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Theoretical approaches are formulated to investigate the molecular mobility under various cooling rates of amorphous drugs. We describe the structural relaxation of a tagged molecule as a coupled process of cage-scale dynamics and…

Soft Condensed Matter · Physics 2019-12-10 Anh D. Phan , Katsunori Wakabayashi , Marian Paluch , Vu D. Lam

We discuss the relaxation dynamics of a simple lattice gas model for glass-forming systems and show that with increasing density of particles this dynamics slows down very quickly. By monitoring the trajectory of tagged particles we find…

Soft Condensed Matter · Physics 2010-05-07 Pinaki Chaudhuri , Ludovic Berthier , Srikanth Sastry , Walter Kob

Particle rafts floating at an air-liquid interface exhibit a variety of behaviors when interfacial flow is introduced. Motivated by previous experimental observations, the failure pattern of particle rafts under uniform radial expansion is…

Soft Condensed Matter · Physics 2023-08-16 Khá-Î Tô

The enhancement of mobility at the surface of an amorphous alloy is studied using a combination of molecular dynamic simulations and normal mode analysis of the non-uniform distribution of Debye-Waller factors. The increased mobility at the…

Soft Condensed Matter · Physics 2017-12-20 Gang Sun , Shibu Saw , Ian Douglass , Peter Harrowell

A new class of lattice gas models with trivial interactions but constrained dynamics are introduced. These are proven to exhibit a dynamical glass transition: above a critical density, rho_c, ergodicity is broken due to the appearance of an…

Statistical Mechanics · Physics 2009-11-11 Cristina Toninelli , Giulio Biroli , Daniel S. Fisher

We investigate the non-equilibrium relaxation dynamics of a one dimensional system of interacting spinless fermions near the XXZ integrable point. We observe two qualitatively different regimes: close to integrability and for low energies…

Quantum Gases · Physics 2015-03-10 Nicolas Nessi , Aníbal Iucci

We consider a model fluid with long-ranged, dispersion interparticle potentials confined between competing parallel walls. One wall is solvophilic and would be completely wet at bulk liquid-gas coexistence while the other is solvophobic and…

Soft Condensed Matter · Physics 2015-06-05 M. C. Stewart , R. Evans

We show that the density and temperature dependences of the $\alpha$-relaxation time of several glassforming polymers can be described through a single scaling variable $X=e(\rho)/T$, where $e(\rho)$ is well fitted by a power law $\rho^x$,…

Soft Condensed Matter · Physics 2009-11-10 C. Alba-Simionesco , A. Cailliaux , A. Alegria , G. Tarjus

Within the mode-coupling theory for ideal glass transitions, an analysis for the correlation functions of glass-forming systems for states near higher-order glass-transition singularities is presented. It is shown that the solutions of the…

Soft Condensed Matter · Physics 2007-05-23 W. Gotze , M. Sperl

A Lagrangian fluctuation-dissipation relation has been derived in a previous work to describe the dissipation rate of advected scalars, both passive and active, in wall-bounded flows. We apply this relation here to develop a Lagrangian…

Fluid Dynamics · Physics 2018-03-15 Gregory L. Eyink , Theodore D. Drivas

Amorphous solids or glasses are known to exhibit stretched-exponential decay over broad time intervals in several of their macroscopic observables: intermediate scattering function, dielectric relaxation modulus, time-elastic modulus etc.…

Soft Condensed Matter · Physics 2017-01-19 B. Cui , R. Milkus , A. Zaccone

Microscopic relaxation timescales are estimated from the autocorrelation functions obtained by dynamic light scattering experiments for Laponite suspensions with different concentrations ($C_{L}$), added salt concentrations ($C_{S}$) and…

Soft Condensed Matter · Physics 2016-01-20 Debasish Saha , Yogesh M. Joshi , Ranjini Bandyopadhyay

We study the growing time scales and length scales associated with dynamical slow down for a realistic glass former, using computer simulations. We perform finite size scaling to evaluate a length scale associated with dynamical…

Statistical Mechanics · Physics 2009-11-13 Smarajit Karmakar , Chandan Dasgupta , Srikanth Sastry

The aging dynamics of a colloidal glass has been studied by multiangle Dynamic Light Scattering, Neutron Spin Echo, X-ray Photon Correlation Spectroscopy and Molecular Dynamics simulations. The two relaxation processes, microscopic (fast)…

In the realm of nanoscience, the dynamic behaviors of liquids at scales beyond the conventional structural relaxation time, $\tau$, unfold a fascinating blend of solid-like characteristics, including the propagation of collective shear…

Soft Condensed Matter · Physics 2024-09-11 Yuanxi Yu , Sha Jin , Xue Fan , Mona Sarter , Dehong Yu , Liang Hong , Matteo Baggioli

A new master equation to mimic the dynamics of a collection of interacting random walkers in an open system is proposed and solved numerically.In this model, the random walkers interact through excluded volume interaction (single-file…

Soft Condensed Matter · Physics 2007-05-23 Prasanth P Jose , Biman Bagchi

We use computer simulations to study the microscopic dynamics of an athermal assembly of soft particles near the fluid-to-solid, jamming transition. Borrowing tools developed to study dynamic heterogeneity near glass transitions, we…

Materials Science · Physics 2010-06-24 Claus Heussinger , Ludovic Berthier , Jean-Louis Barrat

Understanding dynamical facilitation in nonequilibrium glass-forming systems driven by active forces remains an open challenge. In particular, it is unclear whether facilitation survives in active glasses, where persistent self-propulsion…

Soft Condensed Matter · Physics 2026-04-14 Dipanwita Ghoshal

The earlier paper of this same title demonstrated a collapse of relaxation data of fragile supercooled glass forming liquids [\textit{J. Phys. Chem. B} \textbf{113}, 5563-5567 (2009)]. For temperature $T$ below that of the onset to…

Statistical Mechanics · Physics 2014-07-31 Yael S. Elmatad , David Chandler , Juan P. Garrahan

We perform extensive molecular dynamics simulations of dense liquids composed of bidisperse dimer- and ellipse-shaped particles in 2D that interact via repulsive contact forces. We measure the structural relaxation times obtained from the…

Soft Condensed Matter · Physics 2015-06-05 Tianqi Shen , Carl Schreck , Bulbul Chakraborty , Denise E. Freed , Corey S. O'Hern