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We study the interaction potential between two polyions inside a colloidal suspension. It is shown that at large separation the interaction potential is purely repulsive, with the induced attractive interactions being doubly screened. For…

Soft Condensed Matter · Physics 2015-06-25 Yan Levin

Over the past few decades the experimental literature has consistently reported observations of attraction between like-charged colloidal particles and macromolecules in solution. Examples include nucleic acids and colloidal particles in…

Soft Condensed Matter · Physics 2020-04-22 Alzbeta Kubincova , Philippe H. Hunenberger , Madhavi Krishnan

We present guidelines to estimate the effect of electrostatic repulsion in sedimenting dilute particle suspensions. Our results are based on combined Langevin dynamics and lattice Boltzmann simulations for a range of particle radii, Debye…

Equation of state for systems with particles self-assembling into aggregates is derived within a mesoscopic theory combining density functional and field-theoretic approaches. We focus on the effect of mesoscopic fluctuations in the…

Statistical Mechanics · Physics 2012-07-13 Alina Ciach , Oksana Patsahan

We study self-diffusion and sedimentation in colloidal suspensions of nearly-hard spheres using the multiparticle collision dynamics simulation method for the solvent with a discrete mesh model for the colloidal particles (MD+MPCD). We…

Soft Condensed Matter · Physics 2022-01-26 Yashraj M. Wani , Penelope Grace Kovakas , Arash Nikoubashman , Michael P. Howard

Shear thickening of particle suspensions is characterized by a transition between lubricated and frictional contacts between the particles. Using 3D numerical simulations, we study how the inter-particle friction coefficient influences the…

Soft Condensed Matter · Physics 2020-01-08 Vishnu Sivadasan , Eric Lorenz , Alfons G. Hoekstra , Daniel Bonn

Sedimentation in active fluids has come into focus due to the ubiquity of swimming micro-organisms in natural and artificial environments. Here, we experimentally investigate sedimentation of passive particles in water containing various…

Fluid Dynamics · Physics 2017-10-12 Jaspreet Singh , Alison E. Patteson , Prashant K. Purohit , Paulo E. Arratia

We investigate the combined effects of electrostatic interactions and hydrodynamic interactions on the short-time rotational self-diffusion coefficient in charge-stabilized suspensions. We calculate this coefficient as a function of volume…

Condensed Matter · Physics 2015-06-25 M. Watzlawek , G. Naegele

Recent work on charged colloidal suspensions with very low levels of added salt has suggested that although pairs of the colloidal particles repel, clusters of the particles attract. Motivated by this, we study simple model particles which…

Soft Condensed Matter · Physics 2009-10-31 Richard P. Sear

We present a numerical study of the effect that fluid and particle inertia have on the motion of suspended spherical particles through a geometric constriction to understand analogous microfluidic settings, such as pinched flow…

Fluid Dynamics · Physics 2013-06-20 Sumedh R. Risbud , Mingxiang Luo , Joelle Frechette , German Drazer

We propose a mean-field analytical model to account for the observed asymmetry in the ability to form long-range attraction by the negatively charged colloidal particles and not their equivalently charged positive counterpart. We conjecture…

Soft Condensed Matter · Physics 2009-11-13 William Kung , Monica Olvera de la Cruz

In order to asses the effect of hydrodynamics in the assembly of active attractive spheres, we simulate a semi-dilute suspension of attractive self-propelled spherical particles in a quasi two dimensional geometry comparing the case with…

Soft Condensed Matter · Physics 2016-12-15 Francisco Alarcón , Chantal Valeriani , Ignacio Pagonabarraga

Contacts between particles in dense, sheared suspensions are believed to underpin much of their rheology. Roughness and adhesion are known to constrain the relative motion of particles, and thus globally affect the shear response, but an…

Many biological systems fold thin sheets of lipid membrane into complex three-dimensional structures. This microscopic origami is often mediated by the adsorption and self-assembly of proteins on a membrane. As a model system to study…

Soft Condensed Matter · Physics 2016-10-11 Raphael Sarfati , Eric R. Dufresne

We study the rheology of a soft particulate system where the inter-particle interactions are weakly attractive. Using extensive molecular dynamics simulations, we scan across a wide range of packing fractions ($\phi$), attraction strengths…

Soft Condensed Matter · Physics 2016-11-30 Ehsan Irani , Pinaki Chaudhuri , Claus Heussinger

Colloidal particles, amphiphiles, and functionalized nanoparticles are examples of systems that frequently exhibit short-range attractions coupled with long-range repulsions. In this work, we observe striking differences in the dynamics of…

Soft Condensed Matter · Physics 2017-06-01 Jakub Pȩkalski , Andrew P. Santos , Athanassios Z. Panagiotopoulos

We report a detailed experimental study of the structure and dynamics of glassy states in hard spheres with short-range attraction. The system is a suspension of nearly-hard-sphere colloidal particles and non-adsorbing linear polymer which…

Soft Condensed Matter · Physics 2009-11-10 K. N. Pham , S. U. Egelhaaf , P. N. Pusey , W. C. K. Poon

We present Monte Carlo simulations of colloidal particles pulled into grafted polymer layers by external fields. The insertion free energy of a single colloid into the polymer layer is qualitatively different for surfaces with an ordered…

Soft Condensed Matter · Physics 2012-10-17 Tine Curk , Francisco J. Martinez-Veracoechea , Daan Frenkel , Jure Dobnikar

In the absence of directional motion it is often hard to recognize athermal fluctuations. Probability currents provide such a measure in terms of the rate at which they enclose area in the reduced phase space. We measure this area enclosing…

In recent years, there has been considerable interest in understanding the motion in Hamiltonian systems when phase space is divided into stochastic and integrable regions. This paper studies one aspect of this problem, namely, the motion…

Chaotic Dynamics · Physics 2007-05-23 Charles F. F. Karney