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We present a unified description of several methods of chiral discrimination based exclusively on electric-dipole interactions. It includes photoelectron circular dichroism (PECD), enantio-sensitive microwave spectroscopy (EMWS),…

Atomic Physics · Physics 2019-01-02 Andres F. Ordonez , Olga Smirnova

We report observation of electron helical dichroism on a material with chiral structure. In analogy with circular dichroism, a common technique for molecular structural fingerprinting, we use a nanofabricated forked diffraction grating to…

Materials Science · Physics 2015-07-08 Tyler R. Harvey , Jordan S. Pierce , Jordan J. Chess , Benjamin J. McMorran

Photoelectron circular dichroism (PECD) is a method whereby randomly oriented chiral molecules are irradiated by circularly-polarized light, photoionizing electrons, which are measured in a momentum-resolved manner. This scheme permits…

Chemical Physics · Physics 2025-05-23 Ofer Neufeld

A detailed theoretical study on the electronic structure and magnetic properties of half-metallic ferromagnet CrO$_2$ was carried out by means of relativistic full-potential linear muffin-tin orbital method within the generalized gradient…

Materials Science · Physics 2009-11-11 V. Kanchana , G. Vaitheeswaran , M. Alouani

We argue that the magnetic circular dichroism (MCD) of the hard x-ray Raman scattering (XRS) could be used as an element selective probe of local spin polarization. The magnitude of the XRS-MCD signal is directly proportional to the local…

Materials Science · Physics 2019-10-01 Manabu Takahashi , Nozomu Hiraoka

Recent advances in transmission electron microscopy (TEM) have opened the path toward spin resonance spectroscopy with single-spin sensitivity. To assess this potential, we investigate the quantum precision limits for sensing magnetic…

Spectroscopic techniques that are sensitive to molecular chirality are important analytical tools to quantitatively determine enantiomeric excess and purity of chiral molecular samples. Many chiroptical processes however produce weak…

Chemical Physics · Physics 2026-04-02 Sebastian Hartweg , Dusan k. Bozanic , Gustavo A. Garcia-Macias , Laurent Nahon

We propose a magnetic measurement method based on combining depth sectioning and electron magnetic circular dichroism in scanning transmission electron microscopy. Electron vortex beams with large convergence angles, as those achievable in…

Materials Science · Physics 2018-11-14 Devendra Negi , Lewys Jones , Juan-Carlos Idrobo , Jan Rusz

We present a parameter-free method of extraction of the electron magnetic circular dichroism spectra from energy-filtered diffraction patterns measured on crystalline specimen. The method is based on multivariate curve resolution technique.…

Materials Science · Physics 2012-06-27 Shunsuke Muto , Kazuyoshi Tatsumi , Jan Rusz

Electron beam energies in Transmission Electron Microscopes (TEMs) reach the relativistic realm constituting Quantum Electrodynamics (QED) the appropriate framework for the study of electron matter interaction in TEMs. We focus on the…

Atomic Physics · Physics 2026-01-12 Ioannis Iatrakis , Valerii Brudanin

In this work we present a detailed analysis on the performance of X-ray magnetic circular dichroism photo-emission electron microscopy (XMCD-PEEM) as a tool for vector reconstruction of the magnetization. For this, we choose 360$^{\circ}$…

Experimental investigations of ultrafast magnetization dynamics increasingly employ resonant magnetic spectroscopy in the ultraviolet spectral range. Besides allowing to disentangle the element-specific transient response of functional…

We demonstrate atomic-scale mapping of local magnetic moments and doping effects in Ti-doped barium hexaferrite (BaFe11TiO19) using atom-sized electron vortex beams (EVBs) with controlled orbital angular momentum (OAM) in a scanning…

Coherent spin resonance methods such as nuclear magnetic resonance (NMR) and electron spin resonance (ESR) spectroscopy have led to spectrally highly sensitive, non-invasive quantum imaging techniques with groundbreaking applications in…

New sources of CP violation beyond the Standard Model of particle physics could be revealed in the laboratory by measuring a non-zero electric dipole moment (EDM) of a spin 1/2 particle such as the neutron. Despite the great sensitivity…

Instrumentation and Detectors · Physics 2019-05-15 G. Pignol

Skyrmions in ultrathin ferromagnetic metal (FM)/heavy metal (HM) multilayer systems produced by conventional sputtering methods have recently generated huge interest due to their applications in the field of spintronics. The sandwich…

Convergent-beam electron diffraction (CBED) is a well-established probe for spatial symmetries of crystalline samples, mainly exploiting the well-defined mapping between the diffraction groups (symmetry group of CBED patterns) and the…

Mesoscale and Nanoscale Physics · Physics 2025-11-18 O. Zaiets , C. Timm , J. Rusz , J. -Á. Castellanos-Reyes , S. Subakti , A. Lubk

The x-ray magnetic circular dichroism (XMCD) sum rule yields an extremely useful ground-state observable, which provides a quantitative measure of spontaneous time-reversal symmetry breaking (T-breaking) in a given material. I derive here…

Materials Science · Physics 2020-05-13 Raffaele Resta

The measurement of circular dichroism (CD) has widely been exploited to distinguish the different enantiomers of chiral structures. It has been applied to natural materials (e.g. molecules) as well as to artificial materials (e.g.…

Scanning electron microscopy with polarization analysis is a powerful lab-based magnetic imaging technique offering parallel imaging of multiple magnetization components and a very high spatial resolution. However, one drawback of the…

Instrumentation and Detectors · Physics 2018-08-22 Daniel Schönke , Andreas Oelsner , Pascal Krautscheid , Robert M. Reeve , Mathias Kläui