Related papers: Time-dependent Nonequilibrium Thermodynamics: A Ma…
The approach to a substantiation of thermodynamics is offered. A conservative system of interacting elements, which is not in equilibrium, is used as a model. This system is then split into small subsystems that are accepted as being in…
Nonequilibrium steady state of isothermal biochemical cycle kinetics has been extensively studied, but much less investigated under non-isothermal conditions. However, once the heat exchange between subsystems is rather slow, the isothermal…
We demonstrate that irreversibility arises from the principle of microscopic reversibility and the presence of memory in the time evolution of a single copy of a system driven by a protocol. We introduce microscopic reversibility by using…
We describe recent progress towards deriving the Fundamental Laws of thermodynamics (the 0th, 1st and 2nd Law) from nonequilibrium quantum statistical mechanics in simple, yet physically relevant models. Along the way, we clarify some basic…
Quantum thermodynamics allows for the interconversion of quantum coherence and mechanical work. Quantum coherence is thus a potential physical resource for quantum machines. However, formulating a general nonequilibrium thermodynamics of…
Events in mesoscopic systems often take place at first-passage times, as is for instance the case for a colloidal particle that escapes a metastable state. An interesting question is how much work an external agent has done on a particle…
Concepts of everyday use like energy, heat, and temperature have acquired a precise meaning after the development of thermodynamics. Thermodynamics provides the basis for understanding how heat and work are related and with the general…
We use the work done on and the heat removed from a system to maintain it in a nonequilibrium steady state for a thermodynamic-like description of such a system as well as of its fluctuations. Based on a generalized Onsager-Machlup theory…
Irreversible processes play a major role in the description and prediction of atmospheric dynamics. In this paper, we present a variational derivation of the evolution equations for a moist atmosphere with rain process and subject to the…
Classical thermodynamics describes physical systems in thermodynamic equilibrium, characterized in particular by the absence of macroscopic motion. Global non-equilibrium thermodynamics extends this framework to include physical systems in…
We analyze an autonomous micro-engine as a closed quantum mechanical system, including the work it performs and the fuel it consumes. Our model system shows by example that it is possible to transfer energy steadily and spontaneously…
We establish the foundations of a nonequilibrium theory of quantum thermodynamics for noninteracting open quantum systems strongly coupled to their reservoirs within the framework of the nonequilibrium Green functions (NEGF). The energy of…
The second law of thermodynamics implies a relationship between the net entropy export by the Earth and its internal irreversible entropy production. The application of this constraint for the purpose of understanding Earth's climate is…
The field-dependent equilibrium thermodynamics is derived with two methods: either by using the potential formalism either by the statistical method. Therefore, Pontrjagin's extremum principle of control theory is applied to an extended…
Two crucial for the breakdown of the master equation arguments are put forward. The first one is related to the violence of a fundamental requirement to the notion of state (thermodynamical) variable, namely: a state variable is defined…
We investigate nonequilibrium chemical reaction systems from the view point of steady state thermodynamics proposed by Oono and Paniconi [Prog. Theor. Phys. Suppl. 130, 29 (1998)]. The concentrations of some compounds are operated by an…
Thermodynamics is traditionally concerned with systems comprised of a large number of particles. Here we present a framework for extending thermodynamics to individual quantum systems, including explicitly a thermal bath and work-storage…
In thermodynamics, quantum coherences - superpositions between energy eigenstates - behave in distinctly nonclassical ways. Recently mathematical frameworks have emerged to account for these features and have provided a range of novel…
Present-day thermodynamics has long outgrown the initial frames of the heat-engine theory and transmuted into a rather general macroscopic method for studying kinetics of various transfer processes in their inseparable connection with the…
All presently available results lead to the conclusion that nonextensivity, in the sense of nonextensive statistical mechanics (i.e., $q \ne 1$), does {\it not} modify anything to the second principle of thermodynamics, which therefore…