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Explicit molecular dynamics simulations were applied to a pair of amorphous silica nanoparticles of diameter 3.2 nm immersed in a background electrolyte. Mean forces acting between the pair of silica nanoparticles were extracted at four…

Chemical Physics · Physics 2007-09-11 S. Jenkins , S. R. Kirk , M. Persson , J. Carlen , Z. Abbas

The effects of particle roughness and short-ranged non-central forces on colloidal gels are studied using computer simulations in which particles experience a sinusoidal variation in energy as they rotate. The number of minima $n$ and…

Soft Condensed Matter · Physics 2019-09-05 Hong T. Nguyen , Alan L. Graham , Peter H. Koenig , Lev D. Gelb

We simulate structural phase behavior of polymer-grafted colloidal particles by molecular Monte Carlo technique. Interparticle potential, which has a finite repulsive square-step outside a rigid core of the colloid, was previously confirmed…

Soft Condensed Matter · Physics 2015-03-19 Yuki Norizoe , Toshihiro Kawakatsu

We study the fluctuation-induced Casimir interactions in colloidal suspensions, especially between colloids immersed in a binary liquid close to its critical demixing point. To simulate these systems, we present a highly efficient cluster…

Soft Condensed Matter · Physics 2017-06-09 Hendrik Hobrecht , Alfred Hucht

Two-dimensional ionic liquids with single site anion and cation-neutral dimer are studied by computer simulations and integral equation techniques, with the aim of characterizing differences with single site anion-cation mixtures, and also…

Chemical Physics · Physics 2018-10-17 Perera Aurélien , Urbic Tomaz

Colloidal particles suspended in liquid crystals can exhibit various effective anisotropic interactions that can be tuned and utilized in self-assembly processes. We simulate a two-dimensional system of hard disks suspended in a solution of…

Soft Condensed Matter · Physics 2020-07-30 David Müller , Tobias A. Kampmann , Jan Kierfeld

The phase behavior of colloidal particles embedded in a binary fluid is influenced by wetting layers surrounding each particle. The free energy of the fluid film depends on its morphology, i.e., on size, shape and connectivity. Under rather…

Soft Condensed Matter · Physics 2007-05-23 Uwe Brodatzki , Klaus Mecke

Point polarizable molecules at fixed spatial positions have solvable electrostatic properties in classical approximation, the most familiar being the Clausius-Mossotti (CM) formula. This paper generalizes the model and imagines various…

Materials Science · Physics 2009-11-10 Philip B. Allen

Confining a colloidal crystal within a long narrow channel produced by two parallel walls can be used to impose a meso-scale superstructure of a predominantly mechanical elastic character [Chui et al., EPL 2008, 83, 58004]. When the crystal…

Soft Condensed Matter · Physics 2009-12-04 Yu-Hang Chui , Surajit Sengupta , Ian K. Snook , Kurt Binder

A binary mixture of super-paramagnetic colloidal particles is confined between glass plates such that the large particles become fixed and provide a two-dimensional disordered matrix for the still mobile small particles, which form a fluid.…

We study the strong-coupling (SC) interaction between two like-charged membranes of finite thickness embedded in a medium of higher dielectric constant. A generalized SC theory is applied along with extensive Monte-Carlo simulations to…

Soft Condensed Matter · Physics 2009-05-26 Y. S. Jho , M. Kanduc , A. Naji , R. Podgornik , M. W. Kim , P. A. Pincus

We study the temperature dependence of static and dynamic responses of Coulomb interacting particles in two-dimensional traps across the thermal crossover from an amorphous solid- to liquid-like behaviors. While static correlations, that…

Disordered Systems and Neural Networks · Physics 2017-10-11 Biswarup Ash , J. Chakrabarti , Amit Ghosal

We perform computational investigations of electrolyte-mediated interactions of charged colloidal particles confined within nanochannels. We investigate the role of discrete ion effects, valence, and electrolyte strength on colloid-wall…

Soft Condensed Matter · Physics 2023-02-28 Inderbir S. Sidhu , Amalie L. Frischknecht , Paul J. Atzberger

Colloidal particles that are confined to an interface effectively form a two-dimensional fluid. We examine the dynamics of such colloids when they are subject to a constant external force, which drives them in a particular direction over…

Soft Condensed Matter · Physics 2011-06-24 Andrew J. Archer , Alexandr Malijevsky

We determine the structure and melting behavior of supported metallic clusters using an ab initio density-functional-based treatment of intracluster interactions and an approximate treatment of the surface as an idealized smooth plane…

Mesoscale and Nanoscale Physics · Physics 2012-10-02 S. A. Blundell , Soumyajyoti Haldar , D. G. Kanhere

In this review, we address the issue of the electrostatic complexation between charged-neutral diblock copolymers and oppositely charged nanocolloids. We show that nanocolloids such as surfactant micelles and iron oxide magnetic…

Soft Condensed Matter · Physics 2011-02-01 J. -F. Berret

In this article, we demonstrate a method for inducing reversible crystal-to-crystal transitions in binary mixtures of soft colloidal particles. Through a controlled decrease of salinity and increasingly dominating electrostatic…

Soft Condensed Matter · Physics 2021-08-30 Jasper N. Immink , Maxime J. Bergman , J. J. Erik Maris , Joakim Stenhammar , Peter Schurtenberger

A density functional theory of two-dimensional freezing is presented for a soft interaction potential that scales as inverse cube of particle distance. This repulsive potential between parallel, induced dipoles is realized for paramagnetic…

Soft Condensed Matter · Physics 2009-05-28 Sven van Teeffelen , Christos N. Likos , Norman Hoffmann , Hartmut Löwen

Here, we investigate the nature of the moment coupling between 10-nm DMSA-coated magnetic nanoparticles, in both colloidal dispersion and in powder form. The individual iron oxide cores were composed of > 95% maghemite and agglomerated to…

Molecular dynamics simulations have been performed on pure liquid water, aqueous solutions of sodium chloride, and polymer solutions exposed to a strong external electric field with the goal to gain molecular insight into the structural…

Soft Condensed Matter · Physics 2016-08-08 I. Nezbeda , J. Jirsák , F. Moučka , W. R. Smith