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We present first-principles calculations of many-electron effects on the optical response of graphene, bilayer graphene, and graphite employing the GW-Bethe Salpeter equation approach. We find that resonant excitons are formed in these…

Materials Science · Physics 2009-10-31 Li Yang , Jack Deslippe , Cheol-Hwan Park , Marvin L. Cohen , Steven G. Louie

Using a combination of ultraviolet-vacuum ultraviolet reflectivity and spectroscopic ellipsometry, we observe a resonant exciton at an unusually high energy of 6.3eV in epitaxial graphene. Surprisingly, the resonant exciton occurs at room…

Significant excitonic effects were observed in graphene by measuring its optical conductivity in a broad spectral range including the two-dimensional {\pi}-band saddle-point singularities in the electronic structure. The strong…

Materials Science · Physics 2015-05-20 Kin Fai Mak , Jie Shan , Tony F. Heinz

We study the effect of electron-electron interactions in the optical conductivity of graphene under applied bias and derive a generalization of Elliot's formula, commonly used for semiconductors, for the optical intensity. We show that {\it…

Mesoscale and Nanoscale Physics · Physics 2010-07-29 N. M. R. Peres , R. M. Ribeiro , A. H. Castro Neto

Biased bilayer graphene, with its easily tunable band gap, presents itself as the ideal system to explore the excitonic effect in graphene based systems. In this paper we study the excitonic optical response of such a system by combining a…

Mesoscale and Nanoscale Physics · Physics 2022-01-20 J. C. G. Henriques , Itai Epstein , N. M. R. Peres

We have performed first-principles calculations to study optical absorption spectra of doped graphene with many-electron effects included. Both self-energy corrections and electron-hole interactions are reduced due to the enhanced screening…

Mesoscale and Nanoscale Physics · Physics 2011-09-09 Li Yang

By employing the first-principles GW-Bethe-Salpeter Equation (BSE) simulation, we obtain, for the first time, the accurate quasiparticle (QP) band gap, optical absorption spectra and their dependence on the gate field of gated bilayer…

Mesoscale and Nanoscale Physics · Physics 2015-06-11 Yufeng Liang , Li Yang

In this work we perform electron energy-loss spectroscopy (EELS) of freestanding graphene with high energy and momentum resolution to disentangle the quasielastic scattering from the excitation gap of Dirac electrons close to the optical…

We develop an ab initio framework that captures the impact of electron-electron and electron-hole interactions on phonon properties. This enables the inclusion of excitonic effects in the optical phonon dispersions and lifetimes of…

Materials Science · Physics 2025-06-17 Alberto Guandalini , Francesco Macheda , Giovanni Caldarelli , Francesco Mauri

The optical properties of graphene are strongly affected by electron-electron (e-e) and electron-hole (e-h) interactions. Here we tune these many-body interactions through varying the density of free charge carriers. Measurements from the…

We compare first-principle band gaps and optical absorption spectra of single- and double-layer fluorographene with bulk graphite fluoride. The electronic properties are calculated using the many-body GW approximation and the optical…

Materials Science · Physics 2014-10-24 František Karlický , Michal Otyepka

Using first principles many-body theory methods (GW+BSE) we demonstrate that optical properties of graphane are dominated by localized charge-transfer excitations governed by enhanced electron correlations in a two-dimensional dielectric…

Materials Science · Physics 2015-05-18 Pierluigi Cudazzo , Claudio Attacalite , Ilya V. Tokatly , Angel Rubio

The exciton Wannier equation for graphene is solved for different background dielectric constants. It is shown that freestanding graphene features strong Coulomb effects with a very large exciton binding energy exceeding $3\,$eV. A…

Materials Science · Physics 2011-07-29 J. H. Grönqvist , T. Stroucken , G. Berghäuser , S. W. Koch

We employ the first-principles GW+Bethe Salpeter equation approach to study the electronic structure and optical absorption spectra of uniaxial strained graphene with many-electron effects included. Applied strain not only induces an…

Materials Science · Physics 2015-05-30 Yufeng Liang , Shouting Huang , Li Yang

We suggest that physics underlying the recently observed removal of sublattice and spin degeneracies in graphene in a strong magnetic field describes a phase transition connected with the generation of an excitonic gap. The experimental…

Strongly Correlated Electrons · Physics 2008-11-26 V. P. Gusynin , V. A. Miransky , S. G. Sharapov , I. A. Shovkovy

Biased bilayer graphene (BBG) is a variable band gap semiconductor, with a strongly field-dependent band gap of up to $300 \, \text{meV}$, making it of particular interest for graphene-based nano-electronic and -photonic devices. The…

Mesoscale and Nanoscale Physics · Physics 2022-03-21 Mikkel Ohm Sauer , Thomas Garm Pedersen

Recent measurements have shown that a continuously tunable bandgap of up to 250 meV can be generated in biased bilayer graphene [Y. Zhang et al., Nature 459, 820 (2009)], opening up pathway for possible graphene-based nanoelectronic and…

Materials Science · Physics 2010-02-11 Cheol-Hwan Park , Steven G. Louie

Bilayer graphene is normally a semimetal with parabolic dispersion, but a tunable bandgap up to few hundreds meV can be opened by breaking the symmetry between the layers through an external potential. Ab-initio calculations show that the…

Mesoscale and Nanoscale Physics · Physics 2015-09-30 Simone De Liberato

We consider the optical properties of the half-filled AB-stacked bilayer graphene with the excitonic pairing and condensation between the layers. Both intra and interlayer local Coulomb interaction effects have been taken into account and…

Mesoscale and Nanoscale Physics · Physics 2021-12-15 V. Apinyan , T. K. Kopec

We present a theory of excitonic processes in gate controlled graphene quantum dots. The dependence of the energy gap on shape, size and edge for graphene quantum dots with up to a million atoms is predicted. Using a combination of…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 A. D. Guclu , P. Potasz , P. Hawrylak
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