Related papers: Slow Molecules Produced by Photodissociation
Molecular cooling is essential for studying the formation of sub-structure of dissipative dark-matter halos that may host compact objects such as black holes. Here, we analyze the reaction rates relevant for the formation, dissociation, and…
Supersonic beams are a prevalent source of cold molecules utilized in the study of chemical reactions, atom interferometry, gas-surface interactions, precision spectroscopy, molecular cooling and more. The triumph of this method emanates…
Biomolecular condensates are small droplets forming spontaneously in biological cells via phase separation. They play a role in many cellular processes, but it is unclear how cells control them. Cellular regulation often relies on…
We propose a method of stimulated laser cooling of diatomic molecules by counter-propagating $\pi$-trains of ultrashort laser pulses. The cooling cycles occur on the rovibrational transitions inside the same ground electronic manifold, thus…
UV ice photodesorption is an important non-thermal desorption pathway in many interstellar environments that has been invoked to explain observations of cold molecules in disks, clouds and cloud cores. Systematic laboratory studies of the…
A chopper wheel construct is used to shorten the duration of a molecular beam to 13 microseconds. Molecular beams seeded with NO or with Br2 and an initial pulse width of greater or equal to 200 microseconds were passed through a spinning…
Metastable helium molecules (He$_2^*$) have been generated by striking a discharge in a supersonic expansion of helium gas from a pulsed valve. When operating the pulsed valve at room temperature, 77K, and 10K, the mean velocity of the…
The dissociation dynamics of diatomic molecules interacting with (near) optical laser pulses of different duration is investigated by an elaborate discussion of the electric field of the laser and by a direct solution of the time-dependent…
The photon emission from a single molecule driven simultaneously by a laser and a slow electric radio frequency (rf) field is studied. We use a non-Hermitian Hamiltonian approach which accounts for the radiative decay of a two level system…
Young massive stars produce Far-UV photons which dissociate the molecular gas on the surfaces of their parent molecular clouds. Of the many dissociation products which result from this ``back-reaction'', atomic hydrogen \HI is one of the…
We consider deflection of polarizable molecules by inhomogeneous optical fields, and analyze the role of molecular orientation and rotation in the scattering process. It is shown that molecular rotation induces spectacular rainbow-like…
We present the first crossed beam scattering experiment using a Zeeman decelerated molecular beam. The narrow velocity spreads of Zeeman decelerated NO ($X ^2\Pi_{3/2}, j=3/2$) radicals result in high-resolution scattering images, thereby…
We discuss the production of ultracold molecules in their electronic ground state by photoassociation employing electronically excited states with ion-pair character and strong spin-orbit interaction. A short photoassociation laser pulse…
At the high densities and low temperatures found in star forming regions, all molecules other than H2 should stick on dust grains on timescales shorter than the cloud lifetimes. Yet these clouds are detected in the millimeter lines of…
We present a method to control photodissociation by manipulating the bond softening mechanism occurring in strong shaped laser fields, by varying the chirp sign and magnitude of an ultra-short laser pulse. Manipulation of bond-softening is…
Molecular nitrogen is one of the key species in the chemistry of interstellar clouds and protoplanetary disks and the partitioning of nitrogen between N and N2 controls the formation of more complex prebiotic nitrogen-containing species.…
We investigate the process of self-regulated star formation via photodissociation of hydrogen molecules in low metallicity clouds. We evaluate the influence region's scale of a massive star in low metallicity gas clouds whose temperatures…
The laser control of photodissociation branching in a diatomic molecule is demonstrated to be effectively achieved with use of the complete reflection phenomenon. The phenomenon and the control condition can be nicely formulated by the…
A longstanding problem in astrochemistry is how molecules can be maintained in the gas phase in dense inter- and circumstellar regions. Photodesorption is a non-thermal desorption mechanism, which may explain the small amounts of observed…
We present a technique to treat systems with very many levels, like molecules, in non-LTE. This method is based on a superlevel formalism coupled with rate operator splitting. Superlevels consist of many individual levels that are assumed…