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A path integral formalism for non-equilibrium systems is proposed based on a manifold of quasi-equilibrium densities. A generalized Boltzmann principle is used to weight manifold paths with the exponential of minus the information…

Mathematical Physics · Physics 2015-03-17 Richard Kleeman

We construct the path integral formulation of the partition function for a free scalar thermal field theory using coherent states, first in the ladder operator basis and then in the field operator basis. In so doing, we provide for the…

High Energy Physics - Theory · Physics 2025-07-17 Rens Roosenstein , Maximilian Attems , W. A. Horowitz

Quantum chemistry calculations on a quantum computer frequently suffer from symmetry breaking: the situation when a state of assumed spin and number of electrons is contaminated with contributions of undesired symmetry. The situation may…

Quantum Physics · Physics 2018-12-27 Ilya G. Ryabinkin , Scott N. Genin

We present measurement schemes that do not rely on photon-number resolving detectors, but that are nevertheless optimal for estimating a differential phase shift in interferometry with either an entangled coherent state or a…

Quantum Physics · Physics 2024-09-12 Z. M. McIntyre , W. A. Coish

Statistics of classical Hamiltonian random walk of particle colliding with atoms of ideal gas is considered from viewpoint of earlier suggested exact pseudo-quantum path integral representation of the problem, and qualitative agreement is…

Statistical Mechanics · Physics 2013-11-14 Yu. E. Kuzovlev

Using the path integral measure factorization method based on the nonlinear filtering equation from the stochastic process theory, we consider the reduction procedure in Wiener path integrals for a mechanical system with symmetry that…

Mathematical Physics · Physics 2020-01-01 S. N. Storchak

We solve numerically exactly a simple toy model to quantum general relativity or more properly to path integral on a curved space. We consider the thermal equilibrium of a quantum many body problem on the sphere, the surface of constant…

Quantum Gases · Physics 2026-03-25 Riccardo Fantoni

We propose a quantum algorithm to simulate the dynamics in quantum chemistry problems. It is based on adding fresh qubits at each Trotter step, which enables a simpler implementation of the dynamics in the extended system. After each step,…

Quantum Physics · Physics 2025-02-07 Maxine Luo , J. Ignacio Cirac

Including quantum mechanical effects on the dynamics of nuclei in the condensed phase is challenging, because the complexity of exact methods grows exponentially with the number of quantum degrees of freedom. Efforts to circumvent these…

Chemical Physics · Physics 2015-06-23 Mariana Rossi , Hanchao Liu , Francesco Paesani , Joel Bowman , Michele Ceriotti

Ensuring a satisfactory statistical convergence of anharmonic thermodynamic properties requires sampling of many atomic configurations, however the methods to obtain those necessarily produce correlated samples, thereby reducing the…

Statistical Mechanics · Physics 2022-06-07 Erki Metsanurk

The problem of existence and constructing of integrals of motion in stationary quantum mechanics and its connection with quantum chaoticity is discussed. It is shown that the earlier suggested quantum chaoticity criterion characterizes…

Quantum Physics · Physics 2007-05-23 V. E. Bunakov , I. B. Ivanov

We formulate and apply a nonperturbative numerical approach to the nonequilibrium current, $I(V)$, through a voltage-biased molecular conductor. We focus on a single electronic level coupled to an unequilibrated vibration mode…

Mesoscale and Nanoscale Physics · Physics 2012-03-20 R. Hützen , S. Weiss , M. Thorwart , R. Egger

In computing electric conductivity based on the Kubo formula, the vertex corrections describe such effects as anisotropic scattering and quantum interference and are important to quantum transport properties. These vertex corrections are…

Materials Science · Physics 2020-09-10 Yi-Wen Wei , Chao-Kai Li , Yuchuang Cao , Ji Feng

In a recent work we have proposed an original analytic expression for the partition function of the quartic oscillator. This partition function, which has a simple and compact form with {\it no adjustable parameters}, reproduces some key…

Quantum Physics · Physics 2024-09-23 Michel Caffarel

Path integral Monte Carlo with Green's function analysis allows the sampling of quantum mechanical properties of molecules at finite temperature. While a high-precision computation of the energy of the Born-Oppenheimer surface from path…

Quantum Physics · Physics 2007-05-23 Daejin Shin , Ming-Chak Ho , J. Shumway

The path integral is not typically utilized for analyzing entanglement experiments, in part because there is no standard toolbox for converting an arbitrary experiment into a form allowing a simple sum-over-history calculation. After…

Quantum Physics · Physics 2023-01-03 Ken Wharton , Raylor Liu

We present a multiple time step algorithm for hybrid path integral Monte Carlo simulations involving rigid linear rotors. We show how to calculate the quantum torques needed in the simulation from the rotational density matrix, for which we…

Statistical Mechanics · Physics 2007-05-23 G. Garberoglio , J. K. Johnson

we will provide a rigorous computation for the harmonic oscillator Feynman path integral. The computation will be done without having prior knowledge of the classical path. We will see that properties of classical physics falls out…

Mathematical Physics · Physics 2007-05-23 Ken Loo

The concepts of phase space Feynman integrals in White Noise Analysis are established. As an example the harmonic oscillator is treated. The approach perfectly reproduces the right physics. I.e., solutions to the Schr\"odinger equation are…

Mathematical Physics · Physics 2013-11-19 Wolfgang Bock , Martin Grothaus

The recursion and path-integral methods are applied to analytically study the electronic structure of a neutral $C_{60}$ molecule. We employ a tight-binding Hamiltonian which considers both the $s$ and $p$ valence electrons of carbon. From…

Materials Science · Physics 2009-10-22 Yeong-Lieh Lin , Franco Nori