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Related papers: Segregation of Polymers in Confined Spaces

200 papers

A number of recent experiments have provided detailed observations of the configurations of long DNA strands under nano-to-micrometer sized confinement. We therefore revisit the problem of an excluded volume polymer chain confined between…

Soft Condensed Matter · Physics 2011-03-23 Debasish Chaudhuri , Bela Mulder

We investigate the dynamics of a particle moving randomly along a disordered hetero-polymer subjected to rapid conformational changes which induce superdiffusive motion in chemical coordinates. We study the antagonistic interplay between…

Statistical Mechanics · Physics 2009-11-10 D. Brockmann , T. Geisel

We study mixtures of self-propelled and passive rod-like particles in two dimensions using Brownian dynamics simulations. The simulations demonstrate that the two species spontaneously segregate to generate a rich array of dynamical domain…

Soft Condensed Matter · Physics 2015-03-13 Samuel R. McCandlish , Aparna Baskaran , Michael F. Hagan

Spherical confinement can act either stabilizing or destabilizing on the collapsed state of a semi-flexible polymer. General free-energy arguments suggest that the order of the unconstrained collapse transition is the distinguishing factor:…

Soft Condensed Matter · Physics 2018-11-14 Martin Marenz , Johannes Zierenberg , Wolfhard Janke

We report the results of Monte Carlo simulations investigating the effect of a spherical confinement within a simple model for a flexible homopolymer. We use the parallel tempering method combined with multi-histogram reweighting analysis…

Soft Condensed Matter · Physics 2012-12-27 M. Marenz , J. Zierenberg , H. Arkin , W. Janke

Recent research has shown that motile cells can adapt their mode of propulsion depending on the environment in which they find themselves. One mode is swimming by blebbing or other shape changes, and in this paper we analyze a class of…

Fluid Dynamics · Physics 2016-10-10 Qixuan Wang , Hans G. Othmer

Given the wide range of length scales, the analysis of polymer systems often requires coarse-graining, for which various levels of description may be possible depending on the phenomenon under consideration. Here, we provide a super-coarse…

Soft Condensed Matter · Physics 2024-09-05 Naoki Iso , Yuki Norizoe , Takahiro Sakaue

We study the dynamics of a polymer when it is quenched from a $\theta$ solvent into a good or bad solvent by means of a Langevin equation. The variation of the radius of gyration is studied as a function of time. For the first stage of…

Soft Condensed Matter · Physics 2008-02-03 E. Pitard , H. Orland

We study the influence of structural obstacles in a disordered environment on the size and shape characteristics of long flexible polymer macromolecules. We use the model of self-avoiding random walks on diluted regular lattices at the…

Soft Condensed Matter · Physics 2010-11-22 Viktoria Blavatska , Wolfhard Janke

We study analytically the intricate phase behavior of cross-linked $AB$ diblock copolymer melts, which can undergo two main phase transitions due to quenched random constraints: Gelation, i.e., spatially random localization of polymers…

Soft Condensed Matter · Physics 2015-02-10 Alice von der Heydt , Annette Zippelius

We computed the phase-separation behavior and effective interactions of colloid-polymer mixtures in the "protein limit", where the polymer radius of gyration is much larger than the colloid radius. For ideal polymers, the critical colloidal…

Soft Condensed Matter · Physics 2009-11-07 Peter G. Bolhuis , Evert Jan Meijer , Ard A. Louis

We present a theoretical model for predicting the phase behavior of polymer solutions in which phase separation competes with oligomerization. Specifically, we consider scenarios in which the assembly of polymer chains into stoichiometric…

Soft Condensed Matter · Physics 2024-07-31 Tianhao Li , W. Benjamin Rogers , William M. Jacobs

It has been shown that under high cylindrical confinement, two ring polymers with excluded volume interactions between monomers, segregate to two halves of the cylinder to maximize their entropy. In contrast, two ring polymers remain mixed…

We use numerical simulations to examine two-dimensional particle mixtures that strongly phase separate in equilibrium. When the system is externally driven in the presence of quenched disorder, plastic flow occurs in the form of meandering…

Statistical Mechanics · Physics 2009-11-13 A. Libal , C. Reichhardt , C. J. Olson Reichhardt

In this work we studied polymerization-induced self-assembly by means of computer simulations. Using this model, phase diagrams of the micelle states were constructed depending on the polymer concentration and the asymmetry of the…

Soft Condensed Matter · Physics 2020-11-17 Ruslan Shupanov , Pavel Kos , Alexei Gavrilov , Alexander Chertovich

In this paper, we investigate a stochastic model describing the time evolution of a polymerization process. A polymer is a macro-molecule resulting from the aggregation of several elementary sub-units called monomers. Polymers can grow by…

Probability · Mathematics 2018-08-24 Philippe Robert , Wen Sun

We present simulations on a binary blend of bead-spring polymer chains. The introduction of monomer size disparity yields very different relaxation times for each component of the blend. Competition between two different arrest mechanisms,…

Soft Condensed Matter · Physics 2007-05-23 Angel J. Moreno , Juan Colmenero

It has been recently suggested that a totally asymmetric exclusion process with two species on an open chain could exhibit spontaneous symmetry breaking in some range of the parameters defining its dynamics. The symmetry breaking is…

Condensed Matter · Physics 2009-10-28 C. Godreche , J. M. Luck , M. R. Evans , D. Mukamel , S. Sandow , E. R. Speer

We show that spontaneous density segregation in dense systems of aligning circle swimmers is a condensation phenomenon at odds with the phase separation scenarios usually observed in two-dimensional active matter. The condensates, which…

Soft Condensed Matter · Physics 2024-12-20 Yujia Wang , Bruno Ventéjou , Hugues Chaté , Xia-qing Shi

We investigate the phase behaviour of random copolymers melts via large scale Monte Carlo simulations. We observe macrophase separation into A and B--rich phases as predicted by mean field theory only for systems with a very large…

Soft Condensed Matter · Physics 2009-11-07 J. Houdayer , M. Mueller