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Rattling-induced superconductivity in the beta-pyrochlore oxide RbOs2O6 is investigated under high pressures up to 6 GPa. Resistivity measurements in a high-quality single crystal show that the superconducting transition temperature Tc…

Superconductivity · Physics 2011-10-04 Nao Takeshita , Hiroki Ogusu , Jun-ichi Yamaura , Yoshihiko Okamoto , Zenji Hiroi

Rattling-induced superconductivity in the {\beta}-pyrochlore oxide KOs2O6 is investigated under high pressure up to 5 GPa. Resistivity measurements in a high-quality single crystal reveal a gradual decrease in the superconducting transition…

Superconducting and normal-state properties of the beta-pyrochlore oxide KOs2O6 are studied by means of thermodynamic and transport measurements. It is shown that the superconductivity is of conventional s-wave type and lies in the…

Superconductivity · Physics 2009-11-13 Z. Hiroi , S. Yonezawa , Y. Nagao , J. Yamaura

We have applied ab initio molecular dynamics (MD) simulations to study metal-metal coupling on the alkali-metal sublattice in the {\beta}-pyrochlore osmates, AOs2O6 (A = K, Rb, Cs) at 300 K. We find that the alkali-metal atoms (rattlers)…

Materials Science · Physics 2015-06-17 E. Shoko , V. K. Peterson , G. J. Kearley

Chemical trends of fundamental superconducting parameters and normal-state properties are described for a family of pyrochlore oxide superconductors. Particularly, the change of Tc from 1.0 K for alpha-pyrochlore Cd2Re2O7 to 3.3 K (A = Cs),…

Superconductivity · Physics 2009-11-11 Zenji Hiroi , Jun-Ichi Yamaura , Shigeki Yonezawa , Hisatomo Harima

Single crystals of RbOs2O6 have been grown from Rb2O and Os in sealed quartz ampoules. The crystal structure has been identified at room temperature as cubic with the lattice constant a = 10.1242(12) A. The anisotropy of the tetrahedral and…

Superconductivity · Physics 2009-11-13 K. Rogacki , G. Schuck , Z. Bukowski , N. D. Zhigadlo , J. Karpinski

{\ss}-pyrochore KOs2O6, which shows superconductivity below ~ 9.7K, has been converted into KxOs2O6 (x < 2/3 - 1/2) electrochemically to show spin glass-like behavior below ~ 6.1K. Room temperature sample surface potential versus charge…

Superconductivity · Physics 2015-05-27 C. C. Lee , W. L. Lee , J. -Y. Lin , C. C. Tsuei , J. G. Lin , F. C. Chou

Pressure dependence of superconducting transition temperature $T_{\rm c}$ has been determined through the DC magnetic measurements under pressure up to $P$=10 GPa for $\beta$-pyrochlore oxides AOs$_2$O$_6$ with A=Cs ($T_{\rm c}$=3.3 K), Rb…

Superconductivity · Physics 2009-11-13 K. Miyoshi , Y. Takaichi , Y. Takamatsu , M. Miura , J. Takeuchi

High pressure effects on the superconducting transitions of beta-pyrochlore superconductors AOs2O6 (A = Cs, Rb, K) are studied by measuring resistivity under high pressures up to 10 GPa. The superconducting transition temperature Tc first…

Superconductivity · Physics 2009-11-11 T. Muramatsu , N. Takeshita , C. Terakura , H. Takagi , Y. Tokura , S. Yonezawa , Y. Muraoka , Z. Hiroi

The discovery of a new beta-pyrochlore oxide superconductor CsOs2O6 with Tc = 3.3 K is reported. It is the third superconductor in the family of beta-pyrochlore oxides, following KOs2O6 with Tc = 9.6 K and RbOs2O6 with Tc = 6.3 K. The Tc of…

Superconductivity · Physics 2009-11-10 Shigeki Yonezawa , Yuji Muraoka , Zenji Hiroi

Electronic, magnetic, and dynamical properties of the new superconducting $\beta$-pyrochlore KOs$_2$O$_6$ and related RbOs$_2$O$_6$ and CsOs$_2$O$_6$ compounds are calculated and compared with experiment and contrasted with structurally…

Superconductivity · Physics 2009-11-10 J. Kunes , T. Jeong , W. E. Pickett

Two beta-pyrochlore oxide superconductors, CsOs2O6 and RbOs2O6, are studied thermodynamically by measuring specific heat on polycrystalline samples. It is found that a Sommerfeld coefficient ? is nearly equal, 20 mJ/K2 mol Os, in the two…

Superconductivity · Physics 2009-11-11 Zenji Hiroi , Shigeki Yonezawa , Takaki Muramatsu , Jun-Ichi Yamaura , Yuji Muraoka

We report the discovery of a new pyrochlore oxide superconductor RbOs2O6. The compound crystallizes in the same beta-pyrochlore structure as the recently discovered superconductor KOs2O6, where Os atoms form a corner-sharing tetrahedral…

Superconductivity · Physics 2009-11-10 S. Yonezawa , Y. Muraoka , Y. Matsushita , Z. Hiroi

Recently new pyrochlore oxides superconductors AOs2O6 (A=K,Rb,Cs) were found and we measured the pressure dependence of magnetization up to 1.2 GPa in order to deduce the pressure effect of Tc in the three beta-pyrochlore oxides. It is…

Superconductivity · Physics 2009-11-10 Takaki Muramatsu , Shigeki Yonezawa , Yuji Muraoka , Zenji Hiroi

Superconductivity in the potassium osmium oxide KOs2O6 crystallizing in the beta-pyrochlore structure is studied by means of electrical resistivity, magnetic susceptibility and specific heat. It is the second superconductor in the family of…

Superconductivity · Physics 2009-11-10 Z. Hiroi , S. Yonezawa , Y. Muraoka

In order to clarify the mechanism of the enhancement of superconducting transition temperature $T_{\rm c}$ due to anharmonic local oscillation of a guest ion in a cage composed of host atoms, i.e., {\it rattling}, we analyze the anharmonic…

Superconductivity · Physics 2015-05-28 Kunihiro Oshiba , Takashi Hotta

Rattling dynamics have been identified as fundamental to superconductivity in defect pyrochlore osmates and aluminium vanadium intermetallics, as well as low thermal conductivity in clathrates and filled skutterudites. Combining inelastic…

We study the influence of the rattling phonons on superconductivity in $\beta$-pyrochlore KOs$_{2}$O$_{6}$ compound based on the strong-coupling Eliashberg approach. In particular, analyzing the specific heat data we find that the rattling…

Superconductivity · Physics 2009-05-29 Jun Chang , Ilya Eremin , Peter Thalmeier

We report the results of 87Rb NMR measurements on RbOs2O6, a new member of the family of the superconducting pyrochlore-type oxides with a critical temperature Tc = 6.4 K. In the normal state, the nuclear spin-lattice relaxation time T1…

Superconductivity · Physics 2009-11-10 K. Magishi , J. L. Gavilano , B. Pedrini , J. Hinderer , M. Weller , H. R. Ott , S. M. Kazakov , J. Karpinski

We have revealed new features in the out-of-plane resistivity rho_c of heavily underdoped RBa_2Cu_3O_{6+x} (R=Tm,Lu) single crystals, which give evidence for two distinct mechanisms contributing the c-axis transport. We have observed a…

Superconductivity · Physics 2009-10-31 A. N. Lavrov , M. Yu. Kameneva , L. P. Kozeeva
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