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Nanoconfined liquid crystals (LCs) and their nanocomposites are driving the next generation of photonic applications. Consequently, deepening our understanding of mesophase stability, defect topology, and the dynamic response of LCs at the…

The ferroelectric nematic phase (NF) is a recently discovered phase of matter in which the orientational order of the conventional nematic liquid crystal state is augmented with polar order. Atomistic simulations suggest that the polar NF…

Soft Condensed Matter · Physics 2023-09-26 Charles Parton-Barr , Helen Gleeson , Richard Mandle

We demonstrate that a first order isotropic-to-nematic phase transition in liquid crystals can be succesfully modeled within the generalized Landau-de Gennes theory by selecting an appropriate combination of elastic constants. The numerical…

Soft Condensed Matter · Physics 2019-02-19 Dmitry Golovaty , Young-Ki Kim , Oleg D. Lavrentovich , Michael Novack , Peter Sternberg

We report filling-fraction dependent dielectric spectroscopy measurements on the relaxation dynamics of the rod-like nematogen 7CB condensed in 13 nm silica nanochannels. In the film-condensed regime, a slow interface relaxation dominates…

Soft Condensed Matter · Physics 2015-04-21 Sylwia Calus , Andriy V. Kityk , Manfred Eich , Patrick Huber

Single crystal nematic elastomers undergo a transition from a strongly ordered phase N to an "isotropic" phase I. We show that: (a) samples produced under tension by the Finkelmann procedure are intrinsically anisotropic and should show a…

Soft Condensed Matter · Physics 2009-11-10 Pierre-Gilles de Gennes , Ko Okumura

Ferronematic phases, composed of liquid crystals doped with magnetic nanoparticles, exhibit unique magnetomechanical coupling effects that are of interest for responsive materials. In this study, we investigate the influence of…

Microstructure, phase transitions, electrical conductivity, and optical and electrooptical properties of multiwalled carbon nanotubes (NTs), dispersed in the cholesteric liquid crystal (cholesteryl oleyl carbonate, COC), nematic 5CB and…

Vapor pressure grows rapidly above the boiling temperature, and past the critical point liquid droplets disintegrate. Our atomistic simulations show that this sequence of events is reversed inside carbon nanotubes (CNT). Droplets…

Materials Science · Physics 2012-02-07 Vitaly V. Chaban , Victor V. Prezhdo , Oleg V. Prezhdo

The confining effect of a spherical substrate inducing anchoring (normal to the surface) of rod-like liquid crystal molecules contained in a thin film spread over it has been investigated with regard to possible changes in the nature of the…

Soft Condensed Matter · Physics 2015-05-20 D. Jayasri , T. Sairam , V. S. S. Sastry , K. P. N. Murthy

We report on strong pretransitional effects across the isotropic liquid-plastic crystal melting temperature in linear and nonlinear dielectric response. Studies were carried out for cyclooctanol (C8H16O) in the unprecedented range of…

Soft Condensed Matter · Physics 2019-12-10 A. Drozd-Rzoska , S. Starzonek , S. J. Rzoska , J. Łoś , Z. Kutnjak , S. Kralj

Using first principles calculations, we model the chemical vapor deposition (CVD) growth of carbon nanotubes (CNT) on nanoparticles of late transition (Ni, Pd, Pt) and coinage (Cu, Ag, Au) metals. The process is analyzed in terms of the…

Materials Science · Physics 2008-04-17 Oleg V. Yazyev , Alfredo Pasquarello

The effects of multiwalled carbon nanotubes (NTs) on low-temperature phase transformations in 5CB were studied by means of differential scanning calorimetry (DSC), low-temperature photoluminescence and measurements of electrical…

Soft Condensed Matter · Physics 2015-06-15 N. Lebovka , V. Melnyk , Ye. Mamunya , G. Klishevich , A. Goncharuk , N. Pivovarova

We find in a model system of thermotropic liquid crystals that the translational diffusion coefficient parallel to the director $D_{\parallel}$ first increases and then decreases as temperature drops through the nematic phase, and this…

Soft Condensed Matter · Physics 2009-11-11 Dwaipayan Chakrabarti , Biman Bagchi

In this study, the synthesis of multi-walled carbon nanotubes (MWCNTs) was carried out by chemical vapor deposition (CVD) using propane as the carbon source and Si as the catalyst support. The effect of CVD process variables such as…

Applied Physics · Physics 2018-08-21 Joydip Sengupta

Recently unusual properties of water in single-walled carbon nanotubes (CNT) with diameters ranging from 1.05 nm to 1.52 nm were observed. It was found that water in the CNT remains in an ice-like phase even when the temperature ranges…

Mesoscale and Nanoscale Physics · Physics 2017-03-23 Siddhartha Sen , Kumar S. Gupta

The optical birefringence of rod-like nematogens (7CB, 8CB), imbibed in parallel silica channels with 10 nm diameter and 300 micrometer length, is measured and compared to the thermotropic bulk behavior. The orientational order of the…

Soft Condensed Matter · Physics 2016-09-08 Andriy V. Kityk , Matthias Wolff , Klaus Knorr , Denis Morineau , Ronan Lefort , Patrick Huber

We explore the structure of nuclei and topological defects in the first-order phase transition between the nematic (N) and isotropic (I) phases in lyotropic chromonic liquid crystals (LCLCs). The LCLCs are formed by self-assembled molecular…

Soft Condensed Matter · Physics 2015-06-15 Young-Ki Kim , Sergij V. Shiyanovskii , Oleg D. Lavrentovich

The transition from a nematic to an isotropic state in a self-closing spherical liquid crystal shell with tangential alignment is a stimulating phenomenon to investigate, as the topology dictates that the shell exhibits local isotropic…

Soft Condensed Matter · Physics 2024-02-02 Yucen Han , Jan Lagerwall , Apala Majumdar

During the last half-decade, a new class of ferroic-fluid, ferroelectric nematic liquid crystals (NFLCs), creates a noise owing to its exceptional properties such as a colossal polarization, high electro-optic activity plus high fluidity.…

Recently, laser-assisted chemical vapor deposition was used to synthesize a free-standing, continuous, and stable monolayer amorphous carbon (MAC). MAC is a pure carbon structure composed of randomly distributed five, six, seven, and eight…