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Under homogeneous uniaxial strains, the Raman 2D band of graphene involving two-phonon double-resonance scattering processes splits into two peaks and they altogether redshift strongly depending on the direction and magnitude of the strain.…

Mesoscale and Nanoscale Physics · Physics 2015-03-19 Duhee Yoon , Young-Woo Son , Hyeonsik Cheong

We have studied, both experimentally and theoretically, the change of the so-called 2D band of the Raman scattering spectrum of graphene (the two-phonon peak near 2700 cm-1) in an external magnetic field applied perpendicular to the…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 C. Faugeras , P. Kossacki , D. M. Basko , M. Amado , M. Sprinkle , C. Berger , W. A. de Heer , M. Potemski

The polarization dependences of the G, D, and 2D (G$'$) bands in Raman spectra at graphene bulk and edge are examined theoretically. The 2D and D bands have different selection rules at bulk and edge. At bulk, the 2D band intensity is…

Mesoscale and Nanoscale Physics · Physics 2010-11-15 K. Sasaki , K. Wakabayashi , T. Enoki

A simple, non-invasive method using Raman spectroscopy for the estimation of the thickness of graphene layers grown epitaxially on silicon carbide (SiC) is presented, enabling simultaneous determination of thickness, grain size and disorder…

Materials Science · Physics 2015-05-13 Shriram Shivaraman , M. V. S. Chandrashekhar , John J. Boeckl , Michael G. Spencer

Raman spectroscopy is an integral part of graphene research. It is used to determine the number and orientation of layers, the quality and types of edge, and the effects of perturbations, such as electric and magnetic fields, strain,…

Materials Science · Physics 2015-06-16 Andrea C. Ferrari , Denis M. Basko

Few-layer graphene possesses low-energy carriers which behave as massive fermions, exhibiting intriguing properties in both transport and light scattering experiments. Lowering the excitation energy of resonance Raman spectroscopy down to…

The buffer layer has been analysed by combined micro-Raman and micro-transmission experiments. The epitaxial graphene growth on the (0001) Si face of 6H-SiC substrates was tuned to get a mixed surface at the early stage of graphitization…

Mesoscale and Nanoscale Physics · Physics 2012-12-07 A. Tiberj , J. R. Huntzinger , N. Camara , P. Godignon , J. Camassel

We study the 2D Raman band of in-plane uniaxially strained graphene within a non-orthogonal tight-binding model. At non-zero strain, the obtained 2D band splits into two subbands at strain angles $0^{\circ}$ and $30^{\circ}$ or into three…

Mesoscale and Nanoscale Physics · Physics 2013-06-11 Valentin N. Popov , Philippe Lambin

The stacking faults (deviates from Bernal) will break the translational symmetry of multilayer graphenes and modify their electronic and optical behaviors to the extent depending on the interlayer coupling strength. This paper addresses the…

Materials Science · Physics 2015-05-13 Zhenhua Ni , Lei Liu , Yingying Wang , Zhe Zheng , Lain-Jong Li , Ting Yu , Zexiang Shen

Raman spectra were measured for mono-, bi- and trilayer graphene grown on SiC by solid state graphitization, whereby the number of layers was pre-assigned by angle-resolved ultraviolet photoemission spectroscopy. It was found that the only…

Though graphene has been intensively studied by Raman spectroscopy, in this letter, we report a study of second-order overtone and combinational Raman modes in an unexplored range of 1690-2150 cm-1 in nonsuspended commensurate (AB-stacked),…

Materials Science · Physics 2010-10-19 Chunxiao Cong , Ting Yu , Riichiro Saito

We present a systematic Raman study of unconventionally-stacked double-layer graphene, and find that the spectrum strongly depends on the relative rotation angle between layers. Rotation-dependent trends in the position, width and intensity…

Mesoscale and Nanoscale Physics · Physics 2012-06-15 Kwanpyo Kim , Sinisa Coh , Liang Z. Tan , William Regan , Jong Min Yuk , Eric Chatterjee , M. F. Crommie , Marvin L. Cohen , Steven G. Louie , A. Zettl

Results of room temperature Raman scattering studies of ultrathin graphitic films supported on Si (111)/SiO2 substrates are reported. The results are significantly different from those known for graphite. Spectra were collected using 514 nm…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Awnish Gupta , Gugang Chen , P. Joshi , S. Tadigadapa , P. C. Eklund

We report a Raman study of the so-called buffer layer with $(6\sqrt3\times6\sqrt3)R30^{\circ}$ periodicity which forms the intrinsic interface structure between epitaxial graphene and SiC(0001). We show that this interface structure leads…

We report a study of graphene and graphene field effect devices after exposure to a series of short pulses of oxygen plasma. We present data from Raman spectroscopy, back-gated field-effect and magneto-transport measurements. The intensity…

Mesoscale and Nanoscale Physics · Physics 2011-02-15 Isaac Childres , Luis A. Jauregui , Jifa Tian , Yong P. Chen

We compare the main feature of the measured Raman scattering spectra from single layer graphene with a bilayer in which the two layers are arbitrarily misoriented. The profiles of the 2D bands are very similar having only one component,…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Philippe Poncharal , Anthony Ayari , Thierry Michel , Jean-Louis Sauvajol

The linear band dispersion of graphene's bands near the Fermi level gives rise to its unique electronic properties, such as a giant carrier mobility, and this has triggered extensive research in applications, such as graphene field-effect…

This review presents the state of the art in strain and ripple-induced effects on the electronic and optical properties of graphene. It starts by providing the crystallographic description of mechanical deformations, as well as the…

Mesoscale and Nanoscale Physics · Physics 2017-08-22 Gerardo G. Naumis , Salvador Barraza-Lopez , Maurice Oliva-Leyva , Humberto Terrones

We review field theoretical studies dedicated to understanding the effects of electron-electron interaction in graphene, which is characterized by gapless bands, strong electron-electron interactions, and emerging Lorentz invariance deep in…

High Energy Physics - Theory · Physics 2023-05-30 A. V. Kotikov

Confocal Raman spectroscopy is a versatile, non-invasive investigation tool and a major workhorse for graphene characterization. Here we show that the experimentally observed Raman 2D line width is a measure of nanometer-scale strain…