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We have examined an isovalent Rh substitution effect on the transport properties of the thermoelectric oxide Ca$_3$Co$_{4}$O$_9$ using single-crystalline form. With increasing Rh content $x$, both the electrical resistivity and the Seebeck…

Strongly Correlated Electrons · Physics 2016-06-10 Yusuke Ikeda , Kengo Saito , Ryuji Okazaki

Polycrystalline Sb 2 Te 3-x Se x (0.0 < x < 1.0) samples were synthesized by the solid state reaction method. The structural analysis showed that up to the maximal concentration of Se, the samples possess the Rhombohedral crystal symmetry…

The presence of complexity in the electronic structure of strongly correlated electron system NdCoO$_3$ (NCO) have sparked interest in the investigation of its physical properties. Here, we study the the Seebeck coefficient ($\alpha $) of…

Materials Science · Physics 2023-12-19 Abhishek Pandey , Sudhir K. Pandey

An asymmetry as a function of the direction of current flow is observed in the current-voltage characteristic (CVC) and its first and second derivatives for point heterocontacts between pure metals {Cu, Ni, Fe) as well as between these…

Mesoscale and Nanoscale Physics · Physics 2013-06-19 Yu. G. Naidyuk , N. N. Gribov , O. I. Shklyarevskii , A. G. M. Jansen , I. K. Yanson

We study the Seebeck effect in the $\tau$-type organic conductors, $\tau$-(EDO-$S$,$S$-DMEDT-TTF)$_{2}$(AuBr$_{2}$)$_{1+y}$ and $\tau$-(P-$S$,$S$-DMEDT-TTF)$_{2}$(AuBr$_{2}$)$_{1+y}$, where EDO-$S$,$S$-DMEDT-TTF and P-$S$,$S$-DMEDT-TTF are…

Thermoelectric effects, measured by the Seebeck coefficients, refer to the phenomena in which a temperature difference or gradient imposed across a thermoelectric material induces an electrical potential difference or gradient, and vice…

Materials Science · Physics 2018-12-05 Yi Wang , Yong-Jie Hu , Shun-Li Shang , Bi-Cheng Zhou , Zi-Kui Liu , Long-Qing Chen

Thermoelectric (TE) materials seamlessly convert thermal into electrical energy and vice versa, making them promising for applications such as power generation or cooling. Although historically the TE effect was first discovered in metals,…

Search of new thermoelectric (TE) materials with high \textit{figure-of-merit} (ZT) is always inspired the researcher in TE field. Here, we present a combined experimental and theoretical study of TE properties of Na$_{0.74}$CoO$_{2}$…

Materials Science · Physics 2020-08-26 Shamim Sk , Jayashree Pati , R. S. Dhaka , Sudhir K. Pandey

The temperature dependence of the Seebeck coefficient of homoepitaxial metal organic vapor phase (MOVPE) grown, silicon doped $\beta$-Ga$_2$O$_3$ thin films was measured relative to aluminum. For room temperature we found the relative…

The goal of this work is studying the evolution of thermoelectric transport across the members of the Ruddlesden-Popper series iridates Srn+1IrnO3n+1, where a metal-insulator transition driven by bandwidth change occurs, from the strongly…

Strongly Correlated Electrons · Physics 2016-01-22 I. Pallecchi , M. T. Buscaglia , V. Buscaglia , E. Gilioli , G. Lamura , F. Telesio , M. R. Cimberle , D. Marre'

We prepared polycrystalline samples of R$_2$PdO$_4$ (R = La, Nd, Sm and Gd) using a NaCl-flux technique. The measured resistivity is of the order of 10$^3-10^4$ $\Omega$cm at room temperature, which is two orders of magnitude smaller than…

Strongly Correlated Electrons · Physics 2009-11-11 S. Shibasaki , I. Terasaki

The thermoelectric and transport properties of a Fe3O4/SiO2/p-Si(100) heterostructure have been investigated between 100 and 300 K. Both Hall and Seebeck coefficients change sign from negative to positive with increasing temperature while…

Materials Science · Physics 2015-06-19 Z. Viskadourakis , M. L. Paramês , O. Conde , M. Zervos , J. Giapintzakis

The layered misfit cobaltate Ca$_3$Co$_4$O$_9$, also known as Ca$_2$CoO$_3$[CoO$_2$]$_{1.62}$, is a promising p-type thermoelectric oxide. Employing density functional theory, we study its electronic structure and determine, on the basis of…

Materials Science · Physics 2017-06-13 Bin Amin , Ulrich Eckern , Udo Schwingenschlögl

Thermoelectric properties of the layered cobalt oxide system LixCoO2 were investigated in a wide range of Li composition, 0.98 >= x >= 0.35. Single-phase bulk samples of LixCoO2 were successfully obtained through electrochemical…

Strongly Correlated Electrons · Physics 2011-05-25 T. Motohashi , Y. Sugimoto , Y. Masubuchi , T. Sasagawa , W. Koshibae , T. Tohyama , H. Yamauchi , S. Kikkawa

Temperature dependence of relaxation dynamics of UX$_{3}$ (X = Al, Ga, Sn) compounds is studied using time resolved pump-probe technique in the reflectance geometry. UGa$_{3}$ is an itinerant antiferromagnet, while UAl$_{3}$ and USn$_{3}$…

Strongly Correlated Electrons · Physics 2015-06-05 Saritha K. Nair , J. -X. Zhu , J. L. Sarrao , A. J. Taylor , Elbert E. M. Chia

A simple apparatus for the measurement of Seebeck coefficient ($\alpha$) in the temperature range 300-620 K has been fabricated. Our design is appropriate for the characterization of samples with different geometries like disk and rod…

Instrumentation and Detectors · Physics 2017-04-25 Saurabh Singh , Sudhir K. Pandey

At the ultra-thin film limit, quantum confinement strongly improves thermoelectric figure of merit in materials such as Sb$_2$Te$_3$ and Bi$_2$Te$_3$. These high quality films have only been realized using well controlled techniques such as…

Mesoscopic transport measurements are underexplored as probes of quasiparticles and their properties in correlated metals. The mixed valence compound YbAl$_3$ exhibits a single-ion Kondo temperature of 670 K, while thermodynamic and…

High-performance thermoelectric oxides could offer a great energy solution for integrated and embedded applications in sensing and electronics industries. Oxides, however, often suffer from low Seebeck coefficient when compared with other…

Materials Science · Physics 2020-08-25 M. Hussein N. Assadi , J. Julio Gutiérrez Moreno , Marco Fronzi

Magnetic dc susceptibility between 1.5 and 800 K, ac susceptibility and magnetization, thermodynamic properties, temperature dependence of radio and audio-wave dielectric constants and conductivity, contact-free dielectric constants at…

Materials Science · Physics 2010-07-22 Jun Lu , A. Günther , F. Schrettle , F. Mayr , S. Krohns , P. Lunkenheimer , A. Pimenov , V. D. Travkin , A. A. Mukhin , A. Loidl