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We use spin-density functional theory to obtain novel expressions for the charge and spin local-field factors of an electron gas in terms of its electron-pair structure factors. These expressions (i) satisfy the compressibility and spin…

Strongly Correlated Electrons · Physics 2009-11-07 B. Davoudi , M. Polini , M. P. Tosi

In this paper we present a new approach how to extract polarization-dependent exchange-correlation energy densities for two-dimensional systems from reference densities and energies of quantum dots provided by exact diagonalization.…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Andreas Wensauer , Ulrich Rössler

We discuss a general form of the exchange energy for a homogeneous system of interacting electrons in two spatial dimensions which is particularly suited in the presence of a generic spin-orbit interaction. The theory is best formulated in…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 S. Chesi , G. F. Giuliani

The uniform electron gas and the hydrogen atom play fundamental roles in condensed matter physics and quantum chemistry. The former has an infinite number of electrons uniformly distributed over the neutralizing positively-charged…

Chemical Physics · Physics 2016-06-22 Jianwei Sun , John P. Perdew , Zenghui Yang , Haowei Peng

The exchange and correlation $E_{xc}$ of strongly correlated electrons in 2D layers of finite width are studied as a function of the density parameter $r_s$, spin-polarization $\zeta$ and the temperature $T$. We explicitly treat…

Strongly Correlated Electrons · Physics 2009-11-11 M. W. C. Dharma-wardana

Quantum rings can be characterized by a specific radius and ring width. For this rich class of physical systems, an accurate approximation for the exchange-hole potential and thus for the exchange energy is derived from first principles.…

Strongly Correlated Electrons · Physics 2009-02-04 E. Rasanen , S. Pittalis , C. R. Proetto , E. K. U. Gross

Recent progress in the formulation of a fully dynamical local approximation to time-dependent Density Functional Theory appeals to the longitudinal and transverse components of the exchange and correlation kernel in the linear…

Condensed Matter · Physics 2008-12-18 R. Nifosi' , S. Conti , M. P. Tosi

We calculate the correlation energy of a two-dimensional homogeneous electron gas using several available approximations for the exchange-correlation kernel $f_{\rm xc}(q,\omega)$ entering the linear dielectric response of the system. As in…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 R. Asgari , M. Polini , B. Davoudi , M. P. Tosi

The one-particle Green function of a many-electron system is traditionally formulated within the self-energy picture. A different formalism was recently proposed, in which the self-energy is replaced by a dynamical exchange-correlation…

Strongly Correlated Electrons · Physics 2025-05-27 F. Aryasetiawan

In this chapter, we provide a review of ground-state Kohn-Sham density-functional theory of electronic systems and some of its extensions, we present exact expressions and constraints for the exchange and correlation density functionals,…

Chemical Physics · Physics 2022-09-12 Julien Toulouse

Based on its known exact properties and a new set of extensive fixed-node reptation quantum Monte Carlo simulations (both with and without backflow correlations, which in this case turn out to yield negligible improvements), we propose a…

Strongly Correlated Electrons · Physics 2009-11-10 Paola Gori-Giorgi , Saverio Moroni , Giovanni B. Bachelet

We present here novel insight into exchange-correlation functionals in density functional theory, based on the viewpoint of optimal transport. We show that in the case of two electrons and in the semiclassical limit, the exact…

Analysis of PDEs · Mathematics 2015-03-19 Codina Cotar , Gero Friesecke , Claudia Klüppelberg

Spin is a fundamental property of any many-electron system. The ability of density functional theory to accurately predict the physical properties of a system, while varying its spin, is crucial for describing magnetic materials and…

Chemical Physics · Physics 2024-11-05 Alon Hayman , Eli Kraisler , Tamar Stein

We investigate the behavior of three-dimensional (3D) exchange-correlation energy functional approximations of density functional theory in anisotropic systems with two-dimensional (2D) character. Using two simple models, quasi-2D electron…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Yong-Hoon Kim , In-Ho Lee , Satyadev Nagaraja , Jean-Pierre Leburton , Randolph Q. Hood , Richard M. Martin

An exchange energy functional is proposed and tested for obtaining a class of excited-state energies using density-functional formalism. The functional is the excited-state counterpart of the local-density approximation functional for the…

Other Condensed Matter · Physics 2007-05-23 Prasanjit Samal , Manoj K. Harbola

Motivated by the considerable importance of material properties in modern condensed matter physics research, and using techniques of the $N_{e}$ -electron systems in terms of the electron density $n_{\sigma e}\left( r\right) $ needed to…

Materials Science · Physics 2024-07-19 A. Belhaj , S. E. Ennadifi

Commonly used semilocal density functional approximations for the exchange-correlation energy fail badly when the true two dimensional limit is approached. We show, using a quasi-two-dimensional uniform electron gas in the infinite barrier…

Materials Science · Physics 2015-05-13 Lucian A. Constantin

An exchange energy functional is proposed and tested for obtaining a class of excited-state energies using density functional formalism. The functional is the excited-state counterpart of the local-density approximation functional for the…

Materials Science · Physics 2007-05-23 Prasanjit Samal , Manoj K. Harbola

We analyze the effective electron-electron interaction in a two dimensional polarized paramagnetic system. The spin degree of freedom, s, is manifestly present in the expressions of spin dependent local field factors that describe the short…

Strongly Correlated Electrons · Physics 2007-05-23 Juana Moreno , D. C. Marinescu

We prove that, in the large-dimension limit, the high-density correlation energy $\Ec$ of two opposite-spin electrons confined in a $D$-dimensional space and interacting {\em via} a Coulomb potential is given by $\Ec \sim -1/(8D^2)$ for any…

Strongly Correlated Electrons · Physics 2015-03-17 Pierre-François Loos , Peter M. W. Gill