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Within the mode-coupling theory (MCT) for the evolution of structural relaxation in glass-forming liquids, correlation functions and susceptibility spectra are calculated characterizing the rotational dynamics of a top-down symmetric…

Soft Condensed Matter · Physics 2015-06-24 W. Gotze , A. P. Singh , Th. Voigtmann

Previous studies have suggested a conundrum in the relaxation dynamics of polydisperse supercooled liquids. It has been shown that in two dimensions, the relative relaxation times of particles of different sizes become more similar as the…

Soft Condensed Matter · Physics 2025-03-06 Ilian Pihlajamaa , Lotte van Gessel , Corentin Laudicina , Luc van Burik , Liesbeth Janssen

Using molecular dynamics simulations we investigate the relaxation dynamics of a supercooled liquid close to a rough as well as close to a smooth wall. For the former situation the relaxation times increase strongly with decreasing distance…

Statistical Mechanics · Physics 2009-11-07 Peter Scheidler , Walter Kob , Kurt Binder

We introduce a three-dimensional lattice gas model to study the glass transition. In this model the interactions come from the excluded volume and particles have five arms with an asymmetrical shape, which results in geometric frustration…

Statistical Mechanics · Physics 2007-05-23 Anastasio Díaz-Sánchez

Employing wide-angle neutron spin echo spectroscopy, we measured the Q-dependent coherent intermediate scattering function of the prototypical ionic glass former Ca0.4K0.6(NO3)1.4, in the equilibrium and supercooled liquid states beyond the…

We investigate the characteristic length scales associated with the glass transition phenomenon. By studying an atomic glass-forming liquid in negatively curved space, for which the local order is well identified and the amount of…

Statistical Mechanics · Physics 2010-02-10 François Sausset , Gilles Tarjus

The dramatic slowdown of dynamics in supercooled liquids approaching the glass transition remains one of the central unresolved problems in condensed matter physics. We review approaches that attribute this slowdown to growing thermodynamic…

Soft Condensed Matter · Physics 2026-03-06 Massimo Pica Ciamarra , Jeppe C. Dyre , Edan Lerner , Matthieu Wyart

The dynamical glass transition is typically taken to be the temperature at which a glassy liquid is no longer able to equilibrate on experimental timescales. Consequently, the physical properties of these systems just above or below the…

Soft Condensed Matter · Physics 2017-03-08 Samuel S. Schoenholz , Ekin D. Cubuk , Efthimios Kaxiras , Andrea J. Liu

Active glasses refer to a class of driven non-equilibrium systems that share remarkably similar dynamical behavior as conventional glass-formers in equilibrium. Glass-like dynamical characteristics have been observed in various biological…

Soft Condensed Matter · Physics 2024-12-24 Subhodeep Dey , Smarajit Karmakar

Understanding the influence of activity on dense amorphous assemblies is crucial for biological processes such as wound healing, embryogenesis, or cancer progression. Here, we study the effect of self-propulsion forces of amplitude $f_0$…

Soft Condensed Matter · Physics 2026-01-27 Puneet Pareek , Peter Sollich , Saroj Kumar Nandi , Ludovic Berthier

We report that the local Debye-Waller factor in a simulated 2D glass-forming mixture exhibits significant spatial heterogeneities and that these short time fluctuations provide an excellent predictor of the spatial distribution of the long…

Statistical Mechanics · Physics 2009-01-23 Asaph Widmer-Cooper , Peter Harrowell

We present a formulation for investigating quench dynamics across quantum phase transitions in the presence of decoherence. We formulate decoherent dynamics induced by continuous quantum non-demolition measurements of the instantaneous…

Quantum Physics · Physics 2021-03-16 Wei-Ting Kuo , Daniel Arovas , Smitha Vishveshwara , Yi-Zhuang You

By means of the isoconfigurational method we calculate the change in the propensity for motion that the structure of a glass-forming system experiences during its relaxation dynamics. The relaxation of such a system has been demonstrated to…

Soft Condensed Matter · Physics 2008-10-09 J. A. Rodriguez Fris , L. M. Alarcón , G. A. Appignanesi

The lack of ultimate scaling relations for previtreous changes of the primary relaxation time or viscosity in glass-forming systems constitutes the grand fundamental challenge, also hindering the development of relevant material engineering…

Soft Condensed Matter · Physics 2022-06-28 Aleksandra Drozd-Rzoska , Sylwester J. Rzoska , Szymon Starzonek

Characterizing the glass state remains elusive since its distinction from a liquid state is not obvious. Glasses are liquids whose viscosity has increased so much that they cannot flow. Accordingly there have been many attempts to define a…

Statistical Mechanics · Physics 2015-05-27 Smarajit Karmakar , Edan Lerner , Itamar Procaccia

The interplay between the structural relaxation and the rheological response of a binary LJ glass former is studied via MD simulations. In the quiescent state, the model is well known for its sluggish dynamics and a two step relaxation of…

Soft Condensed Matter · Physics 2015-05-14 Fathollah Varnik

We provide a theoretical description of dynamical heterogeneities in glass-forming liquids, based on the premise that relaxation occurs via local rearrangements coupled by elasticity. In our framework, the growth of the dynamical…

Soft Condensed Matter · Physics 2023-11-02 Ali Tahaei , Giulio Biroli , Misaki Ozawa , Marko Popović , Matthieu Wyart

The Debye-Stokes-Einstein (DSE) model of rotational diffusion predicts that the rotational correlation times $\tau_{l}$ vary as $[l(l+1)]^{-1}$, where $l$ is the rank of the orientational correlation function (given in terms of the Legendre…

Soft Condensed Matter · Physics 2009-11-11 Prasanth P. Jose , Dwaipayan Chakrabarti , Biman Bagchi

In an earlier preprint (V. V. Ginzburg, O. V. Gendelman, R. Casalini, and A. Zaccone, arxiv:2409.17291), we demonstrated that the dynamic (relaxation time) and volume equations of state for many amorphous polymers are near-universal -- each…

Soft Condensed Matter · Physics 2025-01-03 Valeriy V. Ginzburg , Oleg V. Gendelman , Riccardo Casalini , Alessio Zaccone

It has been demonstrated recently that supercooled liquids sharing simple structural features (e.g. pair distribution functions) may exhibit strikingly distinct dynamical behavior. Here we show that a more subtle structural feature…

Statistical Mechanics · Physics 2012-06-04 Glen M. Hocky , Thomas E. Markland , David R. Reichman