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Aliovalent rare earth substitution into the alkaline earth site of CaFe2As2 single-crystals is used to fine-tune structural, magnetic and electronic properties of this iron-based superconducting system. Neutron and single crystal x-ray…

Superconductivity · Physics 2015-03-19 S. R. Saha , N. P. Butch , T. Drye , J. Magill , S. Ziemak , K. Kirshenbaum , P. Y. Zavalij , J. W. Lynn , J. Paglione

We present a calorimetric study on single crystals of Ca(Fe1-xCox)2As2 (x = 0, 0.032, 0.051, 0.056, 0.063, and 0.146). The combined first order spin-density wave/structural transition occurs in the parent CaFe2As2 compound at 168 K and…

Superconductivity · Physics 2015-05-30 M. Abdel-Hafiez , L. Harnagea , S. Singh , U. Stockert , S. Wurmehl , R. Klingeler , A. U. B. Wolter , B. Buechner

Single crystals of Rb{0.8}Fe2Se2 are successfully synthesized with the superconducting transition temperatures T_c{onset}= 31 K and T_c{zero}= 28 K. A clear anomaly of resistivity was observed in the normal state at about 150 K, as found in…

Superconductivity · Physics 2011-05-30 Chun-Hong Li , Bing Shen , Fei Han , Xiyu Zhu , Hai-Hu Wen

The structural and microstructural properties of the Sm(Fe1-xRux)As(O0.85F0.15) system were investigated by means of high-resolution synchrotron X-ray powder diffraction between 10 K and 300 K. The tetragonal to orthorhombic structural…

Superconductivity · Physics 2018-11-16 A. Martinelli

We present a systematic pressure study of poly- and single crystalline SrFe2As2 by electrical resistivity and X-ray diffraction measurements. SrFe2As2 exhibits a structural phase transition from a tetragonal to an orthorhombic phase at…

We present the structural, magnetic, thermal and ab-plane electronic transport properties of single crystals of CaCu1.7As2 grown by the self-flux technique that were investigated by powder x-ray diffraction, magnetic susceptibility chi,…

Superconductivity · Physics 2013-08-20 V. K. Anand , D. C. Johnston

The crystal structure of Na0.5CoO2, determined by powder neutron diffraction, is reported. The structure consists of layers of edge-shared CoO6 octahedra in a triangular lattice, with Na ions occupying ordered positions in the interleaving…

Strongly Correlated Electrons · Physics 2009-11-10 Q. Huang , M. L. Foo , J. W. Lynn , H. W. Zandbergen , G. Lawes , Yayu Wang , B. H. Toby , A. P. Ramirez , N. P. Ong , R. J. Cava

We report neutron powder diffraction measurements on a series of NaxCoO2 samples with x near 0.75 which were prepared under different synthesis conditions. Two different crystal structures for the samples are observed at room temperature.…

Strongly Correlated Electrons · Physics 2012-04-12 Q. Huang , B. Khaykovich , F. C. Chou , J. H. Cho , J. W. Lynn , Y. S. Lee

The results of differential-thermal analysis of various samples as well as dielectric measurements of solid solutions $TlIn_{1-x}Fe_x^{56,57}S_2$ are presented. It has been established that phase transitions become blurred and shift to low…

Condensed Matter · Physics 2007-05-23 R. M. Sardarli , A. P. Abdullayev , O. A. Samedov , N. A. Eubova , B. R. Gadjiyev

The temperature dependence of the ac susceptibility for single-crystalline Fe1.02Se has been measured at high pressures to 6.7 GPa. The superconducting transition temperature Tc displays a large increase from 7 K to 30 K in the two-phase…

Superconductivity · Physics 2013-05-29 V. G. Tissen , E. G. Ponyatovskii , M. V. Nefedova , A. N. Titov , V. V. Fedorenko

Temperature dependent measurements of 57Fe Mossbauer spectra on CaFe2As2 single crystals in the tetragonal and collapsed tetragonal phases are reported. Clear features in the temperature dependencies of the isomer shift, relative spectra…

Materials Science · Physics 2016-01-27 Sergey L. Bud'ko , Xiaoming Ma , Milan Tomic , Sheng Ran , Roser Valenti , Paul C. Canfield

We successfully synthesized the BaPt$_2$As$_2$ single crystals and studied their structural and physical properties at low temperatures. BaPt$_2$As$_2$ crystallizes in the CaBe$_2$Ge$_2$-type tetragonal structure (P4/nmm) at room…

Superconductivity · Physics 2015-06-23 W. B. Jiang , C. Y. Guo , Z. F. Weng , Y. F. Wang , Y. H. Chen , Y. Chen , G. M. Pang , T. Shang , X. Lu , H. Q. Yuan

Temperature-dependent, in-plane, thermoelectric power data are presented for single crystals of Ba(Fe1-xCox)2As2, 0\leqx\leq0.05, and Ba(Fe1-xRhx)2As2, (0\leqx\leq0.171). Given that previous thermoelectric power and angle resolved…

Superconductivity · Physics 2013-08-14 H. M. Hodovanets , A. Thaler , E. Mun , N. Ni , S. L. Bud'ko , P. C. Canfield

We report high pressure powder synchrotron x-ray diffraction studies on MFe2As2 (M=Ba, Ca) over a range of temperatures and pressures up to about 56 GPa using a membrane diamond anvil cell. A phase transition to a collapsed tetragonal phase…

Perturbed angular correlation spectroscopy combined with $ab-initio$ electronic structure calculations is used to unravel the structural phase transition path from the low-temperature polar structure to the high-temperature structural phase…

We study the anisotropic in-plane optical conductivity of detwinned Ba(Fe1-xCox)2As2 single crystals for x=0, 2.5% and 4.5% in a broad energy range (3 meV-5 eV) across their structural and magnetic transitions. For temperatures below the…

Strongly Correlated Electrons · Physics 2016-11-25 A. Lucarelli , A. Dusza , A. Sanna , S. Massidda , J. -H. Chu , I. R. Fisher , L. Degiorgi

The compound CaV2O4 contains V^{+3} cations with spin S = 1 and has an orthorhombic structure at room temperature containing zigzag chains of V atoms running along the c-axis. We have grown single crystals of CaV2O4 and report…

The effects of pressure up to $\sim 20$ kbar, on the structural phase transition of SrFe$_2$As$_2$ and lightly Sn-doped BaFe$_2$As$_2$, as well as on the superconducting transition temperature and upper critical field of…

Superconductivity · Physics 2009-11-13 M. S. Torikachvili , S. L. Bud'ko , N. Ni , P. C. Canfield

We performed systematic measurements of magnetic susceptibility on single crystals of La$_{1.875}$Ba$_{0.125-x}$Sr$_x$CuO$_4$. The dependence of the superconducting transition temperature on Sr-concentration demonstrates a step-like pattern…

Superconductivity · Physics 2009-10-31 M. Fujita , H. Goka , K. Yamada

The tetragonal-to-orthorhombic structural phase transition (SPT) in LaFeAsO (La-1111) and SmFeAsO (Sm-1111) single crystals measured by high resolution x-ray diffraction is found to be sharp while the RFeAsO (R=La, Nd, Pr, Sm)…