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Magneto Raman scattering study of the E$_{2g}$ optical phonons in multi-layer epitaxial graphene grown on a carbon face of SiC are presented. At 4.2K in magnetic field up to 33 T, we observe a series of well pronounced avoided crossings…

Materials Science · Physics 2015-05-13 C. Faugeras , M. Amado , P. Kossacki , M. Orlita , M. Sprinkle , C. Berger , W. A. de Heer , M. Potemski

We show that the electron-phonon coupling in graphene, in contrast with the non-relativistic two-dimensional electron gas, leads to shifts in the phonon frequencies that are non-trivial functions of the electronic density. These shifts can…

Strongly Correlated Electrons · Physics 2013-05-29 A. H. Castro Neto , Francisco Guinea

Graphene phonons are measured as a function of electron doping via the addition of potassium adatoms. In the low doping regime, the in-plane carbon G-peak hardens and narrows with increasing doping, analogous to the trend seen in graphene…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 C. A. Howard , M. P. M. Dean , F. Withers

We present the results of a neutron scattering study of the high energy phonons in the superconducting graphite intercalation compound CaC$_6$. The study was designed to address hitherto unexplored aspects of the lattice dynamics in…

The doping of graphene to tune its electronic structure is essential for its further use in carbon based electronics. Adapting strategies from classical silicon based semiconductor technology, we use the incorporation of heteroatoms in the…

Density functional perturbation theory is used to analyze electron-phonon interaction in bilayer graphene. The results show that phonon scattering in bilayer graphene bears more resemblance with bulk graphite than monolayer graphene. In…

Mesoscale and Nanoscale Physics · Physics 2010-11-29 K. M. Borysenko , J. T. Mullen , X. Li , Y. G. Semenov , J. M. Zavada , M. Buongiorno Nardelli , K. W. Kim

We have investigated the effects of ozone treatment on graphene by Raman scattering. Sequential ozone short-exposure cycles resulted in increasing the $p$ doping levels as inferred from the blue shift of the 2$D$ and $G$ peak frequencies,…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 F. Alzina , H. Tao , J. Moser , Y. Garcia , A. Bachtold , C. M. Sotomayor-Torres

Superconductivity in graphite intercalated compounds has been studied for more than 40 years and it is still not fully understood, despite the recent progress and the discovery of relatively high Tc superconductivity in CaC6 and YbC6.…

Superconductivity · Physics 2009-04-14 T. Valla , J. Camacho , Z-H. Pan , A. V. Fedorov , A. C. Walters , C. A. Howard , M. Ellerby

The out-of-plane intercalate phonons of superconducting YbC6 have been measured with inelastic x-ray scattering. Model fits to this data, and previously measured out-of-plane intercalate phonons in graphite intercalation compounds (GICs),…

Superconductivity · Physics 2015-05-20 M. H. Upton , T. R. Forrest , A. C. Walters , C. A. Howard , M. Ellerby , A. H. Said , D. F. McMorrow

We present an ab initio computational approach for the calculation of resonant Raman intensities, including both excitonic and non-adiabatic effects. Our diagrammatic approach, which we apply to two prototype, semiconducting layered…

Mesoscale and Nanoscale Physics · Physics 2020-10-01 Sven Reichardt , Ludger Wirtz

An experimental study of Raman scattering in N-layer graphene as a function of the top layer doping is reported. At high doping level, achieved by a CHF_3 plasma treatment, we observe a splitting of the $G$ band in the spectra of bilayer…

Mesoscale and Nanoscale Physics · Physics 2010-03-23 M. Bruna , S. Borini

The low energy phonons of two different graphite intercalation compounds (GICs) have been measured as a function of temperature using inelastic x-ray scattering (IXS). In the case of the non-superconductor BaC6, the phonons observed are…

We use first-principles density-functional calculations to determine the frequency shift of the A$'_1$-${\bf K}$ phonon (Raman D band) in monolayer graphene, as a function of the charge doping. A detailed DFT study on the electron-phonon…

Materials Science · Physics 2007-05-23 Srijan Kumar Saha , U. V. Waghmare , H. R. Krishnamurthy , A. K. Sood

The role of electron-phonon interactions is experimentally and theoretically investigated near the saddle point absorption peak of graphene. The differential optical transmission spectra of multiple, non-interacting layers of graphene…

Room temperature Raman scattering measurements have been carried out on well characterized samples of MgB2-xCx. The Raman line corresponding to the E2g phonon mode shows progressive hardening from 620 cm-1 in pristine MgB2 to 775 cm-1 in…

Superconductivity · Physics 2009-11-11 T. Sakuntala , A. Bharathi , S. K. Deb , N. Gayathri , C. S. Sundar , Y. Hariharan

Motivated by the recent discovery of superconductivity in Ca- and Yb-intercalated graphite (CaC$_{6}$ and YbC$_{6}$) and from the ongoing debate on the nature and role of the interlayer state in this class of compounds, in this work we…

Superconductivity · Physics 2016-08-14 Lilia Boeri , Giovanni B. Bachelet , Matteo Giantomassi , Ole K. Andersen

The occurrence of non-adiabatic effects in the vibrational properties of metals have been predicted since the 60's, but hardly confirmed experimentally. We report the first fully \emph{ab initio} calculations of non-adiabatic frequencies of…

Materials Science · Physics 2009-11-13 A. Marco Saitta , Michele Lazzeri , Matteo Calandra , Francesco Mauri

Far from resonance, the coupling of the G-band phonon to magneto-excitons in single layer graphene displays kinks and splittings versus filling factor that are well described by Pauli blocking and unblocking of inter- and intra- Landau…

Mesoscale and Nanoscale Physics · Physics 2014-05-29 Sebastian Rémi , Bennett B. Goldberg , Anna K. Swan

The aim of this model study of the electron-phonon coupling in graphene was to find out about the relative importance of the inter- and intraband scattering and which phonon modes are the most active. This was achieved by analyzing the…

Mesoscale and Nanoscale Physics · Physics 2016-09-21 H. Toren , L. Samuelsson , B. Hellsing

Following the work in graphene, we report a first-principles study of electron-phonon coupling (EPC) in low-buckled (LB) monolayer silicene and germanene. Despite of the similar honeycomb atomic arrangement and linear band dispersion, the…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Jia-An Yan , Ryan Stein , David M. Schaefer , Xiao-Qian Wang , M. Y. Chou
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