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Modification of surfaces to enable dropwise condensation is a promising approach for achieving high condensation rates. In this work, we present an experimental study on condensation of water on copper surfaces coated with an ultrathin, 5…

While nearly all theoretical and computational studies of entangled polymer melts have focused on uniform samples, polymer synthesis routes always result in some dispersity, albeit narrow, of distribution of molecular weights (D_M=M_w/M_n ~…

Soft Condensed Matter · Physics 2018-08-15 Brandon Peters , K. Michael Salerno , Ting Ge , Dvora Perahia , Gary Grest

Adhesion control at the interface of two surfaces is crucial in many applications. Examples are the design of micro and nanodevices such as microfuidics devices, biochips, and electronic sensors. Adhesion at the interface of two materials…

Soft Condensed Matter · Physics 2024-12-11 Susheel Kumar , Chiranjit Majhi , Krishnacharya Khare , Manjesh Kumar Singh

We study the influence of chain stiffness on droplet flow in a nano-channel, coated with semiflexible hydrophobic polymers by means of non-equilibrium molecular-dynamics simulations. The studied system is then a moving droplet in the slit…

Soft Condensed Matter · Physics 2017-10-18 Kevin Speyer , Claudio Pastorino

We develop thin films of blends of polystyrene (PS) with the thermoresponsive polymer poly(N-isopropylacrylamide) (PNIPAM) (PS/PNIPAM) and its diblock copolymer polystyrene-b-poly(N-isopropylacrylamide) (PS/PS-b-PNIPAM) in different blend…

Pressure sensitive adhesives (PSAs) are viscoelastic polymers that can form fast and robust adhesion with various adherends under fingertip pressure. The rapidly expanding application domain of PSAs, such as healthcare, wearable…

Soft Condensed Matter · Physics 2024-10-16 Yichen Wan , Qianfeng Yin , Ping Zhang , Canhui Yang , Ruobing Bai

The study of the dewetting of very thin polymer films has recently revealed many unexpected features (e.g. unusual rim morphologies and front velocities) which have been the focus of several theoretical models. Surprisingly, the most…

Polymer brushes are increasingly used to tailor surface physicochemistry for various applications such as wetting, adhesion of biological objects, implantable devices, etc. We perform Dissipative Particle Dynamics simulations to study the…

Soft Condensed Matter · Physics 2015-10-01 Sofia Biagi , Lorenzo Rovigatti , Francesco Sciortino , Chaouqi Misbah

We examine the thermally-induced fracture of an unstrained polymer chain of discrete segments coupled by an anharmonic potential by means of Molecular Dynamics simulation with a Langevin thermostat. Cases of both under- and over-damped…

Soft Condensed Matter · Physics 2015-05-27 J. Paturej , A. Milchev , V. G. Rostiashvili , T. A. Vilgis

Growth and roughness of the interface of deposited polymer chains driven by a field onto an impenetrable adsorbing surface are studied by computer simulations in (2+1) dimensions. The evolution of the interface width W shows a crossover…

Soft Condensed Matter · Physics 2007-05-23 Frank W. Bentrem , R. B. Pandey , Fereydoon Family

Thermal conduction in polymer nanocomposites depends on several parameters including the thermal conductivity and geometrical features of the nanoparticles, the particle loading, their degree of dispersion and formation of a percolating…

Applied Physics · Physics 2021-01-25 Alessandro di Pierro , Alberto Fina

Recent experiments have demonstrated that the glass transition temperature of thin polymer films can be shifted as compared to the same polymer in the bulk, the amplitude and the sign of this effect depending on the interaction between the…

Statistical Mechanics · Physics 2007-05-23 D. Long , P. Sotta

Slippage of Newtonian liquids in the presence of a solid substrate is a newly found phenomenon the origin of which is still under debate. In this paper, we present a new analysis method to extract the slip length. Enhancing the slip of…

Soft Condensed Matter · Physics 2007-05-23 R. Fetzer , K. Jacobs

We describe a microscope-based optical setup that allows us to perform space-and time-resolved measurements of the spectral reflectance of transparent substrates coated with ultrathin films. This technique is applied to investigate the…

Soft Condensed Matter · Physics 2016-03-25 Siddhartha Varma , Lionel Bureau , Delphine Débarre

The interaction between polymer brush and colloidal particles has been intensively studied in the last two decades. Here we consider a flat chain-grafted substrate immersed in a bath of active particles. Simulations show that an increase in…

Soft Condensed Matter · Physics 2017-05-17 Hui-shu Li , Bo-kai Zhang , Jian Li , Wen-de Tian , Kang Chen

Brush-like structures emerge from stretching of long polymer chains, densely grafted on to the surface of an impermeable substrate. They arise due to the competition between conformational entropic elasticity of polymer chains and excluded…

Applied Physics · Physics 2020-08-11 M. Manav , P. Anilkumar , A. Srikantha Phani

Self-healing of polymer films often takes place as the molecules diffuse across a damaged region, above their melting temperature. Using molecular dynamics simulations we probe the healing of polymer films and compare the results with those…

Soft Condensed Matter · Physics 2015-06-22 Ting Ge , Mark O. Robbins , Dvora Perahia , Gary S. Grest

Recently a novel class of responsive uncharged polymer brushes has been proposed [Klushin et al, J. Chem. Phys. 154, 074904 (2021)] where the brush-forming chains have an affinity to the substrate. For sufficiently strong surface…

Bonding between polymeric interfaces is encountered widely in several industrial applications. Many of these bonding processes rely on time-consuming and temperature-dependent classical mechanism of polymer interdiffusion via reptation in a…

Soft Condensed Matter · Physics 2022-05-10 Nikhil Padhye , Ajay Vallabh

Hypothesis: Surfactants are often added to aqueous solutions to induce spreading on otherwise unwettable hydrophobic surfaces. Alternatively, they can be introduced directly into solid hydrophobic materials-such as the soft elastomer,…

Soft Condensed Matter · Physics 2021-07-01 Daniel Joseph O'Brien , Makarand Paranjape