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The classical theory of Laplace is not suitable for describing the behavior of microscopic bubbles. The theory of second gradient fluids (which are able to exert shear stresses in equilibrium conditions) allows us to obtain a new expression…

Classical Physics · Physics 2008-08-05 Francesco Dell'Isola , Henri Gouin , Pierre Seppecher

The phase field theory of crystal nucleation described in [L. Granasy, T. Borzsonyi, T. Pusztai, Phys. Rev. Lett. 88, 206105 (2002)] is applied for nucleation in hard--sphere liquids. The exact thermodynamics from molecular dynamics is…

Statistical Mechanics · Physics 2009-11-10 Laszlo Granasy , Tamas Pusztai , Zoltan Jurek , Massimo Conti , Bjorn Kvamme

Phase field models for two-phase flow with a surfactant soluble in possibly both fluids are derived from balance equations and an energy inequality so that thermodynamic consistency is guaranteed. Via a formal asymptotic analysis, they are…

Fluid Dynamics · Physics 2013-03-12 Harald Garcke , Kei Fong Lam , Björn Stinner

Diffuse-interface theory provides a foundation for the modeling and simulation of microstructure evolution in a very wide range of materials, and for the tracking/capturing of dynamic interfaces between different materials on larger scales.…

Computational Physics · Physics 2018-08-03 Zhijie Xu , Paul Meakin , Alexandre Tartakovsky

Colloidal particles that are confined to an interface such as the air-water interface are an example of a two-dimensional fluid. Such dispersions have been observed to spontaneously form cluster and stripe morphologies in certain systems…

Soft Condensed Matter · Physics 2008-09-17 A. J. Archer

We investigate the energetics of droplets sourced by the thermal fluctuations in a system undergoing a first-order transition. In particular, we confine our studies to two dimensions with explicit calulations in the plane and on the sphere.…

Statistical Mechanics · Physics 2018-06-27 Eric M. Horsley , Maxim O. Lavrentovich , Randall D. Kamien

The present paper proposes a two-phase flow model that is able to account for two-scale kinematics and two-scale surface tension effects based on geometric variables at small scale. At large scale, the flow and the full geometry of the…

Fluid Dynamics · Physics 2019-11-01 Pierre Cordesse , Samuel Kokh , Ruben Di Battista , Florence Drui , Marc Massot

A thermomechanical model of continuous fluid media based on second gradient theory is used to study motions in liquid-vapor interfaces. At equilibrium, the model is shown to be equivalent to mean-field molecular theories of capillarity. In…

Fluid Dynamics · Physics 2011-08-17 Henri Gouin

In the study of crystal nucleation via computer simulations, hard spheres are arguably the most extensively explored model system. Nonetheless, even in this simple model system, the complex thermodynamics of crystal nuclei can sometimes…

Soft Condensed Matter · Physics 2025-02-19 Marjolein de Jager , Carlos Vega , Pablo Montero de Hijes , Frank Smallenburg , Laura Filion

Nucleation on top of two-dimensional islands with step edge barriers is investigated using scaling arguments. The nucleation rate is expressed in terms of three basic time scales: The time interval between deposition events, the residence…

Materials Science · Physics 2009-10-31 Joachim Krug

We theoretically investigate the nucleation of liquid droplets from vapor in the presence of a charged spherical particle. Due to field gradients, sufficiently close to the critical point of the vapor--gas system, the charge destabilizes…

Chemical Physics · Physics 2021-11-04 Roni Kroll , Yoav Tsori

The dynamics of phase transitions plays a crucial r\^ole in the so-called interface between high energy particle physics and cosmology. Many of the interesting results generated during the last fifteen years or so rely on simplified…

High Energy Physics - Phenomenology · Physics 2007-05-23 Marcelo Gleiser

We introduce a shell-model theory that combines traditional spherical states, which yield a diagonal representation of the usual single-particle interaction, with collective configurations that track deformations, and test the validity of…

Nuclear Theory · Physics 2009-11-07 V. G. Gueorguiev , W. E. Ormand , C. W. Johnson , J. P. Draayer

Numerical methods for the simulation of cavitation processes have been developed for more than 50 years. The rich variety of physical phenomena triggered by the collapse of a bubble has several applications in medicine and environmental…

Fluid Dynamics · Physics 2024-04-30 Mandeep Saini , Lucas Prouvost , Stephane Popinet , Daniel Fuster

Surface tension plays a ubiquitous role in phase transitions including condensation or evaporation of atmospheric liquid droplets. Especially, understanding of interfacial thermodynamics of the critical nucleus of 1 nm scale is important…

Soft Condensed Matter · Physics 2020-04-28 QHwan Kim , Wonho Jhe

Combining three numerical methods (forward flux sampling, seeding of droplets, and finite size droplets), we probe the crystallization of hard spheres over the full range from close to coexistence to the spinodal regime. We show that all…

Soft Condensed Matter · Physics 2018-08-17 David Richard , Thomas Speck

The classical nucleation theory (CNT) concept of a nucleus as a fragment of the bulk new phase fails for nanosized nuclei. An extension of CNT taking into account the properties of the transition region between coexisting bulk phases is…

Chemical Physics · Physics 2017-06-09 Nikolay V. Alekseechkin

This article presents a multi-physics methodology for the numerical simulation of physical systems that involve the non-linear interaction of multi-phase reactive fluids and elastoplastic solids, inducing high strain-rates and high…

Computational Physics · Physics 2021-06-04 Tim Wallis , Philip T. Barton , Nikolaos Nikiforakis

The development and validation of 3D multiphase computational fluid dynamics (M-CFD) models and physics-informed data-driven modeling require data of high-quality and high-resolution. Considering the difficulties in acquiring the…

Fluid Dynamics · Physics 2020-09-01 Mengnan Li , Joachim Moortgat , Igor A. Bolotnov

We present numerical simulation of 2D turbulent flow using a new model for the subgrid scales which are computed using a dynamic equation linking the subgrid scales with the resolved velocity. This equation is not postulated, but derived…

Fluid Dynamics · Physics 2009-11-07 J. -P. Laval , B. Dubrulle , S. Nazarenko
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