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Spatially resolved neutron diffraction as a function of crystal depth in Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ reveals the presence of a distinct near-surface region. A dramatic change in both the lattice constant and the Bragg peak intensity as…

Materials Science · Physics 2009-11-10 K. Conlon , H. Luo , D. Viehland , J. F. Li , T. Whan , J. H. Fox , C. Stock , G. Shirane

The barium sodium niobate (BNN) with tungsten-bronze structure is one of well-known optical crystals for electro-optic and nonlinear optic applications. This paper reviews the ferroelectric instability of BNN crystals. BNN is a uniaxial…

Materials Science · Physics 2023-01-05 S. Kojima

The prototypical $\alpha\to\omega$ phase transition in zirconium is an ideal test-bed for our understanding of polymorphism under extreme loading conditions. After half a century of study, a consensus had emerged that the transition is…

Materials Science · Physics 2024-04-30 P. G. Heighway , S. Singh , M. G. Gorman , D. McGonegle , J. H. Eggert , R. F. Smith

When an X-ray area detector based on a single crystalline material, for instance, a state of the art hybrid pixel detector, is illuminated from a point source by monochromatic radiation, a pattern of lines appears which overlays the…

Instrumentation and Detectors · Physics 2014-08-01 Christian Gollwitzer , Michael Krumrey

Relaxor ferroelectric PbMg_1/3Ta_2/3O_3 ceramics and thin films were investigated by means of broad-band dielectric, time-domain terahertz (THz) and Fourier-transform infrared (IR) spectroscopy in the frequency range 100 Hz - 90 THz at…

Materials Science · Physics 2009-11-13 S. Kamba , D. Nuzhnyy , S. Veljko , V. Bovtun , J. Petzelt , Y. L. Wang , J. Levoska , M. Tyunina , J. Macutkevic , N. Setter , J. Banys

We present a generalized method to describe the x-ray scattering intensity of the Bragg spots in a diffraction pattern from nanocrystals exposed to intense x-ray pulses. Our method involves the subdivision of a crystal into smaller units.…

Atomic and Molecular Clusters · Physics 2017-08-24 Malik Muhammad Abdullah , Zoltan Jurek , Sang-Kil Son , Robin Santra

Empirical potential structure refinement (EPSR) simulations are performed on total neutron scattering data from powder samples of polytetrafluoroethylene (PTFE) and polychlorotrifluoroethylene (PCTFE), both at 300K. For PTFE a number of…

Soft Condensed Matter · Physics 2013-09-27 A K Soper , K Page , A Llobet

It is now well established that the unique properties of relaxor ferroelectrics are due to the presence of polar nanoregions (PNR's). We present recent results from Neutron and Raman scattering of single crystals of PZN, PZN-xPT, and PMN.…

Materials Science · Physics 2009-11-10 D. La-Orauttapong , O. Svitelskiy , J. Toulouse

Using neutron elastic and inelastic scattering and high-energy x-ray diffraction, we present a comparison of 40% Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$-60% PbTiO$_{3}$ (PMN-60PT) with pure Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) and PbTiO$_{3}$…

Materials Science · Physics 2009-11-11 C. Stock , D. Ellis , I. P. Swainson , Guangyong Xu , H. Hiraka , Z. Zhong , H. Luo , X. Zhao , D. Viehland , R. J. Birgeneau , G. Shirane

Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ is one of the simplest representatives of the class of lead relaxors and often serves as a model system for more complicated compounds. In this paper we analyse both polarized and depolarized Raman scattering…

Materials Science · Physics 2009-11-10 Oleksiy Svitelskiy , Jean Toulouse , Z. -G. Ye

High-temperature (T) and high-electric-field (E) effects on Pb[(Zn_{1/3} Nb_{2/3})_{0.92} Ti_{0.08}]O_3 (PZN-8%PT) were studied comprehensively by neutron diffraction in the ranges 300 <= T <= 550 K and 0 <= E <= 15 kV/cm. We have focused…

Materials Science · Physics 2009-11-07 Kenji Ohwada , Kazuma Hirota , Paul W. Rehrig , Yasuhiko Fujii , Gen Shirane

We present a theoretical framework for understanding diffuse multiple scattering (DMS) in single crystals, focusing on diffuse scattering-Bragg (DS-Bragg) channels. These channels, when probed with high-flux, low-divergent monochromatic…

We review some of the current research on two of the ultra-high piezoelectric relaxors Pb(Mg1/3Nb2/3)O3 (PMN) and Pb(Zn1/3Nb2/3)O3 (PZN). The discovery of a monoclinic phase in Pb(Zr1-xTix)O3 (PZT) in 1999 by Noheda et al. forced a…

Materials Science · Physics 2007-05-23 G. Shirane , P. M. Gehring

Neutron scattering has been used to study the nature of the ferromagnetic transition in single crystals of La_0.7Ca_0.3MnO_3 and La_0.8Ca_0.2MnO_3, and polycrystalline samples of La_0.67Ca_0.33MnO_3 and La_5/8Ca_3/8MnO_3 where the naturally…

Strongly Correlated Electrons · Physics 2009-11-10 C. P. Adams , J. W. Lynn , V. N. Smolyaninova , A. Biswas , R. L. Greene , W. Ratcliff , S-W. Cheong , Y. M. Mukovskii , D. A. Shulyatev

Small angle neutron and x-ray scattering methods are used to investigate the structure of dilute suspensions of two different ferrofluid systems dispersed in soft polyacrylamide hydrogels. It is found that the particles in the fluid are…

Localized surface plasmon resonances (LSPRs) have recently been identified in extremely diluted electron systems obtained by doping semiconductor quantum dots. Here we investigate the role that different surface effects, namely electronic…

Optics · Physics 2015-04-29 R. Carmina Monreal , Tomasz J. Antosiewicz , S. Peter Apell

The dielectric response in relaxor ferroelectrics is analyzed in the framework a model for the polarization dynamics in the presence of polar clusters. We associate the origin of polar clusters with the atoms displaced from their…

Condensed Matter · Physics 2007-05-23 B. E. Vugmeister , H. Rabitz

Experimental and theoretical studies of unusual polar, dielectric and magnetic properties of room temperature multiferroics, such as perovskites Pb(Fe$_{1/2}$Nb$_{1/2}$)O$_3$ (PFN) and Pb(Fe$_{1/2}$Ta$_{1/2}$)O$_3$ (PFT), are very…

Inelastic neutron scattering study of the perovskite relaxor ferroelectric PZN:8%PT elucidates the origin of the previously reported unusual kink on the low frequency transverse phonon dispersion curve (known as "waterfall" effect). We show…

Materials Science · Physics 2012-12-18 J. Hlinka , S. Kamba , J. Petzelt , J. Kulda , C. A. Randall , S. J. Zhang

Using neutron pair distribution function (PDF) analysis over the temperature range from 1000 K to 15 K, we demonstrate the existence of local polarization and the formation of medium-range, polar nanoregions (PNRs) with local rhombohedral…

Disordered Systems and Neural Networks · Physics 2009-11-10 I. -K. Jeong , T. W. Darling , J. K. Lee , Th. Proffen , R. H. Heffner , J. S. Park , K. S. Hong , W. Dmowski , T. Egami