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Currently, identification of crystallization pathways in polymers is being carried out using molecular simulation-based data on a preset cut-off point on a single order parameter (OP) to define nucleated or crystallized regions. Aside from…

Computational Physics · Physics 2025-07-25 Elyar Tourani , Brian J. Edwards , Bamin Khomami

A goal in the kinetic characterization of a macromolecular system is the description of its slow relaxation processes, involving (i) identification of the structural changes involved in these processes, and (ii) estimation of the rates or…

Chemical Physics · Physics 2015-06-15 Guillermo Perez-Hernandez , Fabian Paul , Toni Giorgino , Gianni de Fabritiis , Frank Noé

High-dimensional chaotic dynamical systems can exhibit strongly transient features. These are often associated with instabilities that have finite-time duration. Because of the finite-time character of these transient events, their…

Dynamical Systems · Mathematics 2017-06-28 Hessam Babaee , Mohamad Farazmand , George Haller , Themistoklis P. Sapsis

We obtain and investigate theoretically a broad family of stable and unstable time-periodic orbits-oscillating Turing rolls (OTR)-in the Lugiato-Lefever model of optical cavities. Using the dynamical systems tools developed in fluid…

Pattern Formation and Solitons · Physics 2025-09-15 Andrey Gelash , Savyaraj Deshmukh , Andrey Shusharin , Tobias M. Schneider , Tobias J. Kippenberg

We report a fully quantum-dynamical study of the intramolecular vibrational energy redistribution (IVR) in the electronic ground state of carbonyl sulfide (OCS), which is a prototype of an isolated many-body quantum system with strong…

Quantum Physics · Physics 2018-06-08 J. B. Pérez , J. C. Arce

We reveal the escape mechanism of orbits in a Hamiltonian system with four exit channels composed of two-dimensional perturbed harmonic oscillators. We distinguish between trapped chaotic, non-escaping regular and escaping orbits by…

Chaotic Dynamics · Physics 2017-09-28 Euaggelos E. Zotos

Many interesting physical problems described by systems of hyperbolic conservation laws are stiff, and thus impose a very small time-step because of the restrictive CFL stability condition. In this case, one can exploit the superior…

Numerical Analysis · Mathematics 2025-02-17 Gabriella Puppo , Matteo Semplice , Giuseppe Visconti

We experimentally demonstrated strong adiabatic mixed-field orientation of carbonyl sulfide molecules (OCS) in their absolute ground state of $\text{N}_{\text{up}}/\text{N}_{\text{tot}}=0.882$. OCS was oriented in combined non-resonant…

Observation of internal quantum dynamics relies on correlations between the system being observed and the measurement apparatus. We propose using the center-of-mass (c.m.) degrees of freedom of atoms and molecules as a "built-in" monitoring…

Atomic Physics · Physics 2020-07-01 A. W. Bray , U. Eichmann , S. Patchkovskii

The phase stability and equilibria of carbon dioxide is investigated from 125 -- 325K and 1 -- 10,000 atm using extensive molecular dynamics (MD) simulations and the Two-Phase Thermodynamics (2PT) method. We devise a direct approach for…

Materials Science · Physics 2021-07-28 Amanda A. Chen , Alexandria Do , Tod A. Pascal

In the context of linear stability analysis, considering unsteady base flows is notoriously difficult. A generalisation of modal linear stability analysis, allowing for arbitrarily unsteady base flows over a finite time, is therefore…

Fluid Dynamics · Physics 2023-06-16 Miguel Beneitez , Yohann Duguet , Philipp Schlatter , Dan S. Henningson

Context. The chemistry of the diffuse interstellar medium rests upon three pillars: exothermic ion-neutral reactions (" cold chemistry "), endothermic neutral-neutral reactions with significant activation barriers (" warm chemistry "), and…

Studying accretion-driven episodic outbursts in YSOs is key to understanding the later stages of star and planet formation. FU Orionis-type objects form a YSO subclass, distinguished by rapid, multi-magnitude increases in brightness at…

Solar and Stellar Astrophysics · Physics 2025-02-26 Zs. M. Szabó , A. Belloche , K. M. Menten , Y. Gong , Á. Kóspál , P. Ábrahám , W. Yang , C. J. Cyganowski , F. Wyrowski

We study the Vlasov-Poisson-Fokker-Planck system with uncertainty and multiple scales. Here the uncertainty, modeled by random variables, enters the solution through initial data, while the multiple scales lead the system to its high-field…

Analysis of PDEs · Mathematics 2017-10-18 Shi Jin , Yuhua Zhu

The frontier orbital sequence of individual dicyanovinyl-substituted oligothiophene molecules is studied by means of scanning tunneling microscopy. On NaCl/Cu(111) the molecules are neutral and the two lowest unoccupied molecular states are…

Mesoscale and Nanoscale Physics · Physics 2017-08-09 Ping Yu , Nemanja Kocić , Benjamin Siegert , Andrea Donarini , Jascha Repp

We introduce a model of a lossy second-harmonic-generating (chi^2) cavity externally pumped at the third harmonic, which gives rise to driving terms of a new type, corresponding to a cross-parametric gain. The equation for the…

Pattern Formation and Solitons · Physics 2009-11-10 Vitaly Lutsky , Boris A. Malomed

Out-of-time-order correlators (OTOCs) can be used to probe how quickly a quantum system scrambles information when the initial conditions of the dynamics are changed. In sufficiently large quantum systems, one can extract from the OTOC the…

Chemical Physics · Physics 2022-03-31 Chenghao Zhang , Peter G. Wolynes , Martin Gruebele

Strong collisional shocks in multi-ion plasmas are featured in many high-energy-density environments, including Inertial Confinement Fusion (ICF) implosions. However, their basic structure and its dependence on key parameters (e.g., the…

Plasma Physics · Physics 2017-11-22 Brett D. Keenan , Andrei N. Simakov , Luis Chacon , William T. Taitano

Fast scrambling, quantified by the exponential initial growth of Out-of-Time-Ordered-Correlators (OTOCs), is the ability to efficiently spread quantum correlations among the degrees of freedom of interacting systems, and constitutes a…

Quantum Physics · Physics 2023-05-04 Felix Meier , Mathias Steinhuber , Juan Diego Urbina , Daniel Waltner , Thomas Guhr

The soft-core boson system is one of the simplest models of supersolids, which have both off-diagonal long-range order (Bose-Einstein condensation) and diagonal long-range order (crystalline order). Although this model has been studied from…

Quantum Gases · Physics 2012-09-18 Masaya Kunimi , Yusuke Kato