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We present a detailed comparison of the electronic structure of BaFe2As2 in its paramagnetic and antiferromagnetic (AFM) phases, through angle-resolved photoemission studies. Using different experimental geometries, we resolve the full…

Electronic correlations in the Fe-pnictide BaFe2As2 are explored within LDA+DMFT, the combination of density functional theory with dynamical mean-field theory. While the correlated band structure is substantially renormalized there is only…

Despite the wealth of experimental data on the Fe-pnictide compounds of the KFe2As2-type, K = Ba, Ca, or Sr, the main theoretical work based on multiorbital tight-binding models has been restricted so far to the study of the related 1111…

Superconductivity · Physics 2010-06-16 S. Graser , A. F. Kemper , T. A. Maier , H. -P. Cheng , P. J. Hirschfeld , D. J. Scalapino

The interplay between structural phase and electronic correlations has been an intriguing topic of research. An prominent example is the pressure-induced uncollapsed to collapsed tetragonal phase transition observed in CaFe$_2$As$_2$, which…

Strongly Correlated Electrons · Physics 2021-03-17 Jianzhou Zhao , Yilin Wang , Xiaolong Feng , Shengyuan A. Yang

Electronic structure of single crystalline Ba(Zn$_{0.875}$Mn$_{0.125}$)$_{2}$As$_{2}$, parent compound of the recently founded high-temperature ferromagnetic semiconductor, was studied by high-resolution photoemission spectroscopy (ARPES).…

Materials Science · Physics 2016-11-14 Fengfeng Zhu , W. X. Jiang , P. Li , Z. Q. Wang , H. Y. Man , Y. Y. Li , Canhua Liu , D. D. Guan , J. F. Jia , F. L. Ning , Weidong Luo , D. Qian

A Projector Augmented Wave (PAW) atomic data file is needed to be generated for each element, and plays in the PAW method the role of the pseudopotential file for norm-conserving (NC) or ultra-soft (US) plane wave calculations. In this…

Materials Science · Physics 2014-03-05 François Jollet , Marc Torrent , Natalie Holzwarth

We report high resolution angle-resolved photoemission spectroscopy (ARPES) studies of the electronic structure of BaFe$_2$As$_2$, which is one of the parent compounds of the Fe-pnictide superconductors. ARPES measurements have been…

By the first-principles electronic structure calculations, we find that energetically the most favorable cleaved $A$Fe$_2$As$_2$(001) surface ($A$=Ba, Sr, or Ca) is $A$-terminated with a $(\sqrt{2}\times \sqrt{2})R45^{\circ}$ or $(1\times…

Materials Science · Physics 2010-05-21 Miao Gao , Fengjie Ma , Zhong-Yi Lu , Tao Xiang

We present an approach that combines the local density approximation (LDA) and the dynamical mean-field theory (DMFT) in the framework of the full-potential linear augmented plane waves (FLAPW) method. Wannier-like functions for the…

We have performed the first-principles electronic structure calculation for the novel superconductor Ca4Al2O6Fe2As2 which has the smallest a lattice parameter and the largest As height from the Fe plane among the Fe-As superconductors. We…

Superconductivity · Physics 2010-12-13 Takashi Miyake , Taichi Kosugi , Shoji Ishibashi , Kiyoyuki Terakura

We construct a reference database of materials properties calculated using density-functional theory in the local or generalized-gradient approximation, and an all-electron or a projector augmented-wave (PAW) formulation, for verification…

Materials Science · Physics 2014-04-14 E. Kucukbenli , M. Monni , B. I. Adetunji , X. Ge , G. A. Adebayo , N. Marzari , S. de Gironcoli , A. Dal Corso

We implement a Becke fuzzy cells type space partitioning scheme for the purposes of exchange-correlation within the GPAW projector augmented-wave method based density functional theory code. Space partitioning is needed in the situation…

Materials Science · Physics 2019-02-20 H. Levämäki , M. Kuisma , K. Kokko

The projector-augmented wave (PAW) method is one of the approaches that are widely used to approximately treat core electrons and thus to speed-up plane-wave basis set electronic structure calculations. However, PAW involves approximations…

Chemical Physics · Physics 2023-08-24 Sirous Yourdkhani , Jiri Klimes

Unlike covalent two-dimensional (2D) materials like graphene, 2D metals have non-layered structures due to their non-directional, metallic bonding. While experiments on 2D metals are still scarce and challenging, density-functional theory…

Materials Science · Physics 2023-01-06 Kameyab Raza Abidi , Pekka Koskinen

BaNi$_2$As$_2$ is a structural analog of the pnictide superconductor BaFe$_2$As$_2$, which, like the iron-based superconductors, hosts a variety of ordered phases including charge density waves (CDWs), electronic nematicity, and…

First principles calculations were performed to study the ground state electronic properties of BaFeO3 (BFO) within the density functional theory (DFT). Adopting generalized gradient approximation (GGA) exchange and correlation functional…

Materials Science · Physics 2007-05-23 Hong-Jian Feng , Fa-Min Liu

In this work, we present a computationally efficient methodology that utilizes a local real-space formulation of the projector augmented wave (PAW) method discretized with a finite-element (FE) basis to enable accurate and large-scale…

Computational Physics · Physics 2025-01-03 Kartick Ramakrishnan , Sambit Das , Phani Motamarri

Superconductivity up to 30 K in charge neutrally doped BaFe2[As(1-x)P(x)]2 has been ascribed to chemical pressure, caused by the shrinking unit cell. But the latter induces no superconductivity in [Ba(1-x)Sr(x)]Fe2As2 in spite of the same…

Superconductivity · Physics 2010-07-14 Marianne Rotter , Christine Hieke , Dirk Johrendt

The role of orbital differentiation on the emergence of superconductivity in the Fe-based superconductors remains an open question to the scientific community. In this investigation, we employ a suitable microscopic spin probe technique,…

Superconductivity · Physics 2014-02-11 P. F. S. Rosa , C. Adriano , T. M. Garitezi , T. Grant , Z. Fisk , R. R. Urbano , P. G. Pagliuso

In Kohn-Sham electronic structure computations, wave functions have singularities at nuclear positions. Because of these singularities, plane-wave expansions give a poor approximation of the eigenfunctions. In conjunction with the use of…

Numerical Analysis · Mathematics 2023-01-02 Xavier Blanc , Eric Cancès , Mi-Song Dupuy