Related papers: Nonlinear dielectric effect of dipolar fluids
We investigate dielectric saturation and increment in polar liquids under external fields. We couple a previously introduced dipolar solvent model to a uniform electric field and derive the electrostatic kernel of interacting dipoles. This…
A second-order Taylor series expansion of the free energy functional provides analytical expressions for the magnetic field dependence of the free energy and of the magnetization of ferrofluids, here modelled by dipolar Yukawa interaction…
We study a two-dimensional fluid of dipolar hard disks by Monte Carlo simulations in a square with periodic boundary conditions and on the surface of a sphere. The theory of the dielectric constant and the asymptotic behaviour of the…
The solution of the mean spherical approximation (MSA) integral equation for isotropic multicomponent dipolar hard sphere fluids without external fields is used to construct a density functional theory (DFT), which includes external fields,…
The strengths and short-comings of the point-dipole model for polar fluids of spherical molecules are illustrated by considering the physically more relevant case of extended dipoles formed by two opposite charges $\pm q$ separated by a…
We study a two-dimensional system of dipolar hard disks in the presence of a uniform external electric field $\boldsymbol{\mathcal{E}} $ by Monte Carlo simulations in a square with periodic boundary conditions. The study is performed in…
Van der Waals interactions are ubiquitous and they play an important role for the stability of materials. Current understanding of this type of coupling is based on linear response theory, while optical nonlinearities are rarely considered…
We generalize the predictions for attractions between over-all neutral surfaces induced by charge fluctuations/correlations to non-uniform systems that include dielectric discontinuities, as is the case for mixed charged lipid membranes in…
A mean-field Fokker-Planck equation approach to the dynamics of ferrofluids in the presence of a magnetic field and velocity gradients is proposed that incorporates magnetic dipole-dipole interactions of the colloidal particles. The model…
Electrostatics in the solution phase is governed by free electrical charges such as ions, as well as by bound charges that arise when a polarizable medium responds to an applied field. In a local medium, described by a constant dielectric…
We investigate electric-field effects in dilute electrolytes with nonlinear polarization. As a first example of such systems, we add a dipolar component with a relatively large dipole moment $\mu_0$ to an aqueous electrolyte. As a second…
Statistical theory of the dielectric susceptibility of polar liquid crystals is proposed. The molecules are not uniaxial but similar to cones. It is assumed that the permanent dipole moment of a molecule is parallel to the axis of the…
In this work we study the electric field of a dipole immersed in a medium with permittivity controlled by a real scalar field which is non-minimally coupled to the Maxwell field. We model the system with an interesting function, which…
In the first two papers in this series, we developed new shifted potential (SP), gradient shifted force (GSF), and Taylor shifted force (TSF) real-space methods for multipole interactions in condensed phase simulations. Here, we discuss the…
Electric field produced inside a solute by a uniformly polarized liquid is strongly affected by dipolar polarization of the liquid at the interface. We show, by numerical simulations, that the electric "cavity" field inside a hydrated…
Most prior works studying tidal interactions in tight star/planet or star/star binary systems have employed linear theory of a viscous fluid in a uniformly-rotating two-dimensional spherical shell. However, compact systems may have…
We study the effects of long-range electrostatic interactions on the thermal fluctuations of free-standing crystalline membranes exhibiting spontaneous electric polarization directed at each point along the local normal to the surface. We…
We investigate the role of the electron correlation effects in the calculations of the electric dipole polarizabilities (\alpha) of elements belonging to three different groups of periodic table. To understand the propagation of the…
Quantum electrodynamics (QED) effects may be included in physical processes of magnetar and pulsar magnetospheres with strong magnetic fields. Involving the quantum corrections, the Maxwell electrodynamics is modified to non-linear…
Treating water as a linearly responding dielectric continuum on molecular length scales allows very simple estimates of solvation structure and thermodynamics for charged and polar solutes. While this approach can successfully account for…