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We calculated the dependence of the transition frequencies on the fine-structure constant $\alpha$ ($q$-factors) for Ni~II. Nickel is one of the few elements with high sensitivity to $\alpha$-variation, whose lines are observed at high…

Atomic Physics · Physics 2014-11-03 E. A. Konovalova , M. G. Kozlov , R. T. Imanbaeva

Sensitivity of the frequencies of twenty two atomic transitions to the variation of the fine structure constant $\alpha$ is calculated. The findings are to be used in search for possible variation of $\alpha$ across our Galaxy using high…

Atomic Physics · Physics 2022-06-22 V. A. Dzuba , V. V. Flambaum , M. T. Murphy , D. A. Berke

Theories unifying gravity with other interactions suggest spatial and temporal variation of fundamental ``constants'' in the Universe. A change in the fine structure constant, alpha, could be detected via shifts in the frequencies of atomic…

The comparison of different atomic transition frequencies over time can be used to determine the present value of the temporal derivative of the fine structure constant alpha in a model-independent way without assumptions on constancy or…

Atomic Physics · Physics 2009-11-10 E. Peik , B. Lipphardt , H. Schnatz , T. Schneider , Chr. Tamm , S. G. Karshenboim

We calculate the dependence of atomic transition frequencies on the fine structure constant, $\alpha = e^2/\hbar c$, for some ions of Ti, Mn, Na, C, and O. The results of these calculations will be used in the search for variation of alpha…

Astrophysics · Physics 2007-05-23 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , M. V. Marchenko

We study ultranarrow $5s_{1/2}$ - $4f_{5/2}$ transitions in Nd$^{13+}$ and Sm$^{15+}$ and demonstrate that they lie in the optical region. The transitions are insensitive to external perturbations. At the same time they are sensitive to the…

Atomic Physics · Physics 2015-06-11 V. A. Dzuba , A. Derevianko , V. V. Flambaum

Over a period of eight months, we have monitored transition frequencies between nearly degenerate, opposite-parity levels in two isotopes of atomic dysprosium (Dy). These transition frequencies are highly sensitive to temporal variation of…

Atomic Physics · Physics 2008-11-26 A. Cingoz , A. Lapierre , A. -T. Nguyen , N. Leefer , D. Budker , S. K. Lamoreaux , J. R. Torgerson

The metastable ^{2}F_{7/2} and ^{2}D_{3/2} states of Yb^{+} are of interest for applications in metrology and quantum information and also act as dark states in laser cooling. These metastable states are commonly repumped to the ground…

Atomic Physics · Physics 2015-05-28 M. J. Petrasiunas , E. W. Streed , T. J. Weinhold , B. G. Norton , D. Kielpinski

Precision comparisons of different atomic frequency standards over a period of a few years can be used for a sensitive search for temporal variations of fundamental constants. We present recent frequency measurements of the 688 THz…

Atomic Physics · Physics 2008-11-25 E. Peik , B. Lipphardt , H. Schnatz , Chr. Tamm , S. Weyers , R. Wynands

We report on the spectroscopy of radio-frequency transitions between nearly-degenerate, opposite-parity excited states in atomic dysprosium (Dy). Theoretical calculations predict that these states are very sensitive to variation of the…

Atomic Physics · Physics 2013-08-14 N. Leefer , C. T. M. Weber , A. Cingöz , J. R. Torgerson , D. Budker

The large-$Q^2$ behavior of $\eta_c$-$\gamma$ and $\eta_b$-$\gamma$ transition form factors, $F_{\eta_c\gamma}(Q^2)$ and $F_{\eta_b\gamma}(Q^2)$ are analyzed in the framework of light-cone perturbative QCD with the heavy quark ($c$ and $b$)…

High Energy Physics - Phenomenology · Physics 2011-01-27 Fu-Guang Cao , Tao Huang

We calculate sensitivity coefficients to $\alpha$-variation for the fine-structure transitions (1,0) and (2,1) within $^3P_J[2s^2 2p^2]$ multiplet of the Carbon-like ions C I, N II, O III, Na VI, Mg VII, and Si IX. These transitions lie in…

Atomic Physics · Physics 2009-03-10 M. G. Kozlov , I. I. Tupitsyn , D. Reimers

Relativistic energy shifts of the low energy levels of Fe have been calculated using the Dirac-Hartree-Fock and configuration interaction techniques. The results are to be used in the search for the space-time variation of the fine…

Atomic Physics · Physics 2009-11-13 V. A. Dzuba , V. V. Flambaum

We demonstrate that several metastable excited states in Hf$~$II, Hf$~$IV and W$~$VI ions may be good clock states since they are sufficiently long-living and are not sensitive to the perturbations. Cooling E1 transitions are available.…

Atomic Physics · Physics 2022-09-20 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

The present work tests the suitability of the narrow transitions $7s \ ^2S_{1/2} \to 6d ^2D_{3/2}$ and $7s ^2S_{1/2} \to 6d ^2D_{5/2}$ in Ra$^+$ for optical frequency standard studies. Our calculations of the lifetimes of the metastable…

Atomic Physics · Physics 2009-11-13 B. K. Sahoo , B. P. Das , R. K. Chaudhuri , D. Mukherjee , R. G. E. Timmermans , K. Jungmann

We study transitions between ground and low-energy excited states of heavy ions corresponding to s-d single-electron transitions or s^2-d^2 double-electron transitions. The large nuclear charge Z and significant change in angular momentum…

Atomic Physics · Physics 2011-12-02 J. C. Berengut , V. A. Dzuba , V. V. Flambaum

Ab initio calculations of QED radiative corrections to the $^2P_{1/2}$ - $^2P_{3/2}$ fine-structure transition energy are performed for selected F-like ions. These calculations are nonperturbative in $\alpha Z$ and include all first-order…

Atomic Physics · Physics 2019-08-05 A. V. Volotka , M. Bilal , R. Beerwerth , X. Ma , Th. Stöhlker , S. Fritzsche

The precise measurement of molecular vibrational transition frequencies is useful in the search for variation in the proton-to-electron mass ratio {\mu}. Homonuclear diatomic molecules are particularly advantageous for precise measurement…

Atomic Physics · Physics 2017-03-01 Masatoshi Kajita

Quasi-forbidden electronic transitions in atoms and quasi-degenerate vibronic transitions in molecules serve as powerful probes of hypothetical temporal variations of fundamental constants. Computation of the sensitivity of a transition to…

Chemical Physics · Physics 2025-11-17 Carsten Zülch , Konstantin Gaul , Robert Berger

We performed accurate calculation of $\alpha$-dependence ($\alpha=e^2/hc$) of the transition frequencies for ions, which are used in a search for the variation of the fine structure constant $\alpha$ in space-time. We use Dirac-Hartree-Fock…

Atomic Physics · Physics 2009-08-18 V. A. Dzuba , V. V. Flambaum , M. G. Kozlov , M. Marchenko