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The interrelation of dynamic processes active on separated time-scales in glasses and viscous liquids is investigated using a model displaying two time-scale bifurcations both between fast and secondary relaxation and between secondary and…

Disordered Systems and Neural Networks · Physics 2015-03-19 Andrea Crisanti , Luca Leuzzi , Matteo Paoluzzi

We numerically elucidate the microscopic mechanisms controlling the relaxation dynamics of a three-dimensional lattice glass model that has static properties compatible with the approach to a random first-order transition. At low…

Disordered Systems and Neural Networks · Physics 2024-02-09 Yoshihiko Nishikawa , Ludovic Berthier

We present a mean-field theory of a coarse-grained model of a super-cooled liquid in which relaxation occurs via local plastic rearrangements. Local relaxation can be induced by thermal fluctuations or by the long-range elastic consequences…

Soft Condensed Matter · Physics 2023-12-07 Joseph W. Baron , Giulio Biroli

Glass-forming liquids have only a modest tendency to crystallize and hence their dynamics can be studied even below the melting temperature. The relaxation dynamics of most of these liquids shows at a temperature $T_c$, somewhat above the…

Soft Condensed Matter · Physics 2025-01-17 Francesco Rusciano , Raffaele Pastore , Francesco Greco , Walter Kob

The mode-coupling theory of the glass transition treats the dynamics of supercooled liquids in terms of two-point density correlation functions. Here we consider a generalized, hierarchical formulation of schematic mode-coupling equations…

Statistical Mechanics · Physics 2014-11-27 Liesbeth M. C. Janssen , Peter Mayer , David R. Reichman

A unified treatment of structural relaxation in a deeply supercooled glassy liquid is developed which extends the existing mode coupling theory (MCT) by incorporating the effects of activated events by using the concepts from the random…

Disordered Systems and Neural Networks · Physics 2007-05-23 Sarika Maitra Bhattacharyya , Biman Bagchi , Peter G. Wolynes

Glass-like materials are nonequilibrium systems where the relaxation time may exceed reasonable time scales of observations. In the present paper a dynamic percolation model is introduced in order to explain the principal properties of…

Condensed Matter · Physics 2007-05-23 A. Vazquez , O. Sotolongo-Costa

We propose a dynamic structure of coupled dynamic molecular strings for supercooled small polar molecule liquids and accordingly we obtain the Hamiltonian of the rotational degrees of freedom of the system. From the Hamiltonian, the…

Disordered Systems and Neural Networks · Physics 2009-11-10 Y. N. Huang , C. J. Wang , E. Riande

Supercooled liquid and glassy acetyl salicylic acid was studied using dielectric spectroscopy and deuteron relaxometry in a wide temperature range. The supercooled liquid is characterized by major deviations from thermally activated…

Soft Condensed Matter · Physics 2009-11-11 R. Nath , T. El Goresy , H. Zimmermann , R. Bohmer

The primary relaxation in glass forming supercooled liquids (SCLs) above the glass transformation temperature T_g is discussed in terms of the first-order (steepness) and the second-order (curvature) temperature derivatives of the observed…

Chemical Physics · Physics 2007-05-23 Valery B. Kokshenev , Pablo D. Borges , Neil S. Sullivan

The interplay between the structural relaxation and the rheological response of a binary LJ glass former is studied via MD simulations. In the quiescent state, the model is well known for its sluggish dynamics and a two step relaxation of…

Soft Condensed Matter · Physics 2015-05-14 Fathollah Varnik

According to the Random First Order Transition (RFOT) theory of glasses, the barriers for activated dynamics in supercooled liquids vanish as the temperature of a viscous liquid approaches the dynamical transition temperature from below.…

Disordered Systems and Neural Networks · Physics 2009-11-10 Vassiliy Lubchenko , Peter G. Wolynes

For several atomistic models of glass formers, at conditions below their glassy dynamics onset temperatures, ${T_\mathrm{o}}$, we use importance sampling of trajectory space to study the structure, statistics and dynamics of excitations…

Statistical Mechanics · Physics 2014-05-08 Aaron S. Keys , Lester O. Hedges , Juan P. Garrahan , Sharon C. Glotzer , David Chandler

We review the recently proposed elastic approach to glass transition. This approach is based on a simple and a physically transparent idea of elastic interactions between local relaxation events in a liquid. Central to this picture is the…

Soft Condensed Matter · Physics 2008-07-25 Kostya Trachenko

We observe a surprisingly general power law decay at short to intermediate times in orientational relaxation in a variety of model systems (both calamitic and discotic, and also discrete) for thermotropic liquid crystals. As all these…

Soft Condensed Matter · Physics 2009-11-11 Dwaipayan Chakrabarti , Prasanth P. Jose , Suman Chakrabarty , Biman Bagchi

The glass transition is described in terms of thermally activated local structural rearrangements, the secondary relaxations of the glass phase. The interaction between these secondary relaxations leads to a much faster and much more…

Disordered Systems and Neural Networks · Physics 2007-05-23 U. Buchenau

Supercooled liquids display dynamics that are inherently heterogeneous in space. This essentially means that at temperatures below the melting point, particle dynamics in certain regions of the liquid can be orders of magnitude faster than…

Soft Condensed Matter · Physics 2021-01-04 Dipanwita Ghoshal , Ashwin Joy

Extensive computer simulations are performed for a few model glass-forming liquids in both two and three dimensions to study their dynamics when a randomly chosen fraction of particles are frozen in their equilibrium positions. For all the…

Statistical Mechanics · Physics 2016-08-03 Saurish Chakrabarty , Rajsekhar Das , Smarajit Karmakar , Chandan Dasgupta

Upon cooling, glass-forming liquids experience a two-step relaxation associated to the cage rattling and the escape from the cage, and the following decoupling between the \b{eta}- and the {\alpha}-relaxations. The found decoupling…

Disordered Systems and Neural Networks · Physics 2017-06-07 P. Luo , P. Wen , H. Y. Bai , B. Ruta , W. H. Wang

A recent hypothesis claims that the glass transition itself, though it is a very pronounced relaxation peak, is no separate relaxation process at all, but is just the breakdown of the shear modulus due to the weak elastic dipole interaction…

Disordered Systems and Neural Networks · Physics 2007-05-23 U. Buchenau
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