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We present Monte Carlo simulation results of the two-dimensional Zwanzig fluid, which consists of hard line segments which may orient either horizontally or vertically. At a certain critical fugacity, we observe a phase transition with a…

Statistical Mechanics · Physics 2009-11-13 T. Fischer , R. L. C. Vink

The liquid-gas spinodal and the glass transition define ultimate boundaries beyond which substances cannot exist as (stable or metastable) liquids. The relation between these limits is analyzed {\it via} computer simulations of a model…

Statistical Mechanics · Physics 2009-10-31 Srikanth Sastry

Computer simulations are presented of the isotropic-to-nematic transition in a liquid crystal confined between two parallel plates a distance H apart. The plates are neutral and do not impose any anchoring on the particles. Depending on the…

Statistical Mechanics · Physics 2010-08-20 J. M. Fish , R. L. C. Vink

The stability-limit conjecture (SLC) proposes that the liquid spinodal of water returns to positive pressure in the supercooled region, and that the apparent divergence of water's thermodynamic response functions as temperature decreases…

Statistical Mechanics · Physics 2019-07-24 Pheerawich Chitnelawong , Francesco Sciortino , Peter H. Poole

A liquid can exist under conditions of thermodynamic stability or metastability within boundaries defined by the liquid-gas spinodal and the glass transition line. The relationship between these boundaries has been investigated previously…

Soft Condensed Matter · Physics 2009-11-11 S. S. Ashwin , Gautam I. Menon , Srikanth Sastry

While classical theory of phase transitions deals with systems where shape variation is energetically neutral, the account of rigidity can lead to the emergence of new thermodynamic features. One of them is a special type of critical points…

Materials Science · Physics 2024-04-18 Yury Grabovsky , Lev Truskinovsky

Spinodal decomposition in a near-critical binary fluid is examined for experimental scenarios in which the liquid is quenched abruptly by changing the pressure and the subsequent phase separation occurs with no heat flow from the outside,…

Statistical Mechanics · Physics 2021-07-06 James P. Donley

We use numerical simulation to examine the possibility of a reversible liquid-liquid transition in supercooled water and related systems. In particular, for two atomistic models of water, we have computed free energies as functions of…

Statistical Mechanics · Physics 2012-05-11 David T. Limmer , David Chandler

We report a molecular dynamics simulation demonstrating that a columnar liquid crystal, commonly formed by disc-shaped molecules, can be formed by identical particles interacting via a spherically symmetric potential. Upon isochoric cooling…

Soft Condensed Matter · Physics 2015-03-20 Alfredo Metere , Tomas Oppelstrup , Sten Sarman , Mikhail Dzugutov

A liquid can form under cooling a glassy state either as a result of a continuous slowing down or by a first order polyamorphous phase transition. The second scenario has so far always been observed below the melting point where it…

Soft Condensed Matter · Physics 2010-04-16 Måns Elenius , Tomas Oppelstrup , Mikhail Dzugutov

We perform successive umbrella sampling grand canonical Monte Carlo computer simulations of the original ST2 model of water in the vicinity of the proposed liquid-liquid critical point, at temperatures above and below the critical…

Soft Condensed Matter · Physics 2011-08-31 Sciortino Francesco , Saika-Voivod Ivan , Poole Peter

We study the interplay between the fluid-crystal transition and the glass transition of elastic sphere system with polydispersity using nonequilibrium molecular dynamics simulations. It is found that the end point of the crystal-fluid…

Statistical Mechanics · Physics 2010-09-29 Tomoaki Nogawa , Nobuyasu Ito , Hiroshi Watanabe

We investigate the phase behavior of a single-component system in 3 dimensions with spherically-symmetric, pairwise-additive, soft-core interactions with an attractive well at a long distance, a repulsive soft-core shoulder at an…

Soft Condensed Matter · Physics 2009-11-07 G. Franzese , G. Malescio , A. Skibinsky , S. V. Buldyrev , H. E. Stanley

We report the observation of the transition from an ordered solid-like phase to a disordered liquid-like phase of a lattice of spikes on a ferrofluid surface submitted to horizontal sinusoidal vibrations. The melting transition occurs for a…

Soft Condensed Matter · Physics 2010-01-05 François Boyer , Eric Falcon

In ref. cond-mat/0005372, Sastry studies by numerical simulations the phase diagram of a simple fragile glass-forming liquid, presenting very interesting and clear results. We apply to this system, at various density values, the analytic…

Disordered Systems and Neural Networks · Physics 2007-05-23 Barbara Coluzzi , Giorgio Parisi , Paolo Verrocchio

Liquid crystals in two dimensions undergo a first-order isotropic-to-quasi-nematic transition, provided the particle interactions are sufficiently ``sharp and narrow''. This implies phase coexistence between isotropic and quasi-nematic…

Statistical Mechanics · Physics 2009-11-13 R. L. C. Vink

We use super-paramagnetic spherical particles which are arranged in a two-dimensional monolayer at a water/air interface to investigate the crystal to liquid phase transition. According to the KTHNY theory a crystal melts in thermal…

Soft Condensed Matter · Physics 2015-06-11 Patrick Dillmann , Georg Maret , Peter Keim

When a system undergoes a transition from a liquid to a solid phase, it passes through multiple intermediate structures before reaching the final state. However, our knowledge on the exact pathways of this process is limited, mainly due to…

Soft Condensed Matter · Physics 2021-09-17 Peng Tan , Ning Xu , Lei Xu

Liquid crystals in two dimensions do not support long-ranged nematic order, but a quasi-nematic phase where the orientational correlations decay algebraically is possible. The transition from the isotropic to the quasi-nematic phase can be…

Statistical Mechanics · Physics 2014-12-30 Richard L. C. Vink

Much attention has been devoted to water's metastable phase behavior, including polyamorphism (multiple amorphous solid phases), and the hypothesized liquid-liquid transition and associated critical point. However, the possible relationship…

Soft Condensed Matter · Physics 2021-06-09 Thomas E. Gartner , Salvatore Torquato , Roberto Car , Pablo G. Debenedetti
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