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We derive Edgeworth expansions that describe corrections to the Gaussian limiting behaviour of slow-fast systems. The Edgeworth expansion is achieved using a semi-group formalism for the transfer operator, where a Duhamel-Dyson series is…

Chaotic Dynamics · Physics 2019-02-05 Jeroen Wouters , Georg A. Gottwald

Time-dependent density functional theory has emerged as a method of choice for calculations of spectra and response properties in physics, chemistry, and biology, with its system-size scaling enabling computations on systems much larger…

Chemical Physics · Physics 2021-07-13 Neepa T. Maitra

We apply the point form of relativistic quantum mechanics to develop a Poincare invariant coupled-channel formalism for two-particle systems interacting via one-particle exchange. This approach takes the exchange particle explicitly into…

Nuclear Theory · Physics 2009-11-10 A. Krassnigg , W. Schweiger , W. H. Klink

We generalize the recently introduced single-boson exchange formalism to nonlocal interactions. In the functional renormalization group application to the extended Hubbard model in two dimensions, we show that the flow of the rest function…

Strongly Correlated Electrons · Physics 2024-12-11 Aiman Al-Eryani , Sarah Heinzelmann , Kilian Fraboulet , Friedrich Krien , Sabine Andergassen

We provide a rationale for a new class of double-hybrid approximations introduced by Br\'emond and Adamo [J. Chem. Phys. 135, 024106 (2011)] which combine an exchange-correlation density functional with Hartree-Fock exchange weighted by…

Chemical Physics · Physics 2015-05-30 Julien Toulouse , Kamal Sharkas , Eric Brémond , Carlo Adamo

This paper continues the investigation of the exponentially repulsive EXP pair-potential system of Paper I with a focus on isomorphs in the low-temperature gas and liquid phases. As expected from the EXP system's strong virial…

Soft Condensed Matter · Physics 2018-09-20 Andreas Kvist Bacher , Thomas B. Schrøder , Jeppe C. Dyre

Correlated quantum many-particle systems out of equilibrium are of high interest in many fields, including correlated solids, ultracold atoms or dense plasmas. Accurate theoretical description of these systems is challenging both,…

Strongly Correlated Electrons · Physics 2026-04-02 Erik Schroedter , Michael Bonitz

A semi-relativistic density-functional theory that includes spin-orbit couplings and Zeeman fields on equal footing with the electromagnetic potentials, is an appealing framework to develop a unified first-principles computational approach…

Materials Science · Physics 2017-09-13 S. Pittalis , G. Vignale , F. G. Eich

We consider the parity-violating two-pion-exchange potential obtained from the covariant formalism in the past and the state-of-the-art effective field theory approach. We discuss the behavior of the potential in coordinate space and its…

Nuclear Theory · Physics 2009-01-30 C. H. Hyun , B. Desplanques , S. Ando , C. -P. Liu

The performance of density functional theory depends largely on the approximation applied for the exchange functional. We propose here a novel screened exchange potential for semiconductors, with parameters based on the physical properties…

Materials Science · Physics 2021-01-04 Michael Lorke , Peter Deák , Thomas Frauenheim

We consider the extended Hubbard model and introduce a corresponding Heisenberg-like problem written in terms of spin operators. The derived formalism is reminiscent of Anderson's idea of the effective exchange interaction and takes into…

Strongly Correlated Electrons · Physics 2018-07-25 E. A. Stepanov , S. Brener , F. Krien , M. Harland , A. I. Lichtenstein , M. I. Katsnelson

We propose an extension of quasi-Newton methods, and investigate the convergence and the robustness properties of the proposed update formulae for the approximate Hessian matrix. Fletcher has studied a variational problem which derives the…

Computation · Statistics 2010-10-15 Takafumi Kanamori , Atsumi Ohara

A decomposition of the exact exchange-correlation potential of time-dependent density functional theory into an interaction component and a kinetic component offers a new starting point for non- adiabatic approximations. The components are…

Chemical Physics · Physics 2018-11-14 Johanna I. Fuks , Lionel Lacombe , Soeren E. B. Nielsen , Neepa T. Maitra

Previous studies have used numerical methods to optimize the hyperpolarizability of a one-dimensional quantum system. These studies were used to suggest properties of one-dimensional organic molecules, such as the degree of modulation of…

Optics · Physics 2015-05-18 Urszula B. Szafruga , Mark G. Kuzyk , David S. Watkins

New density functional theory approach based on a complete active space self-consistent field (CASSCF) reference function in Extended Koopmans' approximation is discussed. Recently, the number of generalizations of density functional theory…

Chemical Physics · Physics 2018-02-15 Sergey Gusarov , Yurii Dmitriev

The aim of this paper is to discuss both higher-order asymptotic expansions and skewed approximations for the Bayesian Discrepancy Measure for testing precise statistical hypotheses. In particular, we derive results on third-order…

Methodology · Statistics 2025-05-02 Elena Bortolato , Francesco Bertolino , Monica Musio , Laura Ventura

We compute the corrections from two-photon and photon-Z exchange in parity-violating elastic electron-proton scattering, used to extract the strange form factors of the proton. We use a hadronic formalism that successfully reconciled the…

Nuclear Theory · Physics 2014-11-18 J. A. Tjon , W. Melnitchouk

Accounting for dispersion interactions is essential in approximate density functional theory (DFT). Often, a correction potential based on the London formula is added, which is damped at short distances to avoid divergence and double…

Chemical Physics · Physics 2025-06-26 K. Nikolas Lausch , Redouan El Haouari , Daniel Trzewik , Jörg Behler

We have trapped a gas of long-lifetime, high-mobility excitons in an in-plane harmonic potential. Trapping is an important step toward the goal of a controlled Bose-Einstein condensate of excitons. We show that the repulsive interaction…

Strongly Correlated Electrons · Physics 2007-05-23 Z. Vörös , D. W. Snoke , L. Pfeiffer , K. West

This paper develops an extension of infinite-dimensional backstepping method for parabolic and hyperbolic systems in one spatial dimension with two actuators. Typically, PDE backstepping is applied in 1-D domains with an actuator at one…

Optimization and Control · Mathematics 2016-03-17 Rafael Vazquez , Miroslav Krstic