Related papers: Nonequilibrium, thermostats and thermodynamic limi…
Thermostats models in space dimension $d=1,2,3$ for nonequilibrium statistical mechanics are considered and it is shown that, in the thermodynamic limit, the motions of frictionless thermostats and isokinetic thermostats coincide.
The relation between isoenergetic and Hamiltonian thermostats is studied and their equivalence in the thermodynamic limit is proved in space dimension $d=1,2$. v.2: W_n and x_n replace W and x where needed
Thermostats models in space dimension d=1,2,3 for nonequilibrium statistical mechanics are considered and it is shown that, in the thermodynamic limit, the evolutions admit infinitely many constants of motion: namely the intensive…
The Gaussian isokinetic and isoenergetic thermostats of Hoover and Evans are formally equivalent as remarked by Gallavotti, Rondoni and Cohen. But outside of equilibrium the fluctuations are uncontrolled and might break the equivalence. We…
The relation between finite isokinetic thermostats and infinite Hamiltonian thermostats is studied and their equivalence is heuristically discussed.
We have constructed a nonextensive thermodynamic formalism consisting of two sets of parallel Legendre transformation structures in previous papers. One is the physical set and the other is the Lagrange set. In this paper we study the…
Thermodynamic length is a metric distance between equilibrium thermodynamic states. Among other interesting properties, this metric asymptotically bounds the dissipation induced by a finite time transformation of a thermodynamic system. It…
We study continuity, and lack thereof, of thermodynamical properties for one-dimensional dynamical systems. Under quite general hypotheses, the free energy is shown to be almost upper-semicontinuous: some normalised component of a limit…
The meaning of temperature in nonequilibrium thermodynamics is considered by using a forced harmonic oscillator in a heat bath, where we have two effective temperatures for the position and the momentum, respectively. We invent a concrete…
Nonequilibrium thermodynamics has shown its applicability in a wide variety of different situations pertaining to fields such as physics, chemistry, biology, and engineering. As successful as it is, however, its current formulation…
Nonequilibrium molecular dynamics simulations often use mechanisms called thermostats to regulate the temperature. A Hamiltonian is presented for the case of the isoenergetic (constant internal energy) thermostat corresponding to a tunable…
We consider the models of relaxational dynamics within the framework of Berendsen's and Nose-Hoover's thermostats. On studying the crucial case of ideal gas we come to the conclusion that both models mentioned above do not allow for…
The thermodynamics is studied with the thermodynamic parameter of the lifetime, first-passage time, generalizing the equilibrium thermodynamics. Various ways of describing several stationary nonequilibrium states in the system are…
By considering a thermodynamic force as gauge field, we extend constitutive equations of Onsager's non-equilibrium thermodynamics to non-linear equations. In Onsager's non-equilibrium thermodynamics, the thermodynamic force corresponds to a…
Small thermodynamic systems exhibit peculiar behavior different from that observed in long-scale systems. Non-equilibrium processes taking place in those systems are strongly influenced by the presence of fluctuations which can be large.…
We study the problem of a potential interaction of a finite-dimensional Lagrangian system (an oscillator) with a linear infinite-dimensional one (a thermostat). In spite of the energy preservation and the Lagrangian (Hamiltonian) nature of…
Abstract: Models for studying systems in stationary states but out of equilibrium have often empirical nature and very often break the fundamental time reversal symmetry. Here a formal interpretation will be discussed of the widespread idea…
The thermodynamic properties of a nonrelativistic free-electron Fermi gas is of fundamental interest in condensed matter physics. Properties previously studied in three-dimensions (3D) in the low- and high-temperature limits include the…
The nonextensive thermodynamic relations are expressed under the assumption of temperature duality, endowing the "physical temperature" and the "Lagrange temperature" in different physical sense. Based on this assumption, two sets of…
This short paper presents a nontechnical introduction to the problem of nonequivalent microcanonical and canonical ensembles. Both the thermodynamic and the macrostate levels of definition of nonequivalent ensembles are introduced. The many…