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We investigate the optical properties of bromine intercalated highly orientated pyrolytic graphite (Br-HOPG) and provide a novel interpretation of the data. We observe new absorption features below 620 meV which are absent in the absorption…

Materials Science · Physics 2016-11-25 J. Hwang , J. P. Carbotte , S. Tongay , A. F. Hebard , D. B. Tanner

A method to produce suspensions of graphene sheets by combining solution-based bromine intercalation and mild sonochemical exfoliation is presented. Ultrasonic treatment of graphite in water leads to the formation of suspensions of graphite…

Graphene has a high intrinsic thermal conductivity and a high electron mobility. The thermal conductivity of graphene can be significantly reduced when different carbon isotopes are mixed, which can enhance the performance of thermoelectric…

Mesoscale and Nanoscale Physics · Physics 2020-05-20 Eric Whiteway , Michael Hilke

Various bandstructure engineering methods have been studied to improve the performance of graphitic transparent conductors; however none demonstrated an increase of optical transmittance in the visible range. Here we measure in situ optical…

In this letter we report the discovery of superconductivity in the isostructural graphite intercalation compounds C6Yb and C6Ca, with transition temperatures of 6.5K and 11.5K respectively. A structural characterisation of these compounds…

Superconductivity · Physics 2015-06-25 Thomas E. Weller , Mark Ellerby , Siddharth S. Saxena , Robert P. Smith , Neal T. Skipper

We report experimental results indicating possible high-temperature superconductivity in graphite intercalation compounds synthesized with lithium-based alloys. Temperature-dependent measurements of magnetization, trapped magnetic flux, and…

It has been reported that graphite hosts room temperature superconductivity. Here we provide new results that confirm these claims on different samples of highly oriented pyrolytic graphite (HOPG) and commercial flexible graphite gaskets…

We present a density functional theory study of low density bromination of graphene and graphite, finding significantly different behaviour in these two materials. On graphene we find a new Br2 form where the molecule sits perpendicular to…

Mesoscale and Nanoscale Physics · Physics 2011-03-18 A. Yaya , C. P. Ewels , I. Suarez-Martinez , Ph. Wagner , S. Lefrant , A. Okotrub , L. Bulusheva , P. R. Briddon

An interplay between the increase in the number of carriers and the decrease in the scattering time is expected to result in a saturation of the in-plane resistivity, $\rho_{ab}$, in graphite above room temperature. Contrary to this…

Materials Science · Physics 2009-07-23 D. B. Gutman , S. Tongay , H. K. Pal , D. L. Maslov , A. F. Hebard

We report transport and magnetization measurements on graphitic materials that have been hydrogenated after being treated with octane. The temperature-dependent electrical resistivity shows anomalies manifested as re-entrant insulator-metal…

Superconductivity · Physics 2020-05-13 Nadina Gheorghiu , Charles R. Ebbing , Timothy J. Haugan

We find experimentally that the optical sheet conductance of graphite per graphene layer is very close to $(\pi/2)e^2/h$, which is the theoretically expected value of dynamical conductance of isolated monolayer graphene. Our calculations…

Strongly Correlated Electrons · Physics 2009-11-13 A. B. Kuzmenko , E. van Heumen , F. Carbone , D. van der Marel

Graphene, a zero-gap semimetal, can be transformed into a metallic, semiconducting or insulating state by either physical or chemical modification. Superconductivity is conspicuously missing among these states despite considerable…

Superconductivity · Physics 2016-04-05 J. Chapman , Y. Su , C. A. Howard , D. Kundys , A. Grigorenko , F. Guinea , A. K. Geim , I. V. Grigorieva , R. R. Nair

In this letter, we report the discovery of superconductivity in Li3Ca2C6. Several graphite intercalation compounds (GICs) with electron donors, are well known as superconductors. It is probably not astonishing, since it is generally…

High resolution magnetoresistance data in highly oriented pyrolytic graphite thin samples manifest non-homogenous superconductivity with critical temperature $T_c \sim 25 $K. These data exhibit: i) hysteretic loops of resistance versus…

Although not an intrinsic superconductor, it has been long--known that, when intercalated with certain dopants, graphite is capable of exhibiting superconductivity. Of the family of graphite--based materials which are known to superconduct,…

Superconductivity · Physics 2016-08-16 Gabor Csányi , P. B. Littlewood , A. H. Nevidomskyy , Chris J. Pickard , B. D. Simons

Sulfur intercalated graphite composites with diamagnetic transitions at 6.7 K and 37 K are prepared. The magnetization hysteresis loops (MHL), Xray diffraction patterns, and resistance were measured. From the MHL, a slight superconducting…

Superconductivity · Physics 2009-11-07 H. P. Yang , H. H. Wen , Z. W. Zhao , S. L. Li

The graphite conductivity is evaluated for frequencies between 0.1 eV, the energy of the order of the electron-hole overlap, and 1.5 eV, the electron nearest hopping energy. The in-plane conductivity per single atomic sheet is close to the…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 L. A. Falkovsky

We have made thermal and electrical transport measurements of uncompressed pyrolytic graphite sheet (uPGS), a mass-produced thin graphite sheet with various thicknesses between 10 and 100 {\mu}m, at temperatures between 2 and 300 K.…

Materials Science · Physics 2017-10-04 Sachiko Nakamura , Daisuke Miyafuji , Takenori Fujii , Tomohiro Matsui , Hiroshi Fukuyama

We report the discovery of superconductivity below 1.65(6) K in Sr-intercalated graphite SrC6, by susceptibility and specific heat (Cp) measurements. In comparison with CaC6, we found that the anisotropy of the upper critical fields for…

Superconductivity · Physics 2009-11-13 J. S. Kim , L. Boeri , J. R. O'Brien , F. S. Razavi , R. K. Kremer

Surface superconductivity in rhombohedral graphite is a robust phenomenon which can exist even when higher order hoppings between the layers lift the topological protection of the surface flat band and introduce a quadratic dispersion of…

Superconductivity · Physics 2013-05-13 N. B. Kopnin , M. Ijäs , A. Harju , T. T. Heikkilä
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