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Temperature-dependent x-ray diffraction of the low-dimensional spin 1/2 quantum magnet TiOBr shows that the phase transition at T_{c2} = 47.1 (4) K corresponds to the development of an incommensurate superstructure. Below T_{c1} = 26.8 \pm…

Other Condensed Matter · Physics 2007-05-23 Sander van Smaalen , Lukas Palatinus , Andreas Schonleber

We report on a detailed single crystal x-ray diffraction study of the unconventional spin-Peierls compound TiOCl. The intermediate phase of TiOCl is characterized by an incommensurate modulation which is virtually identical to that recently…

Strongly Correlated Electrons · Physics 2007-05-23 A. Krimmel , J. Strempfer , B. Bohnenbuck , B. Keimer , M. Hoinkis , M. Klemm , S. Horn , A. Loidl , M. Sing , R. Claessen , M. v. Zimmermann

We report on the magnetic, thermodynamic and optical properties of the quasi-one-dimensional quantum antiferromagnets TiOCl and TiOBr, which have been discussed as spin-Peierls compounds. The observed deviations from canonical spin-Peierls…

Strongly Correlated Electrons · Physics 2009-11-11 R. Rückamp , J. Baier , M. Kriener , M. W. Haverkort , T. Lorenz , G. S. Uhrig , L. Jongen , A. Möller , G. Meyer , M. Grüninger

The ground state of the spin-Peierls system TiOCl was probed using synchrotron x-ray diffraction on a single-crystal sample at T = 6 K. We tracked the evolution of the structural superlattice peaks associated with the dimerized ground state…

Strongly Correlated Electrons · Physics 2012-08-23 A. Prodi , J. S. Helton , Yejun Feng , Y. S. Lee

In this sturdy, we determine the roles of two successive phase transitions in the new spin-Peierls system TiOBr by electron and synchrotron X-ray diffraction analyses. Results show an incommensurate superstructure along the h- and…

Strongly Correlated Electrons · Physics 2009-11-11 T. Sasaki , M. Mizumaki , T. Nagai , T. Asaka , K. Kato , M. Takata , Y. Matsui , J. Akimitsu

The sequence of phase transitions and the symmetry of in particular the low temperature incommensurate and spin-Peierls phases of the quasi one-dimensional inorganic spin-Peierls system TiOX (TiOBr and TiOCl) have been studied using…

The application of pressure can induce transitions between unconventional quantum phases in correlated materials. The inorganic compound TiOCl, composed of chains of S=1/2 Ti ions, is an ideal realization of a spin-Peierls system with a…

Strongly Correlated Electrons · Physics 2018-02-21 Costel R. Rotundu , Jiajia Wen , Wei He , Yongseong Choi , Daniel Haskel , Young S. Lee

Temperature-dependent x-ray diffraction of the low-dimensional spin 1/2 quantum magnet TiOCl shows that the phase transition at T_{c2} = 90 K corresponds to a lowering of the lattice symmetry. Below T_{c1} = 66 K a twofold superstructure…

Materials Science · Physics 2009-11-11 M. Shaz , S. van Smaalen , L. Palatinus , M. Hoinkis , M. Klemm , S. Horn , R. Claessen

We have studied the S=1/2 quasi-one-dimensional antiferromagnet TiOCl using single crystal x-ray diffraction and inelastic x-ray scattering techniques. The Ti ions form staggered spin chains which dimerize below Tc1 = 66 K and have an…

Strongly Correlated Electrons · Physics 2009-11-13 E. T. Abel , K. Matan , F. C. Chou , E. D. Isaacs , D. E. Moncton , H. Sinn , A. Alatas , Y. S. Lee

In the present work we aim to characterize the lattice configurations and the magnetic behavior in the incommensurate phase of spin-Peierls systems. This phase emerges when the magnetic exchange interaction is coupled to the distortions of…

Strongly Correlated Electrons · Physics 2011-04-26 D. Mastrogiuseppe , C. Gazza , A. Dobry

X-ray scattering measurements on single crystals of TiOCl reveal the presence of commensurate dimerization peaks within both the incommensurate spin-Peierls phase and the so-called pseudogap phase above T_c2. This scattering is relatively…

Strongly Correlated Electrons · Physics 2016-08-05 J. P. Clancy , B. D. Gaulin , K. C. Rule , J. P. Castellan , F. C. Chou

Using elastic and inelastic neutron scattering we show that a cubic spinel, CdCr$_2$O$_4$, undergoes an elongation along the c-axis ($c > a = b$) at its spin-Peierls-like phase transition at $T_N$ = 7.8 K. The N\'{e}el phase ($T < T_N$) has…

Strongly Correlated Electrons · Physics 2009-11-11 J. -H. Chung , M. Matsuda , S. -H. Lee , K. Kakurai , H. Ueda , T. J. Sato , H. Takagi , K. -P. Hong , S. Park

We have performed x-ray scattering measurements on single crystals of the doped spin-Peierls compound Ti(1-x)Sc(x)OCl (x = 0, 0.01, 0.03). These measurements reveal that the presence of non-magnetic dopants has a profound effect on the…

Strongly Correlated Electrons · Physics 2016-08-05 J. P. Clancy , B. D. Gaulin , J. P. Castellan , K. C. Rule , F. C. Chou

Two phase transitions in the tetragonal strongly correlated electron system CeNiAsO were probed by neutron scattering and zero field muon spin rotation. For $T <T_{N1}$ = 8.7(3) K, a second order phase transition yields an incommensurate…

We analyze the effect of the phonon dynamics on a recently proposed model for the uniform-incommensurate transition seen in TiOX compounds. The study is based on a recently developed formalism for nonadiabatic spin-Peierls systems based on…

Strongly Correlated Electrons · Physics 2010-03-19 Diego Mastrogiuseppe , Ariel Dobry

The critical properties at the ferromagnetic - paramagnetic transition have been analysed from data of static magnetization measurements on single crystals of Pr1-xPbxMnO3, for x = 0.23 and x = 0.30. In Pr1-xPbxMnO3 the ferromagnetic…

Strongly Correlated Electrons · Physics 2015-06-25 B. Padmanabhan , H. L. Bhat , Suja Elizabeth , Sahana Roessler , U. K. Roessler , K. Doerr , K. H. Mueller

An interesting feature of spin-1/2 chains with a gap is that they undergo a commensurate-incommensurate transition in the presence of an external magnetic field $H$. The system is in a gapless incommensurate regime for all values of the…

Statistical Mechanics · Physics 2016-08-31 R. Chitra , T. Giamarchi

The interest in the study of spin-Peierls phenomenon has increased with the discovery of copper germanium oxide (CuGeO_3) as an example of spin-Peierls systems. The availability of this inorganic compound as large, high quality single…

Strongly Correlated Electrons · Physics 2007-05-23 J. Srivatsava

The spin$-1/2$ chain with ferromagnetic exchange $J_1 < 0$ between first neighbors and antiferromagnetic $J_2 > 0$ between second neighbors supports two spin-Peierls (SP) instabilities depending on the frustration $\alpha = J_2/\vert…

Strongly Correlated Electrons · Physics 2022-06-23 Manodip Routh , Sudip Kumar Saha , Manoranjan Kumar , Zoltán G. Soos

Going beyond a recently proposed microscopic model for the incommensurate transition in the spin-Peierls TiOX (X=Cl, Br) compounds, in the present work we start by studying the thermodynamics of the model with XY spins and adiabatic…

Strongly Correlated Electrons · Physics 2009-10-02 D. M. Mastrogiuseppe , M. E. Torio , C. J. Gazza , A. O. Dobry
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