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A tight binding model for scanning tunneling microscopy images of a molecule adsorbed on a metal surface is described. The model is similar in spirit to that used to analyze conduction along molecular wires connecting two metal leads and…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Yoel Calev , Hezy Cohen , Gianaurelio Cuniberti , Abraham Nitzan , Danny Porath

A general formula for the orbital magnetic moment of interacting electrons in solids is derived using the many-electron Green function method. The formula factorizes into two parts, a part that contains the information about the…

Materials Science · Physics 2016-04-20 F. Aryasetiawan , K. Karlsson , T. Miyake

A transferable tight-binding potential has been constructed for heteroatomic systems containing carbon and hydrogen. The electronic degree of freedom is treated explicitly in this potential using a small set of transferable parameters which…

chem-ph · Physics 2008-02-03 Yang Wang , C. H. Mak

Photonics, dealing with the generation, manipulation, and detection of photons in various systems, lays the foundation of many advanced technologies. A key task of photonics is to know how photons propagate in complex media such as periodic…

Electronic transport properties through some model quantum systems are re-visited. A simple tight-binding framework is given to describe the systems where all numerical calculations are made using the Green's function formalism. First, we…

Mesoscale and Nanoscale Physics · Physics 2015-03-19 Santanu K. Maiti

An effective Hamiltonian is considered for hydrogen bonding between two molecules due to the quantum mechanical interaction between the orbitals of the H-atom and the donor and acceptor atoms in the molecules. The Hamiltonian acts on two…

Chemical Physics · Physics 2012-04-03 Ross H. McKenzie

We consider a polaron model where molecular \emph{rotations} are important. Here, the usual hopping between neighboring sites is affected directly by the electron-phonon interaction via a {\em twist-dependent} hopping amplitude. This model…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Wei Zhang , Alexander O. Govorov , Sergio E. Ulloa

Solid state physics deals with systems composed of atoms with strongly bound electrons. The tunneling probability of each electron is determined by interactions that typically extend to neighboring sites, as their corresponding wave…

Materials Science · Physics 2019-11-27 F. Ramírez-Ramírez , E. Flores-Olmedo , G. Báez , E. Sadurní , R. ~A. Méndez-Sánchez

This document contains information supplementary to the article [1], but it is self-contained and can be read independently as a pedagogical review. In the first part, we explain our conventions for the tight-binding description of…

Strongly Correlated Electrons · Physics 2016-02-10 G. A. H. Schober , K. -U. Giering , M. M. Scherer , C. Honerkamp , M. Salmhofer

We investigate the conformation-dependent electron transfer in a biphenyl molecule within a simple tight-binding framework. The overall junction current and circular currents in two benzene rings driven by applied bias voltage are…

Mesoscale and Nanoscale Physics · Physics 2013-07-02 Santanu K. Maiti

By deriving a tight-binding model, we demonstrate a mechanism of forming a nodal line of Dirac points in a single-component molecular conductor [Pt(dmtd)$_2$] [Zhou {\it et al.}, Chem. Commun. {\bfseries 55}, 3327 (2019)], consisting of…

Materials Science · Physics 2020-04-01 Reizo Kato , Yoshikazu Suzumura

We present a further development of methods for analytical calculations of Green's functions of lattice fermions based on recurrence relations. Applying it to tight-binding systems and topological superconductors in different dimensions we…

Mesoscale and Nanoscale Physics · Physics 2017-10-11 A. Komnik , S. Heinze

We discuss the general form of the transmission spectrum through a molec- ular junction in terms of the Green function of the isolated molecule. By introducing a tight binding method, we are able to translate the Green func- tion properties…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Daniel A. Lovey , Rodolfo H. Romero

We present a technique to map an electronic model with local interactions (a generalized multi-orbital Hubbard model) onto an effective model of interacting classical spins, by requiring that the thermodynamic potentials associated to spin…

Strongly Correlated Electrons · Physics 2015-05-27 Andrea Secchi , Alexander I. Lichtenstein , Mikhail I. Katsnelson

The intersection of electronic topology and strong correlations offers a rich platform to discover exotic quantum phases of matter and unusual materials. An overarching challenge that impedes the discovery is how to diagnose topology in…

Strongly Correlated Electrons · Physics 2023-11-28 Chandan Setty , Fang Xie , Shouvik Sur , Lei Chen , Silke Paschen , Maia G. Vergniory , Jennifer Cano , Qimiao Si

Various properties of the general two-center two-electron integral over the explicitly correlated exponential function are analyzed for the potential use in high precision calculations for diatomic molecules. A compact one dimensional…

Chemical Physics · Physics 2015-06-11 Krzysztof Pachucki

The screened electron-electron interaction in a multi-band electron system is calculated within the random phase approximation and in the tight-binding representation. The obtained dielectric matrix contains, beside the usual site-site…

Condensed Matter · Physics 2009-10-28 P. Zupanovic , A. Bjelis , S. Barisic

Non-local communication among position based qubits is described for the system of the quantum electromagnetic resonator entangled to two semiconductor electrostatic qubits via interaction between matter and radiation by Jaynes-Cummings…

Quantum Physics · Physics 2020-07-15 Krzysztof Pomorski , Robert Bogdan Staszewski

The basic concepts of orbital entanglement and its application to chemistry are briefly reviewed. The calculation of orbital entanglement measures from correlated wavefunctions is discussed in terms of reduced $n$-particle density matrices.…

Chemical Physics · Physics 2016-10-05 Katharina Boguslawski , Paweł Tecmer

This is the second of two papers devoted to tight-binding electronic spectra on graphs with the topology of the sphere. We investigate the problem of an electron subject to a spin-orbit interaction generated by the radial electric field of…

Mesoscale and Nanoscale Physics · Physics 2008-06-13 Y. Avishai , J. M. Luck