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Slater determinants have underpinned quantum chemistry for nearly a century, yet their full potential has remained challenging to exploit. In this work, we show that a variational wavefunction composed of a few hundred optimized…

Chemical Physics · Physics 2026-04-17 Clemens Giuliani , Jannes Nys , Rocco Martinazzo , Giuseppe Carleo , Riccardo Rossi

We propose a variational alternative to the Trotter-Suzuki decomposition that provides greater control over errors while preserving the unitary structure of time evolution. The variational parameters in our ansatz are derived from a global…

Quantum Physics · Physics 2025-11-20 Ibsal Assi , Michael Vogl , Meenu Kumari , J. P. F. LeBlanc

Two triangular factorizations of the deformation gradient tensor are studied. The first, termed the Lagrangian formulation, consists of an upper-triangular stretch premultiplied by a rotation tensor. The second, termed the Eulerian…

Classical Physics · Physics 2020-03-16 Alan D. Freed , Shahla Zamani , Laszlo Szabo , John D. Clayton

The three dimensional Total Routhian Surface (TRS) calculations are carried out for 64 nuclei between $70\leq A\leq 90$ to find triaxial superdeformed nuclei. Total of 12 nuclei were predicted to have triaxial superdeformation in which the…

Nuclear Theory · Physics 2007-05-23 Caiwan Shen , Y. S. Chen , E. G. Zhao

We use an effective field theory (EFT) approach to calculate the next to leading order (NLO) gravitational spin-orbit interaction between two spinning compact objects. The NLO spin-orbit interaction provides the most computationally complex…

General Relativity and Quantum Cosmology · Physics 2010-12-03 Michele Levi

Coherent or exact equations of motion for a post-Newtonian Lagrangian formalism are the Euler-Lagrange equations without any terms truncated. They naturally conserve energy {and} angular momentum. Doubling the phase-space variables of…

General Relativity and Quantum Cosmology · Physics 2021-12-14 Guifan Pan , Xin Wu , Enwei Liang

Time-dependent density functional theory (TDDFT) is a widely used method to investigate electron dynamics under various external perturbations such as laser fields. In this work, we present a novel approach to accelerate real time TDDFT…

Materials Science · Physics 2024-07-29 Karan Shah , Attila Cangi

We present an analysis of two experimental approaches to controlling the directionality of molecular rotation with ultrashort laser pulses. The two methods are based on the molecular interaction with either a pair of pulses (a "double kick"…

Optics · Physics 2015-06-11 C. Bloomquist , S. Zhdanovich , A. A. Milner , V. Milner

Classical mechanics and Time Dependent Hartree-Fock (TDHF) calculations of heavy ions collisions are performed to study the rotation of a deformed nucleus in the Coulomb field of its partner. This reorientation is shown to be independent on…

Nuclear Theory · Physics 2009-11-10 Cedric Simenel , Philippe Chomaz , Gilles De France

Classical mathematical techniques such as discrete integration, gradient descent optimization, and state estimation (exemplified by the Runge-Kutta method, Gauss-Newton minimization, and extended Kalman filter or EKF, respectively), rely on…

Robotics · Computer Science 2023-08-21 Eduardo Gallo

Localized molecular orbitals are often used for the analysis of chemical bonds, but they can also serve to efficiently and comprehensibly compute linear response properties. While conventional canonical molecular orbitals provide an…

Chemical Physics · Physics 2023-02-08 Souloke Sen , Bruno Senjean , Lucas Visscher

A method for storing quantum information is presented for $3$-level atomic systems interacting dipolarly with a single radiation field. The method involves performing simple local SU(2) rotations on the Hamiltonian. Under equal detuning,…

Quantum Physics · Physics 2023-06-02 R. López-Peña , S. Cordero , E. Nahmad-Achar , O. Castaños

We present a quantum linear response (qLR) approach within an active-space framework for computing indirect nuclear spin-spin coupling constants, a key ingredient in NMR spectra predictions. The method employs the unitary coupled cluster…

The definition for the Slater-type orbitals is generalized. Transformation between an orthonormal basis function and the Slater-type orbital with non-integer principal quantum numbers is investigated. Analytical expressions for the linear…

Chemical Physics · Physics 2022-10-11 A. Bağcı , P. E. Hoggan

Realizing non-unitary transformations on unitary-gate based quantum devices is critically important for simulating a variety of physical problems including open quantum systems and subnormalized quantum states. We present a dilation based…

Whether for fundamental studies or nuclear data evaluations, first-principle calculations of atomic nuclei constitute the path forward. Today, performing \textit{ab initio} calculations (a) of heavy nuclei, (b) of doubly open-shell nuclei…

Nuclear Theory · Physics 2024-07-10 M. Frosini , T. Duguet , P. Tamagno

The exchange-only optimized effective potential method is implemented with the use of Slater-type basis functions, seeking for an alternative to the standard methods of solution with some computational advantages. This procedure has been…

Chemical Physics · Physics 2011-12-22 J. J. Fernandez , J. E. Alvarellos , P. Garcia-Gonzalez , M. Filatov

The doubly odd Ta isotopes are studied within the framework of the particle-rotor model. The main aim of this study is to obtain information on the neutron-proton interaction in deformed nuclei, with particular attention focused on the role…

Nuclear Theory · Physics 2016-11-23 N. Itaco , L. Coraggio , A. Covello , A. Gargano

Soft actuators allow to transform external stimuli to mechanical deformations. Because of their deformational response to external magnetic fields, magnetic gels and elastomers represent ideal candidates for such tasks. Mostly, linear…

Soft Condensed Matter · Physics 2020-07-01 Lukas Fischer , Andreas M. Menzel

The subject of this thesis is the rigorous construction of QFT models with nontrivial interaction. Two different approaches in the framework of AQFT are discussed. On the one hand, an inverse scattering problem is considered. A given…

Mathematical Physics · Physics 2015-03-04 Sabina Alazzawi