRs) are affected by chemical modifications. The edge addends include H, F, N, NH$_{2}$, and NO$_{2}$. Our…

Materials Science · Physics 2007-11-13 Hao Ren , Qunxiang Li , Haibin Su , Q. W. Shi , Jie Chen , Jinlong Yang

Based on first-principles density-functional theory calculations, we present a comparative study of the elec- tronic structures of ultranarrow zigzag graphene nanoribbons (ZGNRs) embedded in hexagonal boron nitride (BN) sheet and fully…

Mesoscale and Nanoscale Physics · Physics 2015-08-05 Sun-Woo Kim , Hyun-Jung Kim , Jin-Ho Choi , Ralph H. Scheicher , Jun-Hyung Cho

We theoretically investigate the thermoelectric properties of zigzag graphene nanoribbons in the presence of extended line defects, substrate impurities and edge roughness along the nanoribbon's length. A nearest-neighbor tight-binding…

Materials Science · Physics 2012-03-12 Hossein Karamitaheri , Neophytos Neophytou , Mahdi Pourfath , Rahim Faez , Hans Kosina

We investigate, in the framework of macroscopic Dirac model, the spectrum, charge density and conductivity of metallic armchair graphene nanoribbons in presence of different mass terms. We reveal the conditions and symmetries governing the…

Mesoscale and Nanoscale Physics · Physics 2018-04-11 C. G. Beneventano , I. V. Fialkovsky , M. Nieto , E. M. Santangelo

Hydrogenated graphene, graphane, is studied on oxygen-terminated silicon dioxide substrate using ab initio calculations. A structure with hydrogenation only on one side of the graphene layer is found stable and its hydrogen configurations…

Mesoscale and Nanoscale Physics · Physics 2011-07-13 M. Ijäs , P. Havu , A. Harju , P. Pasanen

We use a simple tight-binding (TB) model to study electronic properties of free graphene flakes. Valence electrons of triangular graphene flakes show a shell and supershell structure which follows an analytical expression derived from the…

Atomic and Molecular Clusters · Physics 2009-11-13 M. Manninen , H. P. Heiskanen , J. Akola

Among their amazing properties, graphene and related low-dimensional materials show quantized charge-density fluctuations--known as plasmons--when exposed to photons or electrons of suitable energies. Graphene nanoribbons offer an enhanced…

Strongly Correlated Electrons · Physics 2016-09-14 Cristian Vacacela Gomes , Michele Pisarra , Mario Gravina , Jose M. Pitarke , Antonello Sindona

We investigated theoretically the effect of covalent edge functionalization, with organic functional groups, on the electronic properties of graphene nanostructures and nano-junctions. Our analysis shows that functionalization can be…

Materials Science · Physics 2012-03-30 Caterina Cocchi , Alice Ruini , Deborah Prezzi , Marilia J. Caldas , Elisa Molinari

Realizing magnetism in graphene/carbon nanostructures is a decade-long challenge. The magnetic edge state and half metallicity in zigzag graphene nanoribbons are particularly promising [Y.-W. Son, et al., Nature 444, 347 (2006)]. However,…

Mesoscale and Nanoscale Physics · Physics 2018-12-05 Shiyuan Gao , Li Yang

With advanced synthetic techniques, a wide variety of well-defined graphene nano-ribbons (GNRs) can be produced with atomic precision. Hence, finding the relation between their structures and properties becomes important for the rational…

In recent years there has been significant debate on whether the edge type of graphene nanoflakes (GNF) or graphene quantum dots (GQD) are relevant for their electronic structure, thermal stability and optical properties. Using computer…

Mesoscale and Nanoscale Physics · Physics 2016-06-15 Candela Mansilla Wettstein , Franco P. Bonafé , M. Belén Oviedo , Cristián G. Sánchez

We consider plane junctions with graphene electrodes, which are formed by a single-level system ("molecule") placed between the edges of two single-layer graphene half planes. We calculate the edge Green functions of the electrodes and the…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 Dmitry A. Ryndyk , Jan Bundesmann , Ming-Hao Liu , Klaus Richter

Based on atomistic simulations, the nonlinear elastic properties of monolayer graphene nanoribbons under quasistatic uniaxial tension are predicted, emphasizing the effect of edge structures (armchair and zigzag, without and with hydrogen…

Mesoscale and Nanoscale Physics · Physics 2010-07-21 Qiang Lu , Rui Huang

Using a density functional theory based electronic structure method and semi-local density approximation, we study the interplay of geometric confinement, magnetism and external electric fields on the electronic structure and the resulting…

Materials Science · Physics 2015-05-27 Bhagawan Sahu , Hongki Min , Sanjay K. Banerjee

Serving as a new two-dimensional plasmonic material, graphene has stimulated an intensive study of its optical properties which benefit from the unique electronic band structure of the underlying honeycomb lattice of carbon atoms. In…

Mesoscale and Nanoscale Physics · Physics 2015-03-18 Weihua Wang , Thomas Christensen , Antti-Pekka Jauho , Kristian S. Thygesen , Martijn Wubs , N. Asger Mortensen