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This article reviews recent experimental investigations on two binary Fe-chalcogenides: FeSe and Fe$_{1+y}$Te. The main focus is on synthesis, single crystal growth, chemical composition, as well as on the effect of excess iron on…

Superconductivity · Physics 2016-06-06 Sahana Rößler , Cevriye Koz , Steffen Wirth , Ulrich Schwarz

By realizing in thin films a tensile stress state, superconductivity of 13 K was introduced into FeTe, an non-superconducting parent compound of the iron pnictides and chalcogenides, with transition temperature higher than that of its…

Superconductivity · Physics 2010-01-11 Y. Han , W. Y. Li , L. X. Cao , X. Y. Wang , B. Xu , B. R. Zhao , Y. Q. Guo , J. L. Yang

Tetragonal iron selenide, FeSe, the layered parent compound of the recently discovered superconducting arsenide family, has previously been shown to be non magnetic and superconducting with a critical temperature near 8 K. There has,…

Superconductivity · Physics 2009-08-12 A. J. Williams , T. M. McQueen , R. J. Cava

We have carried out a systematic study of the PbO-type compound FeSe_{1-x}Te_x (x = 0~1), where Te substitution effect on superconductivity is investigated. It is found that superconducting transition temperature reaches a maximum of…

We report on a new iron selenide superconductor with a TC onset of 45K and the nominal composition Lix(C5H5N)yFe2-zSe2, synthesized via intercalation of dissolved alkaline metal in anhydrous pyridine at room temperature. This superconductor…

Superconductivity · Physics 2012-09-13 A. Krzton-Maziopa , E. V. Pomjakushina , V. Yu. Pomjakushin , F. von Rohr , A. Schilling , K. Conder

Superconductivity in the iron-chalcogenide series FeSe-Fe(Te, Se)-FeTe has been restricted to the near neighbor of iron selenide (FeSe), with a general consensus that iron telluride (FeTe) is not superconducting. In this study, we report…

Superconductivity · Physics 2026-03-24 Guanyang He , Yuxuan Lei , Tianheng Wei , Yanzhao Liu , Jian Wang

Tetragonal FeSe is a superconductor with a transition temperature Tc of 8 K and shows a huge enhancement of Tc with applying pressure. Tetragonal FeTe has a structure very analogous to superconducting FeSe, but does not show superconducting…

Superconductivity · Physics 2009-08-09 Y. Mizuguchi , F. Tomioka , S. Tsuda , T. Yamaguchi , Y. Takano

It is well established that the occurrence of superconductivity in iron pnictides is closely related to the tetragonal to orthorhombic structural and antiferromagnetic (AFM) phase transitions. It, however, has not been clear whether the…

Superconductivity · Physics 2016-07-06 Shifeng Jin , Xiaozhi Wu , Qingzhen Huang , Hui Wu , Tianping Ying , Xiao Fan , Ruijin Sun , Linlin Zhao , Xiaolong Chen

We investigated the evolution of the temperature-composition phase diagram of Fe$_{1+y}$Te upon Se substitution. In particular, the effect of Se substitution on the two-step, coupled magneto-structural transition in Fe$_{1+y}$Te single…

Superconductivity · Physics 2015-05-12 Dona Cherian , S. Rößler , S. Wirth , Suja Elizabeth

As the simplest iron-based superconductor, FeSe forms a tetragonal structure with transition temperature Tc ~ 8 K. With assistance of pressure, or other techniques, Tc can be greatly enhanced, even to above liquid nitrogen temperature. The…

Superconductivity · Physics 2017-10-16 J. Zhang , F. L. Liu , T. P. Ying , N. N. Li , Y. Xu , L. P. He , X. C. Hong , Y. J. Yu , M. X. Wang , J. Shen , W. G. Yang , S. Y. Li

The study of the iron-based superconductor FeSe has blossomed with the availability of high quality single crystals, obtained through flux/vapor-transport growth techniques below the structural transformation temperature of its tetragonal…

Superconductivity · Physics 2016-08-02 A. E. Böhmer , V. Taufour , W. E. Straszheim , T. Wolf , P. C. Canfield

Here, we report the synthesis and characterization of sulphur-substituted iron telluride i.e. FeTe1-xSx; (x = 0-30 %) system and study the impact of low temperature oxygen (O2) annealing as well. Rietveld analysis of room temperature x-ray…

Superconductivity · Physics 2015-05-19 V. P. S. Awana , Anand Pal , Arpita Vajpayee , Bhasker Gahtori , H. Kishan

Iron-chalcogenide superconductor Fe$_{1.03}$Se$_{0.5}$Te$_{0.5}$ has been investigated under high pressure using synchrotron based x-ray diffraction and mid-infrared reflectance measurements at room temperature. Pressure dependence of the…

Materials Science · Physics 2013-08-16 Pallavi S. Malavi , S. Karmakar , N. N. Patel , Surinder M. Sharma

New iron selenide superconductors by intercalating smaller-sized alkali metals (Li, Na) and alkaline earths using high-temperature routes have been pursued ever since the discovery of superconductivity at about 30 K in KFe2Se2, but all have…

Superconductivity · Physics 2012-05-30 T. P. Ying , X. L. Chen , G. Wang , S. F. Jin , T. T. Zhou , X. F. Lai , H. Zhang , W. Y. Wang

Tetragonal beta-FeSe obtained by hydrothermal reaction is not superconducting and transforms to a triclinic structure at 60 K unlike superconducting FeSe from solid state synthesis, which becomes orthorhombic at 90 K. In contrast,…

Superconductivity · Physics 2015-10-28 Ursula Pachmayr , Natalie Fehn , Dirk Johrendt

Iron selenide (FeSe) - the structurally simplest iron-based superconductor, has attracted tremendous interest in the past years. While the transition temperature (Tc) of bulk FeSe is $\sim$ 8 K, it can be significantly enhanced to 40 - 50 K…

We investigate the high-pressure phase of the iron-based superconductor FeSe$_{0.89}$S$_{0.11}$ using transport and tunnel diode oscillator studies. We construct detailed pressure-temperature phase diagrams that indicate that outside of the…

Superconductivity · Physics 2022-12-14 Pascal Reiss , Alix McCollam , Zachary Zajicek , Amir A. Haghighirad , Amalia I. Coldea

Pressure plays an essential role in the induction1 and control2,3 of superconductivity in iron-based superconductors. Substitution of a smaller rare-earth ion for the bigger one to simulate the pressure effects has surprisingly raised the…

The discovery of superconductivity of about 30 K in iron selenides with very large magnetic moments simulates the examination of completing orders. Here we report a finding of pressure- induced suppression of the superconducting transition…

In this article we review our studies of the K0.80Fe1.76Se2 superconductor, with an attempt to elucidate the crystal growth details and basic physical properties over a wide range of temperatures and applied magnetic field, including…

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