Related papers: The layered iron arsenides Sr2CrO3FeAs and Ba2ScO3…
The recent discovery of high temperature superconductivity in a layered iron arsenide has led to an intensive search to optimize the superconducting properties of iron-based superconductors by changing the chemical composition of the spacer…
We have synthesized two iron fluo-arsenides $A$Ca$_2$Fe$_4$As$_4$F$_2$ with $A$ = Rb and Cs, analogous to the newly discovered superconductor KCa$_2$Fe$_4$As$_4$F$_2$. The quinary inorganic compounds crystallize in a body-centered…
We report the unprecedented square-planar coordination of iridium in the iron iridium arsenide Ca10(Ir4As8)(Fe2As2)5. This material experiences superconductivity at 16 K. X-ray photoemission spectroscopy and first- principles band…
We have studied the electronic and magnetic structures of the ternary iron arsenides AFe$_2$As$_2$ (A = Ba, Ca, or Sr) using the first-principles density functional theory. The ground states of these compounds are in a collinear…
Resistivity r(T), Hall coefficient RH(T), superconducting temperature Tc, and the slope of the upper critical field -dHc2/dT were studied in poly- and single-crystalline samples of the Fe-based superconductor Lu2Fe3Si5 irradiated by fast…
Iron-based superconductors Ba0.7Rb0.3Fe2As2 and CaFe1.92Co0.08As2 of the '122' family have been investigated by means of the 14.41-keV Moessbauer transition in 57Fe versus temperature ranging from the room temperature till 4.2 K. A…
First principle FLAPW-GGA calculations have been performed with the purpose to understand the electronic properties for the newly synthesized tetragonal (space group P4/nmm) layered iron arsenide-oxide: Sr4Sc2Fe2As2O6 doped with titanium.…
In the exploration of new osmium based double perovskites, Sr2FeOsO6 is a new insertion in the existing family. The polycrystalline compound has been prepared by solid state synthesis from the respective binary oxides. PXRD analysis shows…
By performing high-pressure single-crystal neutron diffraction measurements, the evolution of structure and magnetic ordering in EuFe2As2 under hydrostatic pressure were investigated. Both the tetragonal-toorthorhombic structural transition…
We report the single-crystal X-ray analysis and magnetic properties of a new double-layered perovskite antiferromagnet, Cs$_3$Cu$_2$Cl$_4$Br$_3$. This structure is composed of Cu$_2$Cl$_4$Br$_3$ double layers with elongated CuCl$_4$Br$_2$…
The ordered double perovskites Sr2CrOsO6 and Ca2CrOsO6 have been synthesized and characterized with neutron powder diffraction, electrical transport measurements, and high field magnetization experiments. Sr2CrOsO6 and Ca2CrOsO6 crystallize…
Detailed 57Fe M\"ossbauer spectroscopy measurements on superconducting NaFeAs powder crystals have been performed. The 57Fe spectra recorded in the paramagnetic temperature range (T > TN \approx 46 +/- 2 K) were discussed supposing Fe2+…
Murunskite (K$_2$FeCu$_3$S$_4$) is a bridging compound between the only two known families of high-temperature superconductors. It is a semiconductor like the parent compounds of cuprates, yet isostructural to metallic iron-pnictides.…
We have successfully prepared the new layered oxypnictides $Sr_4Sc_2O_6M_2As_2$ (M=Fe and Co). They adopt the tetragonal structure, being the same as that of $Sr_4Sc_2O_6Fe_2P_2$. The lattice constants are a=0.4045 nm and c= 0.5802 nm for…
We synthesized the samples Sr$_{1-x}$Sm$_x$FFeAs with ZrCuSiAs-type structure. These samples were characterized by resistivity and susceptibility. It is found that substitution of rare earth metal for alkaline earth metal in this system…
Since the discovery of superconductivity\cite{1} at 26 K in oxy-pnictide $LaFeAsO_{1-x}F_x$, enormous interests have been stimulated in the fields of condensed matter physics and material sciences. Among the five different structures in…
We investigated the iron-based ladder compounds (Ba,Cs)Fe$_2$Se$_3$. Their parent compounds, BaFe$_2$Se$_3$ and CsFe$_2$Se$_3$, have different space groups, formal valences of Fe and magnetic structures. Electrical resistivity, specific…
Electronic and magnetic structures of iron selenide compounds Ce2O2FeSe2 (2212\ast) and BaFe2Se3(123\ast) are studied by the first-principles calculations. We find that while all these compounds are composed of one-dimensional (1D) Fe chain…
Superconducting [(Li(1-x)Fex)OH](Fe(1-y)Liy)Se (x ~ 0.2, y ~ 0.08) was synthesized by hydrothermal methods and structurally characterized by single crystal X-ray diffraction. The crystal structure contains anti-PbO type (Fe(1-y)Liy)Se…
The magnetic susceptibility, crystal and magnetic structures, and electronic structure of double perovskite Sr2ScOsO6 are reported. Using both neutron and x-ray powder diffraction we find that the crystal structure is monoclinic P21/n from…