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The compounds Ca(Fe1-xNix)2As2 with the tetragonal ThCr2Si2-type structure (space group I4/mmm) show a continuous transition of the interlayer As-As distances from a non-bonding state in CaFe2As2 (dAs-As = 313 pm) to single-bonded…

Strongly Correlated Electrons · Physics 2013-07-17 Roman Pobel , Rainer Frankovsky , Dirk Johrendt

The finding of superconductivity in Ba0.6K0.4Fe2As2 put the attention on the investigation of compounds that crystallize with ThCr2Si2 structure type such as AT2X2 (A = alkali/ alkaline earth/ rare earth element; T = transition metal and X…

Superconductivity · Physics 2012-12-10 Andrea V. Hoffmann , Viktor Hlukhyy , Thomas F. Fässler

The anisotropy of electrical resistivity was measured in parent compounds of the iron-arsenic high temperature superconductors, AEFe2As2 with Alkali Earth elements AE=Ca,Sr, Ba. Measurements were performed using both the Montgomery…

Superconductivity · Physics 2015-05-13 M. A. Tanatar , N. Ni , G. D. Samolyuk , S. L. Bud'ko , P. C. Canfield , R. Prozorov

We present a comprehensive investigation into the physical properties of intermetallic ErPd$_2$Si$_2$, a compound renowned for its intriguing magnetic and electronic characteristics. We confirm the tetragonal crystal structure of…

Strongly Correlated Electrons · Physics 2024-12-30 Kaitong Sun , Si Wu , Guanping Xu , Lingwei Li , Hongyu Chen , Qian Zhao , Muqing Su , Wolfgang Schmidt , Chongde Cao , Hai-Feng Li

The electronic structure and physical properties of the pnictide compound families $RE$OFeAs ($RE$ = La, Ce, Pr, Nd, Sm), $A$Fe$_{2}$As$_{2}$ ($A$ = Ca, Sr, Ba, Eu), LiFeAs and FeSe are quite similar. Here, we focus on the members of the…

The parent compounds of recently discovered iron-arsenide superconductors, $A$Fe$_2$As$_2$ with alkaline earth $A$=Ca, Sr, Ba, undergo simultaneous structural and magnetic phase transitions at a temperature $T_{SM}$. Using a combination of…

Superconductivity · Physics 2009-06-29 M. A. Tanatar , A. Kreyssig , S. Nandi , N. Ni , S. L. Bud'ko , P. C. Canfield , A. I. Goldman , R. Prozorov

The electronic structure of layered Sr$_{3}$Ru$_{2}$O$_{7}$ in its orthorhombic structure is investigated using density functional calculations. The band structure near the Fermi energy, consists of Ru $% t_{2g}$ states hybridized with O…

Superconductivity · Physics 2009-10-31 D. J. Singh , I. I. Mazin

Nematicity, defined as broken rotational symmetry, has recently been observed in competing phases proximate to the superconducting phase in the cuprate high temperature superconductors. Similarly, the new iron-based high temperature…

We use angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) calculations to study the electronic structure of CaFe$_2$As$_2$ in previously unexplored collapsed tetragonal (CT) phase. This unusual phase of…

Electrical resistivity measurements of detwinned single crystals of the representative iron arsenide Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$ reveal a dramatic in-plane anisotropy associated with the tetragonal-to-orthorhombic structural transition…

By means of first-principles calculations, the electronic structure and chemical bonding for the recently discovered tetragonal (s.g. P4/n; # 85) superconducting (Tc ~ 25K) phase Ca10(Pt4As8)(Fe2As2)5 have been examined in details, and the…

Superconductivity · Physics 2011-08-04 I. R. Shein , A. L. Ivanovskii

We explore the structural, electronic, bonding, mechanical, thermodynamic and superconducting properties of two newly discovered isostructural bulk superconductors barium iridium phosphide BaIr2P2 (Tc ~ 2.1 K) and barium iridium arsenide…

Materials Science · Physics 2016-11-22 Md. Zahidur Rahaman , Md. Atikur Rahman

In a joint experimental and theoretical study, we investigate the isostructural collapse from the ambient pressure tetragonal phase to a collapsed tetragonal phase for non-superconducting metallic SrFe2As2 and SrFe_1.8Ru_0.2As_2. The…

SrRh2As2 exhibits structural phase transitions reminiscent to those of BaFe2As2, but crystallizes with three polymorphs derived from the tetragonal ThCr2Si2-type structure. The structure of \alpha-SrRh2As2 is monoclinic with a = 421.2(1)…

Superconductivity · Physics 2012-02-02 V. Zinth , V. Petricek , M. Dusek , D. Johrendt

By means of first-principles calculations we study the structural and electronic properties of a superlattice made of Sr2RuO4 and Sr3Ru2O7 ruthenate oxides. Due to the symmetry mismatch of the two systems a significant structural…

Materials Science · Physics 2026-01-13 Carmine Autieri , Mario Cuoco , Canio Noce

Layered materials span a very broad range of solids ranging from van der Waals materials to highly complex crystal structures such as clays. They are commonly believed to have highly anisotropic properties, which is essentially attributed…

Materials Science · Physics 2020-02-17 Jiawei Zhang , Lirong Song , Mattia Sist , Kasper Tolborg , Bo Brummerstedt Iversen

Intrinsic, in-plane anisotropy of electrical resistivity was studied on mechanically detwinned single crystals of SrFe$_2$As$_2$ above and below the temperature of the coupled structural/magnetic transition, $T_{\textrm{TO}}$. Resistivity…

Structural stability and electronic properties of alkaline-earth metals (Ca, Sr, Ba) induced Si(111)-3x2 surfaces have been comprehensively studied by means of ab initio calculations. Adsorption energy and charge density difference…

Materials Science · Physics 2018-11-20 Jun-Shuai Chai , Zhen-Zhen Li , Lifang Xu , Jian-Tao Wang

Recently discovered heavy fermion CeRh$_{2}$As$_{2}$ compound crystallizes in the nonsymmorphic $P4/nmm$ symmetry, which enables the occurrence of topological protection. Experimental results show that this material exhibits unusual…

We report the physical properties and electronic structure calculations of a layered chromium oxypnictide, Sr$_2$Cr$_3$As$_2$O$_2$, which crystallizes in a Sr$_2$Mn$_3$As$_2$O$_2$-type structure containing both CrO$_2$ planes and…

Strongly Correlated Electrons · Physics 2016-01-06 Hao Jiang , Jin-Ke Bao , Hui-Fei Zhai , Zhang-Tu Tang , Yun-Lei Sun , Yi Liu , Zhi-Cheng Wang , Hua Bai , Zhu-An Xu , Guang-Han Cao