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Related papers: The Structural Phase Transition in FeSe (Fe1+dSe)

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Tetragonal beta-FeSe obtained by hydrothermal reaction is not superconducting and transforms to a triclinic structure at 60 K unlike superconducting FeSe from solid state synthesis, which becomes orthorhombic at 90 K. In contrast,…

Superconductivity · Physics 2015-10-28 Ursula Pachmayr , Natalie Fehn , Dirk Johrendt

The newly discovered superconductor FeSe1-x (x=0.08, Tconset=13.5 K at ambient pressure rising to 27 K at 1.48 GPa) exhibits a structural phase transition from tetragonal to orthorhombic below 70 K at ambient pressure - the crystal…

The nature of the tetragonal-to-orthorhombic structural transition at $T_s\approx90$ K in single crystalline FeSe is studied using shear-modulus, heat-capacity, magnetization and NMR measurements. The transition is shown to be accompanied…

Superconductivity · Physics 2015-06-22 A. E. Böhmer , T. Arai , F. Hardy , T. Hattori , T. Iye , T. Wolf , H. v. Löhneysen , K. Ishida , C. Meingast

The low-temperature crystal structure of Fe1.13Te, which exhibits an anomalous two-step magnetic transition, was clarified by the systematic x-ray diffraction measurements. It was found that two-step structural phase transition,…

Superconductivity under pressure in FeSe ($T_{\rm c}$$\sim$7.5 K) has been investigated using single-crystal specimens through the measurements of DC magnetization and electrical resistivity. A characteristic three-step increase in $T_{\rm…

We report on the structural phase transitions in the S doped FeSe superconductor by powder synchrotron X ray diffraction at high pressures up to 18.5 GPa under compression and decompression modes. In order to create high quasi hydrostatic…

Here we establish a more complete phase diagram for FeSe system, based on experimental results of nonstoichiometric Fe1-xSe single crystals that we have developed recently, as well as nearly stoichiometric FeSe single crystals. The…

This article reviews recent experimental investigations on two binary Fe-chalcogenides: FeSe and Fe$_{1+y}$Te. The main focus is on synthesis, single crystal growth, chemical composition, as well as on the effect of excess iron on…

Superconductivity · Physics 2016-06-06 Sahana Rößler , Cevriye Koz , Steffen Wirth , Ulrich Schwarz

Superconducting iron chalcogenide FeSe has the simplest crystal structure among all the Fe-based superconductors. Unlike other iron pnictides, FeSe exhibits no long range magnetic order accompanying the tetragonal-to-orthorhombic structural…

We report the temperature dependent x-ray powder diffraction of the FeAs-based superconductors in the range between 300 K and 95 K. In the case of NdOFeAs we have detected the structural phase transition from the tetragonal phase, with…

Superconductivity · Physics 2009-01-12 Alessandro Ricci , Michela Fratini , Antonio Bianconi

Crystal structures and microstructural features, such as structural phase transitions, defect structures, chemical and structural inhomogeneities, are known to have profound effects on the physical properties of superconducting materials.…

Superconductivity · Physics 2013-07-22 Wang Zhen , Cai Yao , Yang Huai-Xin , Tian Huan-Fang , Wang Zhi-Wei , Ma Chao , Chen Zhen , Li Jian-Qi

The study of the iron-based superconductor FeSe has blossomed with the availability of high quality single crystals, obtained through flux/vapor-transport growth techniques below the structural transformation temperature of its tetragonal…

Superconductivity · Physics 2016-08-02 A. E. Böhmer , V. Taufour , W. E. Straszheim , T. Wolf , P. C. Canfield

We study the crystal structure of the tetragonal iron selenide FeSe and its nematic phase transition to the low-temperature orthorhombic structure using synchrotron x-ray and neutron scattering analyzed in both real and reciprocal space. We…

Single crystal synchrotron X-ray diffraction as a function of temperature and pressure has revealed a complex biphase mixture in superconducting FeSe. Based on our experimental results we construct a phase diagram where structural behavior…

Superconductivity · Physics 2017-08-02 V. Svitlyk , M. Raba , V. Dmitriev , P. Rodiere , P. Toulemonde , D. Chernyshov , M. Mezouar

In contrast to the simultaneous structural and magnetic first order phase transition $T_{0}$ previously reported, our detailed investigation on an underdoped Ba$_{0.84}$K$_{0.16}$Fe$_{2}$As$_{2}$ single crystal unambiguously revealed that…

The nuclear and magnetic structure of Fe1+y(Te1-x,Sex) (0 < x < 0.20) compounds was analyzed between 2 K and 300 K by means of Rietveld refinement of neutron powder diffraction data. Samples with x < 0.075 undergo a tetragonal to monoclinic…

As the simplest iron-based superconductor, FeSe forms a tetragonal structure with transition temperature Tc ~ 8 K. With assistance of pressure, or other techniques, Tc can be greatly enhanced, even to above liquid nitrogen temperature. The…

Superconductivity · Physics 2017-10-16 J. Zhang , F. L. Liu , T. P. Ying , N. N. Li , Y. Xu , L. P. He , X. C. Hong , Y. J. Yu , M. X. Wang , J. Shen , W. G. Yang , S. Y. Li

We report measurements of resistance and ac magnetic susceptibility on FeSe single crystals under high pressure up to 27.2 kbar. The structural phase transition is quickly suppressed with pressure, and the associated anomaly is not seen…

We use bulk magnetic susceptibility, electronic specific heat, and neutron scattering to study structural and magnetic phase transitions in Fe$_{1+y}$Se% $_x$Te$_{1-x}$. Fe$_{1.068}$Te exhibits a first order phase transition near 67 K with…

We present results from a detailed experimental investigation of LaFeAsO, the parent material in the series of "FeAs" based oxypnictide superconductors. Upon cooling this material undergoes a tetragonal-orthorhombic crystallographic phase…

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