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We investigate the mass-preserving $L^2$-gradient flow associated with a generalized Cahn--Hilliard equation. Our focus is on the sharp interface regime, where the interface width parameter $\varepsilon > 0$ is small. For well-prepared…

Analysis of PDEs · Mathematics 2025-12-02 Yuan Chen

We argue that the success of DFT can be understood in terms of a semiclassical expansion around a very specific limit. This limit was identified long ago by Lieb and Simon for the total electronic energy of a system. This is a universal…

Chemical Physics · Physics 2021-05-18 Pavel Okun , Kieron Burke

We prove that any limit-interface corresponding to a locally uniformly bounded, locally energy-bounded sequence of stable critical points of the van der Waals--Cahn--Hilliard energy functionals with perturbation parameter tending to 0 is…

Differential Geometry · Mathematics 2010-07-14 Yoshihiro Tonegawa , Neshan Wickramasekera

We consider a non local isoperimetric problem arising as the sharp interface limit of the Ohta-Kawasaki free energy introduced to model microphase separation of diblock copolymers. We perform a second order variational analysis that allows…

Analysis of PDEs · Mathematics 2013-07-24 Vesa Julin , Giovanni Pisante

We study the two and three dimensional stochastic Cahn-Hilliard equation in the sharp interface limit, where the positive parameter $\epsilon$ tends to zero, which measures the width of transition layers generated during phase separation.…

Analysis of PDEs · Mathematics 2016-09-23 Dimitra C. Antonopoulou , Dirk Blömker , Georgia D. Karali

We discuss two doubly degenerate Cahn-Hilliard (DDCH) models for isotropic surface diffusion. Degeneracy is introduced in both the mobility function and a restriction function associated to the chemical potential. Our computational results…

Numerical Analysis · Mathematics 2020-12-17 Marco Salvalaglio , Axel Voigt , Steven M. Wise

We study a two-dimensional quaternary inhibitory system. This free energy functional combines an interface energy favoring micro-domain growth with a Coulomb-type long range interaction energy which prevents micro-domains from unlimited…

Analysis of PDEs · Mathematics 2023-07-25 Stanley Alama , Lia Bronsard , Xinyang Lu , Chong Wang

We study a two-dimensional ternary inhibitory system derived as a sharp-interface limit of the Nakazawa-Ohta density functional theory of triblock copolymers. This free energy functional combines an interface energy favoring micro-domain…

Analysis of PDEs · Mathematics 2019-12-20 Stan Alama , Lia Bronsard , Xinyang Lu , Chong Wang

We study a non-local Cahn-Hilliard energy arising in the study of di-block copolymer melts, often referred to as the Ohta-Kawasaki energy in that context. In this model, two phases appear, which interact via a Coulombic energy. As in our…

Analysis of PDEs · Mathematics 2014-10-28 Dorian Goldman

We consider a class of generalized antiferromagnetic local/nonlocal interaction functionals in general dimension, where a short range attractive term of perimeter type competes with a long range repulsive term characterized by a reflection…

Analysis of PDEs · Mathematics 2021-06-16 Sara Daneri , Eris Runa

In this paper, we introduce a nonlocal, variational model for thin films. We consider convolution-type functionals defined on a thin domain whose thickness is of order $\gamma$, where the effective interactions range between points is of…

Analysis of PDEs · Mathematics 2026-05-08 Nadia Ansini , Antonio Tribuzio

We present a modified form of the Functionalized Cahn Hilliard (FCH) functional which models highly amphiphilic systems in solvent. A molecule is highly amphiphilic if the energy of a molecule isolated within the bulk solvent molecule is…

Analysis of PDEs · Mathematics 2020-09-08 Shibin Dai , Keith Promislow

We give a detailed description of the geometry of single droplet patterns in a nonlocal isoperimetric problem. In particular we focus on the sharp interface limit of the Ohta-Kawasaki free energy for diblock copolymers, regarded as a…

Analysis of PDEs · Mathematics 2011-10-04 Marco Cicalese , Emanuele Spadaro

We address small volume-fraction asymptotic properties of a nonlocal isoperimetric functional with a confinement term, derived as the sharp interface limit of a variational model for self-assembly of diblock copolymers under confinement by…

Analysis of PDEs · Mathematics 2018-10-25 Stan Alama , Lia Bronsard , Rustum Choksi , Ihsan Topaloglu

In this work we introduce volume constraint problems involving the nonlocal operator $(-\Delta)_{\delta}^{s}$, closely related to the fractional Laplacian $(-\Delta)^{s}$, and depending upon a parameter $\delta>0$ called horizon. We study…

Analysis of PDEs · Mathematics 2020-04-28 José C. Bellido , Alejandro Ortega

We consider sharp interface asymptotics for a phase field model of two phase near spherical biomembranes involving a coupling between the local mean curvature and the local composition proposed by the first and second authors. The model is…

Analysis of PDEs · Mathematics 2020-12-24 Charles M. Elliott , Luke Hatcher , Björn Stinner

We study the size estimate problem for the two-phase shallow shell equations in this paper. Our aim is to derive bounds on the volume fraction of each phase assuming that the material properties of the two phases are given. The approach in…

Analysis of PDEs · Mathematics 2012-04-24 Hyeonbae Kang , Graeme W. Milton , Jenn-Nan Wang

Using the delta correction to the standard free energy \cite{bc} in the elastic setting with a quadratic foundation term and some parameters, we introduce a one dimension only model for strong segregation in diblock copolymers, whose sharp…

General Mathematics · Mathematics 2009-05-28 Adam Chmaj

We use the exact strong-interaction limit of the Hohenberg-Kohn energy density functional to approximate the exchange-correlation energy of the restricted Kohn-Sham scheme. Our approximation corresponds to a highly non-local density…

Strongly Correlated Electrons · Physics 2012-12-12 Francesc Malet , Paola Gori-Giorgi

We find the numerically exact partition potential for 1-D systems of interacting electrons designed to model diatomic molecules. At integer fragment occupations, the kinetic contribution to the partition potential develops sharp features in…

Chemical Physics · Physics 2018-11-14 Yan Oueis , Adam Wasserman