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Related papers: Taming Density Functional Theory by Coarse-Grainin…

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This is the second and the final part of the review on density functional theory (DFT), referred to as DFT-II. In the first review, DFT-I, we have discussed wavefunction-based methods, their complexity, and the basic of density functional…

Materials Science · Physics 2023-05-25 Ashish Kumar , Prashant Singh , Manoj K. Harbola

We give the first mathematically rigorous justification of the Local Density Approximation in Density Functional Theory. We provide a quantitative estimate on the difference between the grand-canonical Levy-Lieb energy of a given density…

Mathematical Physics · Physics 2019-11-13 Mathieu Lewin , Elliott H. Lieb , Robert Seiringer

We investigate the detailed properties of Observational entropy, introduced by \v{S}afr\'{a}nek et al. [Phys. Rev. A 99, 010101 (2019)] as a generalization of Boltzmann entropy to quantum mechanics. This quantity can involve multiple…

Quantum Physics · Physics 2019-01-17 Dominik Šafránek , J. M. Deutsch , Anthony Aguirre

We consider a $\lambda \phi^4$ theory in Minkowski spacetime. We compute a "coarse grained effective action" by integrating out the field modes with wavelength shorter than a critical value. From this effective action we obtain the…

High Energy Physics - Theory · Physics 2008-11-26 Fernando Lombardo , Francisco Mazzitelli

In contrast to the original Kohn-Sham (KS) formalism, we propose a density functional theory (DFT) with fractional orbital occupations for the study of ground states of many-electron systems, wherein strong static correlation is shown to be…

Chemical Physics · Physics 2015-06-03 Jeng-Da Chai

While the theory of diffusion of a single Brownian particle in confined geometries is well-established by now, we discuss here the theoretical framework necessary to generalize the theory of diffusion to dense suspensions of strongly…

Soft Condensed Matter · Physics 2014-12-18 H. Löwen , M. Heinen

This chapter introduces thermal density functional theory, starting from the ground-state theory and assuming a background in quantum mechanics and statistical mechanics. We review the foundations of density functional theory (DFT) by…

Chemical Physics · Physics 2014-06-02 Aurora Pribram-Jones , Stefano Pittalis , E. K. U. Gross , Kieron Burke

Simulations in the warm dense matter regime using finite temperature Kohn-Sham density functional theory (FT-KS-DFT), while frequently used, are computationally expensive due to the partial occupation of a very large number of high-energy…

Materials Science · Physics 2018-04-04 Yael Cytter , Eran Rabani , Daniel Neuhauser , Roi Baer

A generalization of the Hohenberg-Kohn theorem proves the existence of a density functional for an intrinsic state, symmetry violating, out of which a physical state with good quantum numbers can be projected.

Nuclear Theory · Physics 2009-02-05 B. G. Giraud , B. K. Jennings , B. R. Barrett

We analyze the inverse problem of Density Functional Theory using a regularized variational method. First, we show that given $k$ and a target density $\rho$, there exist potentials having $k^{\text{th}}$ bound mixed states which densities…

Mathematical Physics · Physics 2022-07-01 Louis Garrigue

By using the quantum Ising chain as a test bed and treating the spin polarization along the external transverse field as the "generalized density", we examine the performance of different levels of density functional approximations parallel…

Computational Physics · Physics 2021-10-27 Jiahao Mao , Haifeng Tang , Wenhui Duan , Zheng Liu

Partition density functional theory is a formally exact procedure for calculating molecular properties from Kohn-Sham calculations on isolated fragments, interacting via a global partition potential that is a functional of the fragment…

Other Condensed Matter · Physics 2015-05-13 Peter Elliott , Kieron Burke , Morrel H. Cohen , Adam Wasserman

Regarding the strange properties of quantum entropy and entanglement, e.g., the negative quantum conditional entropy, we revisited the foundations of quantum entropy, namely, von Neumann entropy, and raised the new method of quantum…

Quantum Physics · Physics 2012-05-08 Dong-Sheng Wang

We present dynamic density functional theory (DDFT) incorporating general inhomogeneous, incompressible, time dependent background flows and inertia, describing externally driven passive colloidal systems out of equilibrium. We start by…

Soft Condensed Matter · Physics 2024-09-11 Rory D. Mills-Williams , Benjamin D. Goddard , Andrew J. Archer

We argue that any general mathematical measure of density error, no matter how reasonable, is too arbitrary to be of universal use. However the energy functional itself provides a universal relevant measure of density errors. For the…

Computational Physics · Physics 2018-11-13 Eunji Sim , Suhwan Song , Kieron Burke

We build quantum field theory on the thermodynamic master equation for dissipative quantum systems. The vacuum is represented by a thermodynamic equilibrium state in the low-temperature limit. All regularization is consistently provided by…

Mathematical Physics · Physics 2018-03-09 Hans Christian Öttinger

We generalize the recently developped "internal" Density Functional Theory (DFT) and Kohn-Sham scheme to multicomponent systems. We obtain a general formalism, applicable for the description of multicomponent self-bound systems (as…

Quantum Physics · Physics 2015-03-19 Jeremie Messud

This article is part-I of a review of density-functional theory (DFT) that is the most widely used method for calculating electronic structure of materials. The accuracy and ease of numerical implementation of DFT methods has resulted in…

Materials Science · Physics 2023-05-25 Prashant Singh , Manoj K Harbola

Kohn-Sham Density Functional Theory (KS-DFT) has been traditionally solved by the Self-Consistent Field (SCF) method. Behind the SCF loop is the physics intuition of solving a system of non-interactive single-electron wave functions under…

The key features of density-functional theory (DFT) within a minimalistic implementation of quantum electrodynamics are demonstrated, thus allowing to study elementary properties of quantum-electrodynamical density-functional theory…