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Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…

Astrophysics of Galaxies · Physics 2015-05-14 H. M. Cuppen , E. F. van Dishoeck , E. Herbst , A. G. G. M. Tielens

We have studied the influence of X-rays from a massive young stellar object (YSO) on the chemistry of its own envelope by extending the models of Doty et al. (2002) and Staeuber et al. (2004). The models are applied to the massive…

Astrophysics · Physics 2007-05-23 P. Staeuber , A. O. Benz , S. D. Doty , E. F. van Dishoeck

We combine Herschel observations of a total of 12 sources to construct the most uniform survey of HF and H2O in our Galactic disk. Both molecules are detected in absorption along all sight lines. The high spectral resolution of the…

Astrophysics of Galaxies · Physics 2015-06-11 P. Sonnentrucker , M. Wolfire , D. A. Neufeld , N. Flagey , M. Gerin , P. Goldsmith , D. Lis , R. Monje

We report the results of initial FUSE observations of molecular hydrogen (H2) in translucent clouds. These clouds have greater optical depth than any of the diffuse clouds previously observed for far-UV H2 absorption, and provide new…

Hydrides are simple compounds containing one or a few hydrogen atoms bonded to a heavier atom. They are fundamental precursor molecules in cosmic chemistry and many hydride ions have become observable in high quality for the first time…

The transition between atomic and molecular hydrogen is associated with important changes in the structure of interstellar clouds, and marks the beginning of interstellar chemistry. Because of the relatively simple networks controlling…

Astrophysics of Galaxies · Physics 2019-01-30 M. Gerin , H. Liszt , D. Neufeld , B. Godard , P. Sonnentrucker , J. Pety , E. Roueff

A solar-type system starts from an initial molecular core that acquires organic complexity as it evolves. The so-called prestellar cores that can be studied are rare, which has hampered our understanding of how organic chemistry sets in and…

Carbon monoxide (CO) is a poor tracer of H$_{2}$ in the diffuse interstellar medium (ISM), where most of the carbon is not incorporated into CO molecules unlike the situation at higher extinctions. We present a novel, indirect method to…

Astrophysics of Galaxies · Physics 2023-12-18 Raphael Skalidis , Paul F. Goldsmith , Philip F. Hopkins , Sam B. Ponnada

The Herschel Space Observatory opens the sky for observations in the far infrared at high spectral and spatial resolution. A particular class of molecules will be directly observable; light diatomic hydrides and their ions (CH, OH, SH, NH,…

Solar and Stellar Astrophysics · Physics 2010-07-21 Simon Bruderer , Arnold O. Benz , P. Stäuber , Steven D. Doty

We have analyzed the archival data of FUV observations for the region of GSH 006-15+7, a large shell-like structure discovered by Moss et al. (2012) from the H I velocity maps. FUV emission is seen to be enhanced in the lower supershell…

Astrophysics of Galaxies · Physics 2015-05-25 Young-Soo Jo , Kyoung-Wook Min , Kwang-Il Seon

We present results from high-resolution three-dimensional simulations of turbulent interstellar gas that self-consistently follow its coupled thermal, chemical and dynamical evolution, with a particular focus on the formation and…

Solar and Stellar Astrophysics · Physics 2015-05-13 S. C. O. Glover , C. Federrath , M. -M. Mac Low , R. S. Klessen

We extend the analytic theory presented by Sternberg et al. (2014) and Bialy & Sternberg (2016) for the production of atomic hydrogen (HI) via FUV photodissociation at the boundaries of dense interstellar molecular (H$_2$) clouds, to also…

Astrophysics of Galaxies · Physics 2023-10-18 Amiel Sternberg , Shmuel Bialy , Alon Gurman

Detections of molecular lines, mainly from H2$ and CO, reveal molecular material in planetary nebulae. Observations of a variety of molecules suggest that the molecular composition in these objects differs from that found in interstellar…

Astrophysics of Galaxies · Physics 2012-06-28 Rafael K. Kimura , Ruth Gruenwald , Isabel Aleman

Deuterium fractionation in molecular ions, in particular HCO+, has been extensively used to estimate the degree of ionization in molecular clouds. This paper reviews recent work on ionization degree in homogeneous clouds. We will show that…

Astrophysics · Physics 2009-11-07 Paola Caselli

Dense gas is important for galaxy evolution and star formation. Optically-thin dense-gas tracers, such as isotopologues of HCN, HCO+, etc., are very helpful to diagnose excitation conditions of dense molecular gas. However, previous studies…

Astrophysics of Galaxies · Physics 2022-08-03 Fei Li , Zhi-Yu Zhang , Junzhi Wang , Feng Gao , Shanghuo Li , Jing Zhou , Yichen Sun , Ziyi Guo , Shu Liu

We study the physical properties and molecular excitation of the different warm gas components found in the protoplanetary nebula CRL 618. We revise our previous Herschel/HIFI observations, which consist of several 12CO and 13CO lines in…

Solar and Stellar Astrophysics · Physics 2015-06-17 R. Soria-Ruiz , V. Bujarrabal , J. Alcolea

We have studied the influence of far ultraviolet (UV) radiation from a massive young stellar object (YSO) on the chemistry of its own envelope by extending the models of Doty et al. (2002) to include a central source of UV radiation. The…

Astrophysics · Physics 2009-11-10 P. Stauber , S. D. Doty , E. F. van Dishoeck , J. K. Jorgensen , A. O. Benz

We have developed a code that models the formation, destruction, radiative transfer, and vibrational/rotational excitation of H_2 in a detailed fashion. We discuss how such codes, together with FUSE observations of H_2 in diffuse and…

Astrophysics · Physics 2009-11-07 Matthew K. Browning , Jason Tumlinson , J. Michael Shull

There is a robust polyatomic chemistry in diffuse, partially-molecular interstellar gas that is readily accessible in absorption at radio/mm/sub-mm wavelengths. Accurate column densities are derived owing to the weak internal excitation, so…

Astrophysics of Galaxies · Physics 2023-02-15 Harvey Liszt , Maryvonne Gerin

We report the first ensemble results from the FUSE survey of molecular hydrogen in lines of sight with A_V $\gtrsim$ 1 mag. We have developed techniques for fitting computed profiles to the low-J lines of H2, and thus determining column…