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Combining high resolution scanning tunneling microscopy and first principle calculations, we identified the major native defects, in particular the Se vacancies and Se interstitial defects that are responsible for the bulk conduction and…

Materials Science · Physics 2016-09-07 Jixia Dai , Damien West , Xueyun Wang , Yazong Wang , Daniel Kwok , S-W. Cheong , S. B. Zhang , Weida Wu

The results of ultra-high vacuum low-temperature scanning-tunneling microscopy (STM) and spectroscopy (STS) of atomically clean (111) surface of the topological insulator Bi$_2$Se$_3$ are presented. We observed several types of new…

Mesoscale and Nanoscale Physics · Physics 2014-12-12 A. Yu. Dmitriev , N. I. Fedotov , V. F. Nasretdinova , S. V. Zaitsev-Zotov

Bi2Se3 is a prototypical topological insulator which has a small band gap (~0.3 eV) and topologically protected conducting surface states. This material exhibits quite strong thermoelectric effects. Here we show in a mechanically exfoliated…

We show that by Ca-doping the Bi2Se3 topological insulator, the Fermi level can be fine tuned to fall inside the band gap and therefore suppress the bulk conductivity. Non-metallic Bi2Se3 crystals are obtained. On the other hand, the Bi2Se3…

Strongly Correlated Electrons · Physics 2015-05-19 Y. S. Hor , J. G. Checkelsky , D. Qu , N. P. Ong , R. J. Cava

Polycrystalline Sb 2 Te 3-x Se x (0.0 < x < 1.0) samples were synthesized by the solid state reaction method. The structural analysis showed that up to the maximal concentration of Se, the samples possess the Rhombohedral crystal symmetry…

By eliminating normal fabrication processes, we preserve the bulk insulating state of calcium-doped Bi2Se3 single crystals in suspended nanodevices, as indicated by the activated temperature dependence of the resistivity at low…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Peng Wei , Zhiyong Wang , Xinfei Liu , Vivek Aji , Jing Shi

We report electrical (angular magneto-resistance, and Hall), thermal (heat capacity) and spectroscopic (Raman, x-ray photo electron, angle resolved photo electron) characterization of bulk Bi2Se3 topological insulator, which is being is…

Strongly Correlated Electrons · Physics 2018-03-14 Rabia Sultana , Geet Awana , Banabir Pal , P. K. Maheshwari , Monu Mishra , Govind Gupta , Anurag Gupta , S. Thirupathaiah , V. P. S. Awana

We report x-ray diffraction, electrical resistivity, and magnetoresistance measurements on Bi2Se3 under high pressure and low temperature conditions. Pressure induces profound changes in both the room temperature value of the electrical…

Materials Science · Physics 2015-06-03 J. J. Hamlin , J. R. Jeffries , N. P. Butch , P. Syers , D. A. Zocco , S. T. Weir , Y. K. Vohra , J. Paglione , M. B. Maple

The thermoelectric properties between 10 and 300 K and the growth of single crystals of n-type and p-type GeBi4Te7, GeSb4Te7, and the Ge(Bi1-xSbx)4Te7 solid solution are reported. Single crystals were grown by the modified Bridgman method,…

Materials Science · Physics 2013-01-28 Fabian von Rohr , Andreas Schilling , Robert J. Cava

At the ultra-thin film limit, quantum confinement strongly improves thermoelectric figure of merit in materials such as Sb$_2$Te$_3$ and Bi$_2$Te$_3$. These high quality films have only been realized using well controlled techniques such as…

We report crystal growth and below 2.5K superconductivity of Nb0.25Bi2Se3. These crystals are grown by self flux method. The X-ray diffraction (XRD) pattern of as grown crystal flake shows (00l) plane (c-orientation) growth. The Rietveld…

Superconductivity · Physics 2019-11-20 M. M. Sharma , P. Rani , Lina Sang , X. L. Wang , V. P. S. Awana

Pure Topological Insulating materials preserve a unique electronic state comprising of bulk insulating gap and conducting surface states. Here we use bulk Bi2Se3 single crystals possessing Se vacancy defects as a prototype topological…

Materials Science · Physics 2019-08-13 Amit Jash , Kamalika Nath , T. R. Devidas , A. Bharathi , S. S. Banerjee

The carrier type and density in Bi2Se3 single crystals are systematically tuned by introducing a calcium (Ca) dopant. A carrier density of ~1x1017 cm-3 which corresponds to ~25 meV in the Fermi energy is obtained in both n- and p-type…

Materials Science · Physics 2015-05-19 Zhiyong Wang , Tao Lin , Peng Wei , Xinfei Liu , Randy Dumas , Kai Liu , Jing Shi

Crystalline $\rm Bi_2Se_3$ is one of the most explored three-dimensional topological insulator, with a $0.3\;\rm eV$ energy gap making it promising for applications. Its amorphous counterpart could bring to light new possibilities for large…

Materials Science · Physics 2021-12-14 Bruno Focassio , Gabriel R. Schleder , F. Crasto de Lima , Caio Lewenkopf , Adalberto Fazzio

With a large band gap and a single Dirac cone responsible for the topological surface states, Bi2Se3 is widely regarded as a prototypical 3D topological insulator. Further applications of the bulk material has, however, been hindered by…

Materials Science · Physics 2023-06-02 Rodrigo T. Paulino , Marcos A. Avila

We report a transport study of exfoliated few monolayer crystals of topological insulator Bi$_2$Se$_3$ in an electric field effect (EFE) geometry. By doping the bulk crystals with Ca, we are able to fabricate devices with sufficiently low…

Mesoscale and Nanoscale Physics · Physics 2011-06-21 J. G. Checkelsky , Y. S. Hor , R. J. Cava , N. P. Ong

Electrical field control of the carrier density of topological insulators (TI) has greatly expanded the possible practical use of these materials. However, the combination of low temperature local probe studies and a gate tunable TI device…

Mesoscale and Nanoscale Physics · Physics 2013-04-15 Tong Zhang , Niv Levy , Jeonghoon Ha , Young Kuk , Joseph A. Stroscio

The single crystal growth and superconducting properties of PbTaSe2 with non-centrosymmetric crystal structure is reported. Using the chemical vapor transport (CVT) technique, PbTaSe2 crystallizes in a layered structure and the crystal…

The exploration of topological Dirac surface states is significant in the realms of condensed matter physics and future technological innovations. Among the materials garnering attention is Sb$_{2}$Te$_{3}$, a compound that theoretically…

PbSe, a predicted two-dimensional (2D) topological crystalline insulator (TCI) in the monolayer limit, possess excellent thermoelectric and infrared optical properties. Native defects in PbSe take a crucial role for the applications.…

Materials Science · Physics 2023-08-24 Qiwei Tian , Ping Li , Li Zhang , Yuan Tian , Long-Jing Yin , Lijie Zhang , Zhihui Qin
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