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We present a combined experimental and theoretical study on strong-field ionization of a three-dimensionally oriented asymmetric top molecule, benzonitrile (C$_7$H$_5$N), by circularly polarized, nonresonant femtosecond laser pulses. Prior…

We calculate the momentum distribution and the second-order correlation function in momentum space, $g^{(2)}({\bf p},{\bf p}',t)$ for molecular dimers that are coherently formed from an ultracold atomic gas by photoassociation or a Feshbach…

Other Condensed Matter · Physics 2009-11-10 D. Meiser , C. P. Search , P. Meystre

We study the rotational and vibrational heating of diatomic molecules placed near a surface at finite temperature on the basis of macroscopic quantum electrodynamics. The internal molecular evolution is governed by transition rates that…

Quantum Physics · Physics 2009-12-14 Stefan Yoshi Buhmann , M. R. Tarbutt , Stefan Scheel , E. A. Hinds

We present quantum mechanical explanations for unresolved phenomena observed in field-free molecular alignment by a femtosecond laser pulse. Quantum phase analysis of molecular rotational states reveals the physical origin of the following…

Optics · Physics 2015-04-09 Sang Jae Yun , Chul Min Kim , Jongmin Lee , Chang Hee Nam

In this work, we put forward a theoretical explanation of a peculiar effect found very recently (A. Gonzalez Urena et al., Chem. Phys. Lett. 341 (2001) 495). They have observed the deflection of a beam of molecules posessing a permanent…

Chemical Physics · Physics 2007-05-23 M. Dorado , M. Morales Furio , J. L. Perez , J. L. Sanchez Gomez

Following excitation by a strong ultra-short laser pulse, molecules develop coordinated rotational motion, exhibiting transient alignment along the direction of the laser electric field, followed by periodic full and fractional revivals…

Quantum Physics · Physics 2007-05-23 Sharly Fleischer , Ilya. Sh. Averbukh , Yehiam Prior

Laser cooling is used to produce ultracold atoms and molecules for quantum science and precision measurement applications. Molecules are more challenging to cool than atoms due to their vibrational and rotational internal degrees of…

Atomic Physics · Physics 2024-09-27 Grace K. Li , Christian Hallas , John M. Doyle

Improved optical control of molecular quantum states promises new applications including chemistry in the quantum regime, precision tests of fundamental physics, and quantum information processing. While much work has sought to prepare…

Fluorescent molecules emit light in a dipole radiation pattern that can be used to infer their orientation through defocused fluorescence microscopy. Proper measurement of the orientation requires mathematical modeling of the radiation…

Optics · Physics 2025-08-07 E. Dey , M. Elorza , F. W. Foss , J. J. Gomez Cadenas , B. J. P. Jones

We demonstrate with an experiment how molecules are a natural test-bed for probing fundamental quantum thermodynamics. Single-molecule spectroscopy has undergone transformative change in the past decade with the advent of techniques…

Quantum Physics · Physics 2017-10-25 Cormac Browne , Tristan Farrow , Oscar C. O. Dahlsten , Vlatko Vedral

Isolating single molecules in the solid state has allowed fundamental experiments in basic and applied sciences. When cooled down to liquid helium temperature, certain molecules show transition lines, that are tens of megahertz wide,…

The phenomenon of polarization of nuclei in the process of stimulated recombination of atoms in the field of circularly polarized laser radiation is considered. This effect is considered for the case of the proton-electron beams used in the…

Atomic Physics · Physics 2017-07-11 M. A. Kutlan

It is discussed the decoherence problems in ensemble large-scale solid state NMR quantum computer based on the array of P donor atoms having nuclear spin I = 1/2. It is considered here, as main mechanisms of decoherence for low temperature…

Quantum Physics · Physics 2009-11-07 A. A. Kokin

The rich information content of measurements in the molecular frame rather than the laboratory frame has motivated the development of several methods for aligning gas phase molecules in space. Even so, for asymmetric tops the problem of…

Atomic Physics · Physics 2016-11-23 Varun Makhija , Xiaoming Ren , Drue Gockel , Anh-Thu Le , Vinod Kumarappan

The ability to cool atoms below the Doppler limit -- the minimum temperature reachable by Doppler cooling -- has been essential to most experiments with quantum degenerate gases, optical lattices and atomic fountains, among many other…

Atomic Physics · Physics 2018-01-17 S. Truppe , H. J. Williams , M. Hambach , L. Caldwell , N. J. Fitch , E. A. Hinds , B. E. Sauer , M. R. Tarbutt

We propose and analyze a nanomechanical architecture where light is used to perform linear quantum operations on a set of many vibrational modes. Suitable amplitude modulation of a single laser beam is shown to generate squeezing,…

Mesoscale and Nanoscale Physics · Physics 2012-12-17 Michael Schmidt , Max Ludwig , Florian Marquardt

We computationally demonstrate a new method for coherently controlling the rotation-axis direction in asymmetric top molecules with an optical centrifuge. Appropriately chosen electric-field strengths and the centrifuge's acceleration rate…

Chemical Physics · Physics 2021-06-16 Emil J. Zak , Andrey Yachmenev , Jochen Küpper

Ultracold polar molecules are promising for quantum information processing and searches for physics beyond the Standard Model. Laser cooling to ultracold temperatures is an established technique for trapped diatomic and triatomic molecules.…

Lie-algebraic and quantum-algebraic techniques are used in the analysis of thermodynamic properties of molecules and solids. The local anharmonic effects are described by a Morse-like potential associated with the $su(2)$ algebra. A…

Statistical Mechanics · Physics 2007-05-23 Maia Angelova

This article reviews the current state of the art in the field of cold and ultracold molecules and demonstrates that chemical reactions, inelastic collisions and dissociation of molecules at subKelvin temperatures can be manipulated with…

Atomic Physics · Physics 2015-06-26 R. V. Krems
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