Related papers: Transfer coefficients for the Gibbs surface in a t…
In earlier work \cite{bedeaux/vdW/I, bedeaux/vdW/II, bedeaux/vdW/III} a systematic extension of the van der Waals square gradient model to non-equilibrium one-component systems was given. In this work the focus was on heat and mass transfer…
We present a theory which describes the transport properties of the interfacial region with respect to heat and mass transfer. Postulating the local Gibbs relation for a continuous description inside the interfacial region, we derive the…
In this paper we derive relations between the local resistivities inside the interfacial region and the overall resistances of the surface between two phases for a mixture. These resistivities are the coefficients in the force-flux…
In recent prior work, the author derived interfacial mass and heat flux conditions for phase-change processes. The mass flux condition is identical to the Schrage equation, but the additional heat flux expression enables one to couple the…
The surface texture of materials plays a critical role in wettability, turbulence and transport phenomena. In order to design surfaces for these applications, it is desirable to characterise non-smooth and porous materials by their ability…
The local entropy production in a shock wave was analysed in the framework of non-equilibrium thermodynamics (NET) of surfaces. We show that the thermodynamic state variables in the shock front are equal to their equilibrium values, despite…
We revisit the sharp-interface continuum thermodynamics of two-phase multicomponent fluid systems with interfacial mass. Since the published work is not fully consistent, we provide a rigorous derivation of the local balance equations and…
We derive the entropy production for transport of multi-phase fluids in a non-deformable, porous medium exposed to differences in pressure, temperature, and chemical potentials. Thermodynamic extensive variables on the macro-scale are…
In this paper we calculate the interfacial resistances to heat and mass transfer through a liquid-vapor interface in a binary mixture. We use two methods, the direct calculation from the actual non-equilibrium solution and integral…
A new diffuse interface model for a two-phase flow of two incompressible fluids with different densities is introduced using methods from rational continuum mechanics. The model fulfills local and global dissipation inequalities and is also…
We investigate interfacial fluid dynamics and heat transfer at nanoscales using an improved diffuse interface approach for liquid-vapor interfaces in non-equilibrium. Conventional Navier-Stokes-Korteweg (NSK) formulations often fail to…
Thermo-osmotic flows, generated by applying a thermal gradient along a liquid-solid interface, could be harnessed to convert waste heat into electricity. While this phenomenon has been known for almost a century, there is a crucial need to…
Although ubiquitous in nature and industrial processes, transport processes at the interface during evaporation and condensation are still poorly understood. Experiments have shown temperature discontinuities at the interface during…
In this paper we first apply the general analysis described in our first paper to a binary mixture of cyclohexane and $n$-hexane. We use the square gradient model for the continuous description of a non-equilibrium surface and obtain…
Motivated by experiments with current biased superconducting atomic point contacts the general problem of nonadiabatic transitions between adiabatic surfaces in presence of strong dissipation is studied. For a single channel device the…
Heat transfer via phase change is a major contributor to heat removal in numerous engineering applications. Thin films of liquid result in increased heat transfer due to a reduction of conduction resistance, in addition the pressure jump at…
Nonequilibrium interfacial thermodynamics is formulated in the presence of surface reactions for the study of diffusiophoresis in isothermal systems. As a consequence of microreversibility and Onsager-Casimir reciprocal relations,…
We present a model treating the kinetics of adsorption of soluble surface-active molecules at the interface between an aqueous solution and another fluid phase. The model accounts for both the diffusive transport inside the solution and the…
This work deals with an inverse two-dimensional nonlinear heat conduction problem to determine the top and lateral surface transfer coefficients. For this, the \textsc{B}ayesian framework with the \textsc{M}arkov Chain \textsc{M}onte…
We present accurate and mathematically consistent formulations of a diffuse-interface model for two-phase flow problems involving rapid evaporation. The model addresses challenges including discontinuities in the density field by several…